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    Mobilization of Tungsten in Greenstone Belts of the Archean Kaapvaal and Singhbhum Cratons

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    Abstract Due to the inherently fluid‐mobile nature of W, the 182 W record of the early Earth may have been obscured by fluid‐induced mobilization of W. To investigate W mobilization in Archean greenstone sequences, we analyzed 182 W isotope systematics and major and trace element concentrations in samples from the 3.53 Ga old Onverwacht Group of the Kaapvaal Craton (South Africa) and the >3.51 Ga old Badampahar Group of the Singhbhum Craton (India). Our results for mafic and ultramafic metavolcanic rocks show W/Th ratios significantly higher than primary magmatic values, which suggests fluid‐induced W enrichment. Samples least affected by secondary W enrichment (W/Th < 0.26) show no resolvable W isotope anomalies from modern mantle values in both cratons. Samples from the Kaapvaal Craton with elevated W/Th exhibit deficits in 182 W as low as −8.1 ± 4.3 ppm compared to the modern mantle. Covariations of μ 182 W with W/Th, and Ce/Pb suggest that negative isotope signatures were introduced during secondary fluid‐mediated processes. The enrichment of W is most evident in altered ultramafic rocks comprising serpentine, resulting in additional covariations between MgO, LOI, and W/Th. The W isotope composition of serpentinized komatiites reflects the composition of younger intruding granitoids. We therefore infer the latter as a possible source of W‐rich fluids. The Badampahar Group samples exhibit little W isotope variability. A well‐resolved 182 W deficit of −6.2 ± 2.9 ppm was determined in a single komatiite sample, which indicates an unknown fluid source, currently not represented in any other unit of the Singhbhum Craton.Plain Language Summary The tungsten (W) isotope composition of ancient rocks can be used to trace processes that occurred during Earth's early evolution. However, interactions between rocks and fluids may alter the W concentration and therefore influence the interpretation of W isotope data. To identify the source of such fluids and the processes by which they affect the W isotope composition of rocks, we analyzed ancient rock samples from South Africa and India. The isotope composition of rocks with a low W concentration reflects that of the modern Earth. Therefore, they do not trace the processes that occurred during Earth's early evolution. Samples from South Africa with untypically high W concentrations show a different isotopic composition. The variation in the W isotope signature correlates with other chemical indices that are susceptible to modification by fluid‐related processes. This shows that the W within the rocks is derived from an external fluid source and not from their original magmatic source. Samples with the highest W enrichment have a similar isotope composition as spatially associated intrusive rocks. By inference, the latter likely represent the source of W‐rich fluids. The samples from India show similar enrichment in W, indicating similar fluid‐related processes and W sources at both localities.Key Points The magmatic sources of metavolcanic rocks from the Onverwacht Group and the Badampahar Group do not exhibit W isotope anomalies Negative W isotope signatures in the Onverwacht Group are likely derived from fluids sourced from younger intrusive granitoids Felsic intrusive rocks are a major source of W‐rich fluids in Paleoarchean greenstone unitsAbstract Due to the inherently fluid‐mobile nature of W, the 182 W record of the early Earth may have been obscured by fluid‐induced mobilization of W. To investigate W mobilization in Archean greenstone sequences, we analyzed 182 W isotope systematics and major and trace element concentrations in samples from the 3.53 Ga old Onverwacht Group of the Kaapvaal Craton (South Africa) and the >3.51 Ga old Badampahar Group of the Singhbhum Craton (India). Our results for mafic and ultramafic metavolcanic rocks show W/Th ratios significantly higher than primary magmatic values, which suggests fluid‐induced W enrichment. Samples least affected by secondary W enrichment (W/Th < 0.26) show no resolvable W isotope anomalies from modern mantle values in both cratons. Samples from the Kaapvaal Craton with elevated W/Th exhibit deficits in 182 W as low as −8.1 ± 4.3 ppm compared to the modern mantle. Covariations of μ 182 W with W/Th, and Ce/Pb suggest that negative isotope signatures were introduced during secondary fluid‐mediated processes. The enrichment of W is most evident in altered ultramafic rocks comprising serpentine, resulting in additional covariations between MgO, LOI, and W/Th. The W isotope composition of serpentinized komatiites reflects the composition of younger intruding granitoids. We therefore infer the latter as a possible source of W‐rich fluids. The Badampahar Group samples exhibit little W isotope variability. A well‐resolved 182 W deficit of −6.2 ± 2.9 ppm was determined in a single komatiite sample, which indicates an unknown fluid source, currently not represented in any other unit of the Singhbhum Craton.Plain Language Summary The tungsten (W) isotope composition of ancient rocks can be used to trace processes that occurred during Earth's early