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Palazzo Bo, i nuovi istituti lungo via Cesare Battisti prima della sopraelevazione
No full textSupporto: Positivo b/n
Retro: 3 mar 1927, timbro; Fig 19. Nuova ala del Palazzo universitario su via Cesare Battisti (architetto G. Fondelli 1922): istituti giuridici, dattiloscritto su carta incollata; timbro Gislon e timbro a secco
Note: Istituti Giuridici via Cesare Battisti; 1927.3.3; Gislon
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Siloxanes removal from biogas by high surface area adsorbents
No full textBiogas utilized for energy production needs to be free from organic silicon compounds, as their burning has damaging effects on turbines and engines; organic silicon compounds in the form of siloxanes can be found in biogas produced from urban wastes, due to their massive industrial use in synthetic product, such as cosmetics, detergents and paints. Siloxanes removal from biogas can be carried out by various methods (Mona, 2009; Ajhar et al., 2010 May; Schweigkofler and Niessner, 2001); aim of the present work is to find a single practical and economic way to drastically and simultaneously reduce both the hydrogen sulphide and the siloxanes concentration to less than 1ppm. Some commercial activated carbons previously selected (Monteleone et al., 2011) as being effective in hydrogen sulfide up taking have been tested in an adsorption measurement apparatus, by flowing the most volatile siloxane (hexamethyldisiloxane or L2) in a nitrogen stream, typically 100-200ppm L2 over N2, through an activated carbon powder bed; the adsorption process was analyzed by varying some experimental parameters (concentration, grain size, bed height). The best activated carbon shows an adsorption capacity of 0.1g L2 per gram of carbon. The next thermogravimetric analysis (TGA) confirms the capacity data obtained experimentally by the breakthrough curve tests. The capacity results depend on L2 concentration. A regenerative carbon process is then carried out by heating the carbon bed up to 200. °C and flushing out the adsorbed L2 samples in a nitrogen stream in a three step heating procedure up to 200. °C. The adsorption capacity is observed to degrade after cycling the samples through several adsorption-desorption cycles. © 2013 Elsevier Ltd
GREENHOUSE GAS EMISSIONS RELATED TO MILK PRODUCTION OF DAIRY COWS
No full textWith global emissions estimated at 7.1 Gt CO2 eq per annum, livestock represents 14.5% of all human-induced emissions and it is considered to be the largest source of greenhouse gas (GHG) emissions from the agricultural sector. However, livestock can contribute to convert nutrients from plant biomass into animal-sourced foods, which are rich in essential macro and micronutrients in the form of milk and meat, thereby utilizing resources that cannot otherwise be consumed by humans. Livestock also contributes to global food security and poverty reduction, providing regular income to producers. To achieve a sustainable supply of animal origin food, farmers need, therefore, to identify strategies, in terms of livestock management and feeding, forage systems and feed growing practices, that make the best use of available resources and minimize the potential environmental impact. The studies of the PhD thesis were mainly developed inside the Life project “Forage4Climate”, a four years project, aimed at demonstrating that forage systems connected to milk production can promote climate change mitigation. The aim of the PhD thesis was the evaluation of GHG emission, related to dairy cattle milk production. Specific aims were: • to identify and evaluate the most common forage systems adopted in dairy cow farms in the Po plain, selecting the systems that can improve milk production and soil carbon (C) sequestration reducing emissions per kg of milk; • to evaluate commercial diets related to these different forage systems, in order to directly assess their digestibility, milk and methane (CH4) production; • to identify, through a survey analysis, the main ingredients used in the total mixed ration (TMR) of high producing lactating cows, in order to assess the best diet composition that can lead to high feed efficiency (FE) and low global warming potential (GWP) at commercial farms scale; • in a future perspective of circular economy, to study the exploitation of different inedible human by-products as growing substrates for Hermetia Illucens larvae, in order to substitute soybean meal (SBM) in the livestock diets with insect proteins. A total of 46 dairy cattle farms in Lombardy, Piedmont and Emilia-Romagna were visited, in order to map