1,720,974 research outputs found

    Rekonstruktion von Metamorphosepfaden mit stabilen Isotopen : Möglichkeiten der Laserfluorinierung am Beispiel des Sächsischen Granulitgebirges

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    Diese Arbeit beschäftigt sich mit der Analyse von Sauerstoffisotopen und der Auswertung und Interpretation der bestimmten Gleich- bzw. Ungleichgewichte. Ein wesentlicher Schwerpunkt der Arbeit liegt auf der Bestimmung von peaknahen Metamorphosetemperaturen. Es wird eine Methode angewendet, die es ermöglicht, aus den Fraktionierungskoeffizienten des Gesamtgesteins und mindestens einer Phase, die für Sauerstoff eine hohe Schließtemperatur hat, solche peakmetamorphen Temperaturen zu ermitteln. Dies geschieht mit Hilfe von Fraktionierungs-Plots, bei denen die Fraktionierungskoeffizienten aller Phasen und vom Gesamtgestein gegen den gemessenen d18O-Wert aufgetragen werden. Im Falle eines Gleichgewichts befinden sich alle Phasen auf einer Geraden. Aus der Steigung der Geraden können für die hier untersuchten Granulite des Sächsischen Granulitgebirges Temperaturen der granulitfaziellen Metamorphose von über 1000°C nachgewiesen werden. Allerdings kommt es in den meisten Gesteinen durch retrograde Diffusion zu einer partiellen Rücksetzung der Isotopengleichgewichte. Aus diesen Ungleichgewichten wurden im Rahmen dieser Arbeit Abkühlraten für die Granulite und für einen Granatgneis des Kordieritgneis-Komplexes iterativ berechnet. Die Abkühlraten liegen zwischen 50 und 80 °C/Ma für die Granulite. Die hier erzielten Ergebnisse werden durch unabhängige Methoden bestätigt. Mit diesen Daten kann ein Beitrag zur Klärung der thermischen Entwicklung und der Hebungsgeschichte eines kontinentalen Krustensegmentes geleistet werden. Es kann gezeigt werden, dass die Granulite einem fast isothermalen Dekompressionspfad folgen. Die für diese Untersuchungen verwendete analytische Methode ist die der Laserfluorinierung in Kombination mit irm-Massenspektrometrie. Zum einen wurden die Untersuchungen an Mineralseparaten, zum anderen wurden In-Situ-Analysen an etwa 2 mm dicken Gesteinsstücken oder großen Einzelkörnern durchgeführt. Daraus ergibt sich ein weiterer Schwerpunkt dieser Arbeit, der sich mit der Weiterentwicklung der Methode der Laserfluorinierung beschäftigt hat. Es ging um die Eliminierung störender Einflüsse, Reduktion der Probenmengen und eine Verbesserung der Reproduzierbarkeit von Analysen. Die In-Situ Analysen dienten zur Untersuchung der O-Isotopen Homogenität der Proben und im Fall eines Granatperidotits zur Klärung der Herkunft des Gesteins. So konnte für die Granulite eindeutig eine homogene O-Isotopen-Verteilung für Granat nachgewiesen werden, wohingegen für einen Granatgneis des aufgelagerten Cordieritgneis-Komplexes starke Inhomogenitäten, teilweise sogar innerhalb eines Korns, nachgewiesen wurden. Die Untersuchungen großer, einzelner Granate aus einem zwischengelagerten Peridotit belegen eine Mantelisotopie

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Reconstruction of sedimentary environment and climate conditions by multi-geochemical investigations of Late Palaeozoic glacial to postglacial sedimentary sequences from SW-Gondwana

