1,721,009 research outputs found
DC Breakdown in gases for complex geometries from high vacuum to atmospheric pressure
This thesis presents an experimental investigation and a numerical simulation of breakdown in a ring assembly. Previous works are mostly limited to breakdown in simple geometries such as parallel plates or pin-to-plate. Here we discuss the effect of more complex geometries for DC breakdown in gases over a large pressure range from high vacuum to atmospheric pressure. The breakdown voltage versus pressure curves shows a similar shape as Paschen curves but with a wide flat plateau between the low and high pressure thresholds. The low pressure threshold determines the limit between gas and vacuum discharges. Additional optical emission spectroscopy confirms the presence of two different kinds of discharges: Gas and vacuum dis- charges. Moreover the global shape of the gas breakdown voltage curve in the ring assembly has been fully understood by a complementary numerical simulation. Fur- ther current-voltage study showed that voltage only is the most significant factor for breakdown and that current determines the kind of discharge after breakdown. As the breakdown voltages are lower for gas discharges than for vacuum discharges, a numerical simulation model for gas breakdown using a fluid model was developed in order to support the experimental conclusions. Starting as simple as possible with par- allel plates (1 mm and 100 mm gap width representing approximatively the shortest and longest electric field path length in the ring assembly geometry) and extending to double gap and multi-gap geometries, an understanding of the overall shape of the breakdown voltage versus pressure curve is established: The high (low) pressure thresholds of gas discharge are determined by the shortest (longest) electric field path length in a complex geometry. Moreover, the availability of multiple path lengths leads to a breakdown voltage minimum over a wide range of intermediate pressure because breakdown can occur in the most favorable gap. Finally, the numerical simulation in the ring assembly shows the importance of parameters such as the secondary electron emission coefficient which play a major role in determining the breakdown voltage value.CRPPSP
Study of radio-frequency plasma deposition of amorphous silicon for the improvement of solar cell production
Plasma enhanced chemical vapour deposition (PECVD) of thin films such as amorphous silicon has widespread applications especially in the field of photovoltaic solar cells and thin-film transistors for flat screen production. Industrial applications require high depositions rates over large areas with a good uniformity in layer thickness. In this thesis, some aspects of PECVD in large surface, industrial type, capacitive radio frequency reactor are investigated. The aim of this work is to study the plasma process conditions to increase the deposition rate of uniform, good quality, a-Si:H layer for solar cell application in a single chamber reactor. The studies realized during this thesis have necessitated the development and the comprehension of diagnostics such as deposition rate measurement by in-situ interferometry, plasma power measurement and layer density measurement by ellipsometry. During the thesis, we have also elaborated a matching-box circuit for using process frequencies of 27.12 MHz and 40.68 MHz. Deposition of a-Si:H in small electrode gap reactor has been studied. At present industrial reactors have a standard electrode gap of 2.4 cm. We modified a reactor to reach a small gap of 1.7 cm. It appears that we have obtained faster deposition rate in the small gap reactor but non-uniformity problems increase due to edge focusing and powder effects. One solution, based on a teflon jigsaw to keep the plasma away from the edge confined spaces, is proposed to suppress focusing effect but the operation parameter space is still reduced by the powder effect. Systematic measurements of a-Si:H layer density was also done by ellipsometry. It is shown that the layer density decreases when the deposition rate increases, independently of pressure, gas flow and frequency (27.12 MHz/40.68 MHz) of the plasma. At high deposition rate, 6 Å/s, only an increase of the process temperature from 200°C to 230°C can significantly improve the layer density. We have noted also a slight improvement of layer density for layers deposited in the small gap reactor. Nevertheless industrial constraints impose a process temperature of 200°C and a standard gap reactor. By optimising the process parameters, keeping the temperature process at 200°C, good quality, uniform, a-Si:H layer were deposited at 3 Å/s on 37 cm × 47 cm glass substrates at 40.68 MHz. A particular source of non-uniformity in large area reactor has been examined. In large area reactors, a perturbation