100,310 research outputs found

    Reductive leaching of manganese and zinc from spent alkaline and zinc-carbon batteries in acidic media

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    The main purpose of this work was to investigate the effectiveness of oxalic acid as a reductant for the leaching of manganese and zinc from spent alkaline and zincâcarbon batteries in sulfuric acid or hydrochloric acid media. Three different types of battery powders were tested: zincâcarbon, alkaline and mixed (50% zincâcarbon, 50% alkaline). Kinetic tests were initially conducted with the mixed battery powder. Leaching experiments were carried out according to 24 full factorial design, and regression equations for the leaching of Mn and Zn were determined. Washing of the powders (neutral leaching) was effective on the removal of potassium and chloride. Increasing solid/liquid ratio from 1/5 to 1/10 in neutral leaching did not significantly change potassium and chloride removal. A leach duration of 3 h was found to be generally sufficient for the equilibrium to be reached for both Zn and Mn. Oxalic acid concentration had strongest negative effect on Zn leaching in both sulfuric and hydrochloric acid media, whereas the concentrations of sulfuric and hydrochloric acids exhibited strongest positive effect for both Mn extraction yield (MnEY) and Zn extraction yield (ZnEY). In the range of tested conditions, pulp density had no important effect on MnEY and ZnEY for both acids. Temperature had negative effect for both MnEY and ZnEY in sulfuric acid solution; however, such effect was less pronounced in hydrochloric acid solution. For the sulfuric acid solution, 91% MnEY and 112% ZnEY were achieved at 45 °C after 3 h of leaching by 10% pulp density, â30% oxalic acid (30% less than the stoichiometric requirement), +30% H2SO4. For the hydrochloric acid solution, about 86% MnEY and 95% ZnEY were obtained at 20% pulp density, â30% oxalic acid, +30% HCl, at 45 °C after 3 h of leaching

    A review of technologies for the recovery of metals from spent alkaline and zincâÂÂcarbon batteries

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    The main aim of this paper is to review and evaluate the recovery studies and associated technologies for metals from spent batteries. More attention was given especially to the recovery of Zn and Mn from spent alkaline and zincâcarbon batteries. Nowadays much research work is concentrated on the recovery of Zn and Mn from alkaline and zincâcarbon batteries. Various different metal recovery processes including physical, pyrometallurgical and hydrometallurgical ones are discussed. Compared to pyrometallurgical methods, hydrometallurgical methods are becoming a well-established and efficient method for recovering metals from raw materials. Although there have been many proposed or currently applied recovery processes majority of them are effective only in recovering certain components of spent batteries. Considering the more stringent regulations and cost, environmental protection, preservation of raw materials issues; thus, effective, economical and practical recovery technologies are required not only for metal recoveries but also for other components of batteries such as plastic, paper, steel, etc. More research work should be conducted to develop such recovery technologies. In addition, process control and plant optimization studies should also be conducted for more feasible full-scale applications

    Letter, [Author unclear] to Paulina T. Merritt

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    Handwritten letter to Paulina Merritt from an unknown author, October 1, 1876.

    Handwritten biographical information on Paulina T. McClung Merritt

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    A handwritten biography of Paulina T. McClung Merritt by an unknown author, 1892.

    Heterogeneous and tissue-specific regulation of effector T cell responses by IFN-gamma during Plasmodium berghei ANKA infection.

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    IFN-γ and T cells are both required for the development of experimental cerebral malaria during Plasmodium berghei ANKA infection. Surprisingly, however, the role of IFN-γ in shaping the effector CD4(+) and CD8(+) T cell response during this infection has not been examined in detail. To address this, we have compared the effector T cell responses in wild-type and IFN-γ(-/-) mice during P. berghei ANKA infection. The expansion of splenic CD4(+) and CD8(+) T cells during P. berghei ANKA infection was unaffected by the absence of IFN-γ, but the contraction phase of the T cell response was significantly attenuated. Splenic T cell activation and effector function were essentially normal in IFN-γ(-/-) mice; however, the migration to, and accumulation of, effector CD4(+) and CD8(+) T cells in the lung, liver, and brain was altered in IFN-γ(-/-) mice. Interestingly, activation and accumulation of T cells in various nonlymphoid organs was differently affected by lack of IFN-γ, suggesting that IFN-γ influences T cell effector function to varying levels in different anatomical locations. Importantly, control of splenic T cell numbers during P. berghei ANKA infection depended on active IFN-γ-dependent environmental signals--leading to T cell apoptosis--rather than upon intrinsic alterations in T cell programming. To our knowledge, this is the first study to fully investigate the role of IFN-γ in modulating T cell function during P. berghei ANKA infection and reveals that IFN-γ is required for efficient contraction of the pool of activated T cells

