1,720,973 research outputs found

    Interfacial Charge Density and Its Connection to Adhesion and Frictional Forces

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    We derive a connection between the intrinsic tribological properties and the electronic properties of a solid interface. In particular, we show that the adhesion and frictional forces are dictated by the electronic charge redistribution occurring due to the relative displacements of the two surfaces in contact. We define a figure of merit to quantify such a charge redistribution and show that simple functional relations hold for a wide series of interactions including metallic, covalent, and physical bonds. This suggests unconventional ways of measuring friction by recording the evolution of the interfacial electronic charge during sliding. Finally, we explain that the key mechanism to reduce adhesive friction is to inhibit the charge flow at the interface and provide examples of this mechanism in common lubricant additives

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

    Author Index

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    koamabayili/VECTRON-author-checklist: VECTRON author checklist

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    We have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used

    Pyrolysis of 3-azidopropionitrile studied by UV photoelectron and matrix-isolation IR spectroscopies: Formation of ketenimine H2Cdouble bond; length as m-dashCdouble bond; length as m-dashNH

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    The electronic structure, vibrational properties and pyrolysis behaviour of 3-azidopropionitrile (3APN, N3CH2CH2CN) are investigated using ultraviolet photoelectron spectroscopy (UVPES) and matrix-isolation infrared (IR) spectroscopy, supported by results from ab initio and DFT electronic structure calculations. 3APN is found to have an HOMO vertical ionisation energy (VIE) of 10.05 ± 0.02 eV and the strongest IR absorption bands located at 2173 and 1296 cm?1. Pyrolysis of the title compound revealed the presence of N2, HCN, CH3CN and ketenimine, H2Cdouble bond; length as m-dashCdouble bond; length as m-dashNH, among the decomposition products, the latter behaving as a reaction intermediate. From G3 computational results, 3-iminopropionitrile, CNsingle bondCH2CHdouble bond; length as m-dashNH, was found to be formed in competition with H2Cdouble bond; length as m-dashN ? CH2CN, through 160–180 kJ mol?1 energy barriers. On the basis of experimental evidence and G3 results, ketenimine is proposed as the dominant intermediate arising from further decomposition of both imine (CNsingle bondCH2CHdouble bond; length as m-dashNH) and H2Cdouble bond; length as m-dashNsingle bondCH2CN compound
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