evolution. However, interactions between rocks and fluids may alter the W concentration and therefore influence the interpretation of W isotope data. To identify the source of such fluids and the processes by which they affect the W isotope composition of rocks, we analyzed ancient rock samples from South Africa and India. The isotope composition of rocks with a low W concentration reflects that of the modern Earth. Therefore, they do not trace the processes that occurred during Earth's early evolution. Samples from South Africa with untypically high W concentrations show a different isotopic composition. The variation in the W isotope signature correlates with other chemical indices that are susceptible to modification by fluid‐related processes. This shows that the W within the rocks is derived from an external fluid source and not from their original magmatic source. Samples with the highest W enrichment have a similar isotope composition as spatially associated intrusive rocks. By inference, the latter likely represent the source of W‐rich fluids. The samples from India show similar enrichment in W, indicating similar fluid‐related processes and W sources at both localities.Key Points The magmatic sources of metavolcanic rocks from the Onverwacht Group and the Badampahar Group do not exhibit W isotope anomalies Negative W isotope signatures in the Onverwacht Group are likely derived from fluids sourced from younger intrusive granitoids Felsic intrusive rocks are a major source of W‐rich fluids in Paleoarchean greenstone unitsAbstract Due to the inherently fluid‐mobile nature of W, the 182 W record of the early Earth may have been obscured by fluid‐induced mobilization of W. To investigate W mobilization in Archean greenstone sequences, we analyzed 182 W isotope systematics and major and trace element concentrations in samples from the 3.53 Ga old Onverwacht Group of the Kaapvaal Craton (South Africa) and the >3.51 Ga old Badampahar Group of the Singhbhum Craton (India). Our results for mafic and ultramafic metavolcanic rocks show W/Th ratios significantly higher than primary magmatic values, which suggests fluid‐induced W enrichment. Samples least affected by secondary W enrichment (W/Th < 0.26) show no resolvable W isotope anomalies from modern mantle values in both cratons. Samples from the Kaapvaal Craton with elevated W/Th exhibit deficits in 182 W as low as −8.1 ± 4.3 ppm compared to the modern mantle. Covariations of μ 182 W with W/Th, and Ce/Pb suggest that negative isotope signatures were introduced during secondary fluid‐mediated processes. The enrichment of W is most evident in altered ultramafic rocks comprising serpentine, resulting in additional covariations between MgO, LOI, and W/Th. The W isotope composition of serpentinized komatiites reflects the composition of younger intruding granitoids. We therefore infer the latter as a possible source of W‐rich fluids. The Badampahar Group samples exhibit little W isotope variability. A well‐resolved 182 W deficit of −6.2 ± 2.9 ppm was determined in a single komatiite sample, which indicates an unknown fluid source, currently not represented in any other unit of the Singhbhum Craton.Plain Language Summary The tungsten (W) isotope composition of ancient rocks can be used to trace processes that occurred during Earth's early evolution. However, interactions between rocks and fluids may alter the W concentration and therefore influence the interpretation of W isotope data. To identify the source of such fluids and the processes by which they affect the W isotope composition of rocks, we analyzed ancient rock samples from South Africa and India. The isotope composition of rocks with a low W concentration reflects that of the modern Earth. Therefore, they do not trace the processes that occurred during Earth's early evolution. Samples from South Africa with untypically high W concentrations show a different isotopic composition. The variation in the W isotope signature correlates with other chemical indices that are susceptible to modification by fluid‐related processes. This shows that the W within the rocks is derived from an external fluid source and not from their original magmatic source. Samples with the highest W enrichment have a similar isotope composition as spatially associated intrusive rocks. By inference, the latter likely represent the source of W‐rich fluids. The samples from India show similar enrichment in W, indicating similar fluid‐related processes and W sources at both localities.Key Points The magmatic sources of metavolcanic rocks from the Onverwacht Group and the Badampahar Group do not exhibit W isotope anomalies Negative W isotope signatures in the Onverwacht Group are likely derived from fluids sourced from younger intrusive granitoids Felsic intrusive rocks are a major source of W‐rich fluids in Paleoarchean greenstone unitsDeutsche Forschungsgemeinschaft https://doi.org/10.13039/501100001659Open-Access-Publikationsfonds 202

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

    Author Index

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    koamabayili/VECTRON-author-checklist: VECTRON author checklist

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    We have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
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