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

    Pelevin’s Trinity in the novel “t”: author – protagonist – reader

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    The article attempts to interpret Pelevin's artistic strategy in the novel "T" by exploring its subject organization and addressing the key problems of the author, the protagonist, and the reader as they are seen by the researcher. The article analyzes the peculiarities of constructing the narrative reality in the novel "T", and goes on to discuss Pelevin's philosophic models of the development of the humankind, and the emergence of his new anthropology

    Measuring industry-science links through inventor-author relations: A profiling method

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    In this pilot study we examine the performance of text-based profiling in recovering a set of validated inventor-author links. In a first step we match patents and publications solely based on their similarity in content. Next, we compare inventor and author names on the highest ranked matches for the occurrence of name matches. Finally, we compare these candidate matches with the names listed in a validated set of inventor-author names. Our text-based profile methodology performs significantly better than a random matching of patents and publications, suggesting that text-based profiling is a valuable complementary tool to the name searches used in previous studies.innovation; industry-science links; text-based profiling;

    Wave turbulence of a rotating array of quantized vortices in the T → 0 temperature limit

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    The dynamics of quantized vortices in the zero temperature limit T0T \rightarrow 0 is currently of great interest, particularly in the case of the Fermi superfluid 3^3He-B. Here we study wave turbulence, generated by the librating motion of a rotating cylindrical container filled with 3^3He-B, in the limit of vanishing viscous forces at temperatures T0.2TcT \leq 0.2 T_{c}. The polarization of the quantized vortices with respect to the axis of rotation is measured using non-invasive NMR techniques. We observe a decrease of the polarization when the librating motion is started, and a two-stage relaxation process when the modulation of the rotation velocity is stopped. The first relaxation process is associated with the dissipation of large-scale flow stored in inertial waves and the solid body rotation of the vortex array. From the decay of these energy reservoirs we determine the rate of energy dissipation of large-scale flow. The later second process is related to the relaxation of Kelvin waves on individual vortices. This process is monitored by the recovery of the polarization. The existence of a Kelvin wave cascade at the lowest temperatures is currently a central open question. We supply some evidence for the cascade

    DNA fusion gene vaccination mobilizes effective anti-leukemic cytotoxic T lymphocytes from a tolerized repertoire

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    The majority of known human tumor-associated antigens derive from non-mutated self proteins. T cell tolerance, essential to prevent autoimmunity, must therefore be cautiously circumvented to generate cytotoxic T cell responses against these targets. Our strategy uses DNA fusion vaccines to activate high levels of peptide-specific CTL. Key foreign sequences from tetanus toxin activate tolerance-breaking CD4+ T cell help. Candidate MHC class Ibinding tumor peptide sequences are fused to the C terminus for optimal processing and presentation. To model performance against a leukemia-associated antigen in a tolerized setting, we constructed a fusion vaccine encoding an immunodominant CTL epitopederived from Friend murine leukemia virus gag protein (FMuLVgag) and vaccinated tolerant FMuLVgag-transgenic (gag-Tg) mice. Vaccination with the construct induced epitopespecificIFN-c-producing CD8+ T cells in normal and gag-Tg mice. The frequency and avidity of activated cells were reduced in gag-Tg mice, and no autoimmune injury resulted. However, these CD8+ T cells did exhibit gag-specific cytotoxicity in vitro and in vivo. Also, epitope-specific CTL killed FBL-3 leukemia cells expressing endogenous FMuLVgag antigen and protected against leukemia challenge in vivo. These results demonstrate a simple strategy to engage anti-microbial T cell help to activate epitope-specific polyclonal CD8+ T cell responses from a residual tolerized repertoire
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