the main forage systems adopted in each area and to characterize them for GHG emission related to milk production (FPCM, fat and protein corrected milk), and soil organic C stock. The evaluation of environmental impact, in terms of GWP, related to the different forage systems was carried out though a Life Cycle Assessment (LCA) method, using the Software SIMAPRO. Six forage systems based on different forages were identified. The main results in terms of GHG per unit milk were: - CONV - Conventional corn silage system: 1.37 kg CO2 eq/kg FPCM (SD 0.26) - HQFS - High quality forage system: 1.18 kg CO2 eq/kg FPCM (SD 0.13) - WICE - Winter cereal silage system: 1.44 kg CO2 eq/kg FPCM (SD 0.43) - MIXED - Mixed less intensive system: 1.36 kg CO2 eq/kg FPCM (SD 0.26) - PR FRESH- Hay and fresh forage system for Parmigiano Reggiano PDO cheese production: 1.51 kg CO2 eq/kg FPCM (SD 0.23) - PR DRY- Hay system for Parmigiano Reggiano PDO cheese production: 1.36 kg CO2 eq/kg FPCM (SD 0.19). The HQFS system registered the lowest value for GWP, mainly due to the higher milk production per cow (daily FPCM/head). More intensive systems, such as HQFS, confirmed that milk production per cow is negatively related to the impact per kilogram of product, as highlighted also by a PROC GLM analysis. The HQFS system also resulted to be more sustainable, in terms of feed self-sufficiency, as it provided a high amount of dry matter (DM) per hectare, consisting of high digestible forages. Despite the lowest value for GWP, the forage system identified as HQFS showed the lowest organic C soil density: 5.6 kg/m2 (SD 1.1). On the contrary, PR FRESH showed the highest value in terms of organic C density in the soil: 9.7 kg/m2 (SD 2.2), compared with an average of 6.7 kg/m2 (SD 0.88) for the other systems. Further investigations are needed to consider environmental sustainability over a wider spectrum. Enteric CH4 was the main contributor to GWP for all forage systems: on average 45.6% (SD 3.89). For this reason, an in vivo evaluation of CH4 and milk production of lactating dairy cows fed four different diets, obtained from the forage systems identified, was performed. Also digestibility of the diets, energy and nitrogen (N) balance were assessed. Four pairs of Italian Friesian lactating cows were used in a repeated Latin Square design, using individual open circuit respiration chambers to determine dry matter intake (DMI), milk production and CH4 emission and to allow total faeces and urine collection for the determination of N and energy balances. Four diets, based on the following main forages, were tested: corn silage (49.3% DM; CS), alfalfa silage (26.8% DM; AS), wheat silage (20.0% DM; WS), hay-based diet (25.3% DM of both alfalfa and Italian ryegrass hays; PR) typical of the area of Parmigiano Reggiano cheese production. Feeding cows with PR diet significantly increased DMI (23.4 kg/d; P=0.006), compared with the others (on average, 20.7 kg/d), while this diet resulted to be the least digestible (e.g. DM digestibility=64.9 vs 71.7% of the other diets, on average). This is probably the reason why, despite higher DMI of cows fed PR diet, the animals did not show higher production, both in terms of milk (kg/d) and energy corrected milk (ECM; kg/d), compared with the other treatments. The urea N concentration was higher in milk of cows fed WS diet (13.8) and lower for cows fed AS diet (9.24). This was also correlated to the highest urinary N excretion (g/d) for cows fed WS diet (189.5 vs 147.0 on average for the other diets). The protein digestibility was higher for cows fed CS and WS diets (on average 68.5%) than for cows fed AS and PR (on average 57.0%); the dietary soybean inclusion was higher for CS and WS than AS and PR. The higher values for aNDFom digestibility were obtained for CS (50.7%) and AS (47.4%) diets. The rumen fermentation pattern was affected by diet; in particular PR diet, characterized by a lower content of NFC and a higher content of aNDFom as compared to CS diet, determined a higher rumen pH and decreased propionate production as compared to CS. Feeding cows with PR diet increased the acetate:propionate ratio in comparison with CS (3.30 vs 2.44 for PR and CS, respectively). Ruminal environment characteristics (i.e higher pH and higher acetate: propionate ratio), together with increased DMI, led cows fed PR DRY diet to have greater (P=0.046) daily production of CH4 (413.4 g/d), compared to those fed CONV diet (378.2 g/d). However, no differences were observed when CH4 was expressed as g/kg DMI or g/kg milk. Hay based diet (PR) was characterized by the lowest digestible and metabolizable