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    FT-IR and 1H-NMR Investigations on the Correlation between Stretching Vibration and the Chemical Shift of Indoles

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    FT-IR and 1H-NMR Investigations on the Correlation between Stretching Vibration and the Chemical Shift of Indoles" con G. Tosi, L. Greci, P. Bruni, E. Giorgini ed E. Maurelli, Proceedings of the 2nd International Workshop on Fourier Transform Infrared Spectroscopy, 1992, 29

    Reaction of indolinonic aminoxyls with nitric oxide

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    2-Methyl-2-phenyl-3-oxoindolin-1-yloxyl and 2-methyl-2-phenyl-3-aryliminoindolin-1-yloxyl radicals react with nitric oxide in the absence and presence of oxygen to form both substituted and unsubstituted N-nitro and N-nitroso stable compounds as the main products, while mono and dinitro compounds are formed in minor yields. In the presence of oxygen, the formation of the corresponding quinone imine N-oxide is observed. Mechanisms for the formation of the reaction products are proposed and discussed, leading to new insights into the chemistry of nitric oxide with aminoxyls. Crystal structures of 2-methyl-2-phenyl-N-nitrosoindolin-3-one and 2-methyl-2-phenyl-N-nitroindolin-3-one have been determined
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