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    Cu3P binary phosphide: Synthesis via a wet mechanochemical method and electrochemical behavior as negative electrode material for lithium-ion batteries

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    Mechanochemical synthesis of Cu3P in the presence of n-dodecane results in a material with a secondary particle size distribution of 10 μ m, secondary particles which consist of homogeneously agglomerated 20 nm primary particles. The electrochemical performance of Cu3P with lithium is infl uenced by the reaction depth, in other words by the lower potential cut-off. During the electrochemical reaction, the displacement of copper by lithium from the Cu3P structure until the formation of Li3 P and Cu deteriorates the capacity retention. Improved performance was obtained when the charge potential was limited to 0.50 V (vs. Li/Li+) and the formation of the Li x Cu 3-x P phase (0 = × = 2). In this case, when the potential is limited to 0.5 V, the capacity is stable for more than 50 cycles. Acceptable electrochemical performances in Li-ion cells within the voltage range 0.50-2.0 V (vs. Li/Li+) were shown when Cu3P was used as an anode and Li 1.2 (Ni0.13Mn0.54Co0.13)O 2and LiNi0.5Mn1.5O4 as positive electrode materials. © 2013 WILEY-VCH Verlag GmbH and Co

    Investigations on cellulose-based high voltage composite cathodes for lithium ion batteries

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    Carboxymethyl cellulose (CMC), a green and low-cost binder, is used to make lithium-ion battery composite electrodes containing the high voltage cathode material Li2MnO3-LiMO2. This combination of materials results in a homogeneous electrode, which is proved by electron microscopy. The results of the electrochemical investigation indicate that CMC operates well at very high voltages (4.8 V). Compared to the PVDF binder, the CMC-based electrode shows an improved cycling stability as well as a very promising rate capability. © 2010 Elsevier B.V. All rights reserved

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Synthesis and electrochemical performance of the high voltage cathode material Li[Li0.2Mn0.56Ni0.16Co 0.08]O2 with improved rate capability

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    The high voltage layered Li[Li0.2Mn0.56Ni 0.16Co0.08]O2 cathode material, which is a solid solution between Li2MnO3 and LiMn 0.4Ni0.4Co0.2O2, has been synthesized by co-precipitation method followed by high temperature annealing at 900 °C. XRD and SEM characterizations proved that the as prepared powder is constituted of small and homogenous particles (100-300 nm), which are seen to enhance the material rate capability. After the initial decay, no obvious capacity fading was observed when cycling the material at different rates. Steady-state reversible capacities of 220 mAh g-1 at 0.2C, 190 mAh g-1 at 1C, 155 mAh g-1 at 5C and 110 mAh g-1 at 20C were achieved in long-term cycle tests within the voltage cutoff limits of 2.5 and 4.8 V at 20 °C. © 2011 Elsevier B.V. All rights reserved

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

    Author Index

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    koamabayili/VECTRON-author-checklist: VECTRON author checklist

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    We have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
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