7,516 research outputs found
Synthesis and coordination chemistry of scorpionate ligands and their applications in 11C-positron emission tomography
No full textThis thesis is concerned with the synthesis and coordination chemistry of· a range of poly(pyrazolyl)borate 'scorpionate' ligands and examines their suitability in facilitating rapid [llC]carbonylation reactions to form radiotracers for application in positron emission tomography (PET). Author (full names): Steven Kealey Title of thesis: Synthesis and Coordination Chemistry of Scorpionate Ligands and their Applications in He-Positron Emission Tomography The second part of this thesis concerns the use of a copper(I)-Tp system for selectively solubilising llCO from nitrogen-rich gas streams for subsequent use in palladium-catalysed carbonylation reactions between amines and aryl-halides to form amides. These reactions were performed on a microfluidic device and in Schlenk apparatus using unlabelled carbon monoxide. These reactions ~were transferred to the radiochemical laboratory whereby efficient llCO trapping was observed prior to the formation of llC-radiolabelled amides. The third part of this thesis explores the coordination chemistry of palladium(II) towards a novel hybrid ligand consisting of pyrazolyl and triphenylphosphine moieties. The potential hemilabile behaviour of this ligand and its derivatives towards palladium was investigated and the use of these complexes as catalysts for carbonylation reactions is described. The final part of this thesis examines the coordination chemistry of poly(pyrazolyl)borates bearing additional coordinating groups appended to the 3- or 5~position ofthe pyrazolyl rings. Reactions ofthe 3-substituted derivatives were carried out with a range of metals and found to display varied coordination behaviour depending on the specific coordination requirements ofthe metal.EThOS - Electronic Theses Online ServiceGBUnited Kingdo
Steven Johnson Author Talk Poster
No full textK-State Book NetworkA poster advertising an author talk by Steven Johnson at Kansas State University on September 3, 2014. Steven Johnson's book "The Ghost Map" was the 2014-2015 common book
Steven Bialer and Patti Smith, July 1978
No full textMusician, poet, and author Patti Smith sits on a bed in a hotel room in July 1978. The photograph was taken by Don Hamerman as part of a session for "Unicorn Times," an alternative performing arts periodical in Washington, D.C. Steven Bialer, the Design Director for "Unicorn Times," is seated on the bed next to Smith
Steven Garber
No full textSteven Garber speaks on the importance and value of truth.
Steven Garber is the principal of The Washington Institute for Faith, Vocation & Culture, which is focused on reframing the way people understand life, especially the meaning of vocation and the common good. A consultant to foundations, corporations and educational institutions, he is a teacher of many people in many places. The author of The Fabric of Faithfulness: Weaving Together Belief and Behavior, and Visions of Vocation: Common Grace for the Common Good, he is also a contributor to the books, Faith Goes to Work: Reflections from the Marketplace, and Get Up Off Your Knees: Preaching the U2 Catalogue. He lives with his wife Meg in Virginia
Steven Yedinak Interview
No full textLTC (RET) Steven M. Yedinak commissioned in the U. S. Army Infantry in 1963 and subsequently spent 26 years in Special Forces and Airborne Infantry. He served two combat tours in Vietnam (1966-67 & 1971-1972), and started the Mobile Guerrilla Force. He is the author of Hard to Forget: An American with the Mobile Guerrilla Force in Vietnam (Random House, 1998). He retired from the Army in 1989
Gamification is broken. An interview with Steven Poole
No full textSteven Poole is the author of Trigger Happy (2000. New York, NY: Arcade Publish), Unspeak (2006. New York, NY: Grove Press), and You Aren’t What You Eat (2012. In press). He has written extensively on books, culture, and videogames for The Guardian and other publications
Steven Pinker on language and thought
No full textEducação Superior::Linguística, Letras e Artes::LinguísticaThis video presents an exclusive preview of Steven Pinker's book: the stuff of thought. The author looks at language and how it expresses what goes on in our minds and how the words we choose communicate much more than we realize. For Steven Pinker, the brilliance of the mind lies in the way it uses just two processes to turn the finite building blocks of our language into infinite meanings. The first is metaphor: we take a concrete idea and use it as a stand-in for abstract thoughts. The second is combination: we combine ideas according to rules, like the syntactic rules of language, to create new thoughts out of old one
Steven Pinker on language and thought
No full textEducação Superior::Linguística, Letras e Artes::LinguísticaThis video presents an exclusive preview of Steven Pinker's book: the stuff of thought. The author looks at language and how it expresses what goes on in our minds and how the words we choose communicate much more than we realize. For Steven Pinker, the brilliance of the mind lies in the way it uses just two processes to turn the finite building blocks of our language into infinite meanings. The first is metaphor: we take a concrete idea and use it as a stand-in for abstract thoughts. The second is combination: we combine ideas according to rules, like the syntactic rules of language, to create new thoughts out of old one
Steven Pinker on language and thought
No full textEducação Superior::Linguística, Letras e Artes::LinguísticaThis video presents an exclusive preview of Steven Pinker's book: the stuff of thought. The author looks at language and how it expresses what goes on in our minds and how the words we choose communicate much more than we realize. For Steven Pinker, the brilliance of the mind lies in the way it uses just two processes to turn the finite building blocks of our language into infinite meanings. The first is metaphor: we take a concrete idea and use it as a stand-in for abstract thoughts. The second is combination: we combine ideas according to rules, like the syntactic rules of language, to create new thoughts out of old one
Steven Pinker on language and thought
No full textEducação Superior::Linguística, Letras e Artes::LinguísticaThis video presents an exclusive preview of Steven Pinker's book: the stuff of thought. The author looks at language and how it expresses what goes on in our minds and how the words we choose communicate much more than we realize. For Steven Pinker, the brilliance of the mind lies in the way it uses just two processes to turn the finite building blocks of our language into infinite meanings. The first is metaphor: we take a concrete idea and use it as a stand-in for abstract thoughts. The second is combination: we combine ideas according to rules, like the syntactic rules of language, to create new thoughts out of old one
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