in RF plasma potential, due to the electrode edge asymmetry, propagates towards the plasma center with a characteristic damping length λ. The variation of RF plasma potential at the edge implies a variation of the deposition rate across the reactor area and then a non-uniformity of the deposited layer. A theoretical study was done to understand of this phenomenon and experimental results confirmed the model. Finally, for solar cell applications, a study of the boron cross-contamination during solar cell deposition in a single chamber process has been done. During the deposition of the intrinsic layer, for a p-i-n cell, i-layer is contaminated by the residual boron radicals present in the reactor after the deposition of the boron-doped layer. This contamination decreases cell performance. Several reactor treatments have been tested to solve this contamination problem. The effectiveness of these treatments was evaluated by secondary ion mass microscopy (SIMS) measurements. It appears that an ammonia flush or a water vapour flush of a few minutes, between the deposition of the p-layer and i-layer, reduces the boron contamination at the p-i interface. The performance of cells made with these treatments, in a single chamber process, are comparable to performance of cells done in a multi-chamber process.CRPPSP
A Grid Reactor with Low Ion Bombardment Energy for Large Area PECVD of Thin Film Silicon Solar Cells
CRPPSP
Negative Hydrogen Ions in a Helicon Plasma Source
There is nowadays a large interest to employ helicon plasmas as sources of negative ions for Neutral Beam Injectors (NBIs). Helicon plasma sources offer a number of advantages compared to current Inductive Couple Plasma (ICP) negative ions source, such as high energy efficiency, high plasma density production, low electron temperature and a considerable amount of H- and D- produced through volumetric processes, without caesium. Therefore, helicon plasma sources are promising candidates to be employed as a negative ion source for future NBIs, such as in DEMO, a next generation tokamak closer to commercial devices. However, many physics and technical aspects of helicon plasmas have to be deeply investigated, before their possible integration in future NBIs. The goal of this thesis is to advance the understanding of the physics of helicon-based negative ion sources in the helicon plasma source RAID (Resonant Antenna Ion Device) at the Swiss Plasma Center of Ecole Polytéchnique Fédérale de Lausanne, Switzerland. The investigations are carried out by employing a variety of plasma diagnostics, and the results are interpreted and compared to numerical models.SP
Going Beyond Counting First Authors in Author Co-citation Analysis
The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Arcing in Very Large Area Plasma-Enhanced Chemical Vapour Deposition Reactors
This thesis presents an investigation into arcing and parasitic plasmas in large area plasma enhanced chemical vapour deposition reactors. Two types were investigated: RF breakdown in millimetric gaps in absence of plasma (e.g. dark space shielding), in a millibar pressure range, and RF hollow cathodes in glow discharges. RF breakdown curves (voltage vs. pressure) for parallel plate electrodes generally show a steep left-hand branch at low pressures and a flatter right hand branch at higher pressures. Introducing protrusions or holes in parallel plate electrodes will lower the breakdown voltage in certain conditions. This is, however, not due to the increased electric field at sharp edges or ridges. Instead, both experiments and simulation show that breakdown at high pressure will occur at the protrusion providing the smallest gap, while breakdown at low pressure will occur in the aperture providing the largest gap. This holds true as long as the feature in question is wide enough: Features that are too narrow will lose too many electrons due to diffusion, either to the walls of the apertures or to the surroundings of the protrusion, which negates the effect on the breakdown voltage. An analytical approximation of breakdown in parallel plates with cylindrical protrusions supports this argument. The simulation developed to study breakdown in structured parallel plate electrodes also presents a tool to aid the design of complex RF parts for dark-space shielding. A method was developed to measure the pressure-limits of ignition for RF hollow cathodes, and it could be shown that these limits not only depend on gas type, diameter and depth of the hollow cathode, but also on the presence and/or absence of other hollow cathodes in the vicinity. It could also be conclusively shown that hollow cathodes damage the electrode by sputtering and/or evaporation.CRPPSP
Variations on the Author
“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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