energy contents which overall determined a lower NEL content for PR than CS diet (1.36 vs 1.70 Mcal/kg DM respectively for PR and CS diets). In order to meet the high demand of nutrients needed to assure high milk production, in addition to fodder a lot of concentrates are also used in dairy cows’ TMR. A survey analysis conducted in commercial farms was performed to evaluate the GWP of different lactating cow TMR and to identify the best dietary strategies to increase the FE and to reduce the enteric CH4 emission. A total of 171 dairy herds were selected: data about DMI, lactating cows TMR composition, milk production and composition were provided by farmers. Diet GWP (kg CO2 eq) was calculated as sum of GWP of each ingredient considering inputs needed at field level, feed processing and transport. For SBM, land use change was included in the assessment. Enteric CH4 production (g/d) was estimated using the equation of Hristov et al. (2013) in order to calculate CH4 emission for kg of FPCM. The dataset was analysed by GLM and logistic analysis using SAS 9.4. The results of frequency distribution showed that there was a wide variation among farms for the GWP of TMR: approximately 25% of the surveyed farms showed a diet GWP of 15 kg CO2 eq, 20% of 13 kg CO2 eq and 16.7% of 17 kg CO2 eq. The variation among farms is due to the feed used. Among feed, SBM had the highest correlation with the GWP of the TMR with the following equation: TMR GWP (kg CO2 eq) = 2.49*kg SBM + 6.9 (r2=0.547). Moreover, an inclusion of SBM >15% of diet DM did not result in higher milk production with respect to a lower inclusion (≤15%). Average daily milk production of cows was 29.8 (SD 4.83) kg with a fat and protein content (%) of 3.86 (SD 0.22) and 3.40 (SD 0.14), respectively. The average value of DMI (kg/d) of lactating cows was 22.3 (SD 2.23). The logistic analysis demonstrated that a level of corn silage ≤ 30% on diet DM was associated with higher FE. Almost 50% percent of the farms had an average value of 15.0 g CH4/kg FPCM and about 30% a value of 12.5 g CH4/kg FPCM. The results demonstrated that a lower enteric CH4 production was related to inclusion (% on diet DM) of less than 12% of alfalfa hay and more than 30% of corn silage. Diets with more than 34% of NDF determined higher CH4 production (≥14.0 g/kg FPCM) compared with diets with lower NDF content. On the contrary, a lower enteric CH4 production (<14.0 g/kg FPCM) was related to diets characterized by more than 1.61 NEl (Mcal/kg) and more than 4% of ether extract. The variability in the GWP of TMR shows a significant potential to reduce both the GWP of the diet through a correct choice and inclusion level in the ration of the ingredients (mainly SBM) and the possibility to decrease CH4 enteric emission associated to milk production. Looking forward, in order to evaluate the opportunity of alternative protein sources in the cow diet, to reduce SBM, waste production, and competition between animals and human for crops, a study on the effects of different by-products for Hermetia illucens rearing on the chemical composition of larvae and their environmental impact was conducted, even if, according to the European legislation, today the use of insects as feed source is not possible in ruminants. Regarding climate change, okara and brewer’s grains were the most promising substrates: 0.197 and 0.228 kg CO2 eq/kg of larvae fresh weight, respectively. Results from these studies show the importance of adopting a holistic approach for the assessment of GHG emission from milk production. Therefore, any strategy aimed at mitigating CH4 emission of dairy cows must also take into account the possible effect on the other GHGs, as well as the effect on C sequestration. Based on the studies, it could also be worth evaluating novel feed as a new and useful solution for mitigation of GHG emission related to milk production. The thesis highlights essential differences among forage systems and among feed ingredients of cow ration, confirming that there is room for improvement in sustainability of milk production. These issues should be taken into consideration by farmers, technicians and policy makers, considering that sustainability of livestock production will be one of the priorities for humankind in next future
ASYMMETRIC-SYNTHESIS OF TRANS-BETA-LACTAMS THROUGH TICL4-MEDIATED ADDITION TO IMINES
No full textTiCl4-mediated addition of the chiral silyl ketene acetal (2) to benzylideneaniline proceeds with high stereoselectivity to give, after cyclization, trans- β -lactam (7) in good yield and 95% e.e
Looking for high-production and sustainable diets for lactating cows : A survey in Italy