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    The most extensive Phanerozoic glaciation and its termination occurred during the Carboniferous-Permian on the southern hemispherical Gondwana supercontinent. This thesis aims to provide detailed geochemical analyses of the lower Karoo Supergroup sediments in southwestern Gondwana with focus on the Karoo Basin in South Africa. Additional samples derive from the Paraná Basin (Brazil), Kalahari Basin (Botswana), and Warmbad Basin (Namibia). Multiple geochemical investigations (element-geochemical, organic-geochemical and isotope data) were supported by mineralogical data. By this multi proxy approach, information about sedimentary environment, climate conditions, and postsedimentary processes can be obtained. orbital frequencyElement geochemical proxies (CIA, Zr/Ti, Rb/K, V/Cr) record three confined shifts in climate and paleoenvironment of the Karoo Basin during deposition of the glacial Dwyka Group. These shifts were induced by changes in sea level, weathering rate, provenance, and redox conditions. Organic geochemical investigations (Corg, C/N, lipid biomarkers) indicate the organic matter in the central Karoo Basin was primarily of algal origin. In agreement with element proxies, the varying δ13Corg, values mirror shifts in pCO2, rather than variations of organic-matter type. A covariation trend between carbon isotope signatures of equatorial carbonates and δ13Corg, values from the Karoo Basin argues against local forcing factors and instead implies a global climate-control mechanism. The 5-7 m.y. duration of a complete glacial cycle is not in tune with any known orbital frequency. The onset of the postglacial phase (Ecca Group) is characterized by significant changes in sedimentary environments. Predominantly fully marine conditions prevailed and the formation of anoxic conditions is indicated by the occurrence of Corg, rich sediments containing mineral phases such as apatite and pyrite. Comparable proxy signals are obtained from localities within the Karoo Basin and from the Warmbad Basin in Namibia. Especially the accumulation of phosphatic sediments points to high bioproductivity due to elevated nutrient supply. At the basin borders (Witbank Basin), in terrestrially dominated sedimentary environments, the onset of postglacial climate conditions was recorded by significant changes in the organic matter composition. The Dwyka/Ecca boundary coincides with a progressional temperature rise. Favourable climate conditions led to the spread of the Glossopteris flora. High chemical weathering rates, assumedly fast growing vegetation and the documented reptile fauna (Mesosaurus), indicate warm-humid climate conditions during the Early to Middle Permian in south Gondwana. During the Middle to Late Permian the continuous retreat of former marine sedimentary environments commences. Turbiditic deposits were replaced by deltaic basin fills, which were in tune covered by fluvial and lacustrine sediments. The retreat of marine conditions in the Karoo Basin was closely related to the rising Cape Fold Belt, whereby the connection to the Panthalassic Ocean was finally terminated. Arid climate conditions during the Late Permian and Lower Triassic are indicated by redbeds and aeolian deposits of the upper Beaufort and Stormberg/Lebung Groups

    Trace element and isotopic (Sr, Nd, Pb, O) arguments for a mid-crustal origin of Pan-African garnet-bearing S-type granites from the Damara orogen (Namibia)

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    Geochronological data, major and trace element abundances, Nd and Sr isotope ratios, δ18O whole rock values and Pb isotope ratios from leached feldspars are presented for garnet-bearing granites (locality at Oetmoed and outcrop 10 km north of Omaruru) from the Damara Belt (Namibia). For the granites from outcrop 10 km N′ Omaruru, reversely discordant U–Pb monazite data give 207Pb/235U ages of 511±2 Ma and 517±2 Ma, similar to previously published estimates for the time of regional high grade metamorphism in the Central Zone. Based on textural and compositional variations, garnets from these granites are inferred to be refractory residues from partial melting in the deep crust. Because P–T estimates from these xenocrystic garnets are significantly higher (800°C/9–10 kbar) than regional estimates (700°C/5 kbar), the monazite ages are interpreted to date the peak of regional metamorphism in the source of the granites. Sm–Nd garnet–whole rock ages are between ∼500 and ∼490 Ma indicating the age of extraction of the granites from their deep crustal sources. For the granites from Oetmoed, both Sm–Nd and Pb–Pb ages obtained on igneous garnets range from ∼500 to ∼490 Ma. These ages are interpreted as emplacement ages and are significantly younger than the previously proposed age of ∼520 Ma for these granites based on Rb/Sr whole rock age determinations. Major and trace element compositions indicate that the granites are moderately to strongly peraluminous S-type granites. High initial 87Sr/86Sr ratios (>0.716), high δ18O values of >13.8‰, negative initial εNd values between −4 and −7 and evolved Pb isotope ratios indicate formation of the granites by anatexis of mid-crustal rocks similar to the exposed metapelites into which they intruded. The large range of Pb isotope ratios and the lack of correlation between Pb isotope ratios and Nd and Sr isotope ratios indicate heterogeneity of the involved crustal rocks. Evidence for the involvement of isotopically highly evolved lower crust is scarce and the influence of a depleted mantle component is unlikely. The crustal heating events that produced these granites might have been caused by crustal thickening and thrusting of crustal sheets enriched in heat-producing elements. Very limited fluxing of volatiles from underthrust low- to medium-grade metasedimentary rocks may have also been a factor in promoting partial melting. Furthermore, delamination of the lithospheric mantle and uprise of hot mantle could have caused localized high-T regions. The presence of coeval A-type granites at Oetmoed that have been derived at least in part from a mantle source supports this model

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
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