No full textThe aim of the present study was to evaluate, through a survey conducted on commercial farms, the global warming potential (GWP) of different lactating cow total mixed rations (TMR) and to identify the best dietary strategies to increase feed efficiency (FE) and reduce enteric CH4 emission. A total of 171 dairy herds were selected: data about dry matter intake (DMI), lactating cow TMR composition, and milk production and composition were provided by farmers. Diet GWP (kg of CO2 equivalents; CO2eq) was calculated as sum of GWP (kg of CO2eq) of each included ingredient, considering inputs needed at field level, feed processing, and transport. For soybean solvent meal, land use change was included in the assessment. Enteric methane production (g/d) was estimated [using the equation CH4 (g/d) = 2.54 + 19.14 × DMI] to calculate CH4 emission for kilograms of fat- and protein-corrected milk (FPCM). The data set was analyzed by generalized linear model and logistic analysis using SAS 9.4 (SAS Institute Inc., Cary, NC). The frequency distribution showed wide variation among farms for GWP (kg of CO2eq) of TMR: approximately 25% of the surveyed farms showed a diet GWP of 15 kg of CO2eq, 20% showed a GWP of 13 kg of CO2eq, and 16.7% showed a GWP of 17 kg of CO2eq. The variation among farms was due to the feedstuffs used. Among feedstuffs, soybean meal (SBM) had the highest correlation with the GWP of the TMR as shown by the following equation: TMR GWP (kg of CO2eq) = 2.49 × kg of SBM + 6.9 (R2 = 0.547). Moreover, diets with inclusion of SBM >15% of dry matter (DM) did not result in higher milk production than diets with a lower inclusion of SBM (≤15%). Average daily milk production of cows was 29.8 [standard deviation (SD) 4.83] kg with fat and protein contents of 3.86% (SD 0.22) and 3.40% (SD 0.14), respectively. The average DMI (kg/d) of lactating cows was 22.3 (SD 2.23). Logistic analysis demonstrated that corn silage ≤30% of diet DM was associated with higher FE. Almost 50% of farms had an average value of 15.0 g of CH4/kg of FPCM and about 30% of farms had an average of 12.5 g of CH4/kg of FPCM. The results demonstrated that lower enteric CH4 production was related to inclusion (% of diet DM) of ≤12% alfalfa hay and >30% corn silage. Diets with >34% neutral detergent fiber had higher CH4 production (>14.0 g/kg of FPCM) than those with lower neutral detergent fiber content. In contrast, lower enteric CH4 production (≤14.0 g/kg of FPCM) was related to diets characterized by net energy of lactation (NEL) >1.61 Mcal/kg and >4% ether extract. The variability in TMR GWP shows significant potential for reducing the GWP of a diet through choice and inclusion levels of ingredients (mainly SBM) and the possibility of decreasing methane enteric emission associated with milk production on a commercial scale
Diet supplementation with canola meal improves milk production, reduces enteric methane emissions, and shifts nitrogen excretion from urine to feces in dairy cows
No full textThe objective of this study was to examine the effect of isonitrogenous substitution of solvent-extracted soybean meal (SBM) with solvent-extracted canola meal (CM) on enteric CH4 production, ruminal fermentation characteristics (including protozoa), digestion (in situ and apparent total-tract digestibility), N excretion, and milk production of dairy cows. For this purpose, 16 lactating Holstein cows, of which 12 were ruminally cannulated, were used in a replicated 4 × 4 Latin square (35-d periods; 14-d adaptation). The cows averaged (mean ± SD) 116 ± 23 d in milk, 692 ± 60 kg of body weight, and 47.5 ± 4.9 kg/d of milk production. The experimental treatments were control diet (no CM; 0%CM) and diets supplemented [dry matter (DM) basis] with 7.9% CM (8%CM), 15.8% CM (16%CM), or 23.7% CM (24%CM) on a DM basis. The forage:concentrate ratio was 52:48 (DM basis) and was similar among the experimental diets. Canola meal was included in the diet at the expense of SBM and soybean hulls, whereas the percentages of the other diet ingredients were the same. Intake of DM increased linearly, whereas apparent total-tract digestibility of DM, crude protein, neutral detergent fiber, and gross energy (GE) declined linearly as CM inclusion in the diet increased. Total volatile fatty acids concentration and butyrate molar proportion decreased linearly, whereas molar proportion of propionate increased linearly, and that of acetate was unaffected by CM inclusion in the diet. Ruminal ammonia concentration was not affected by inclusion of CM in the diet. Energy-corrected milk (ECM) yield increased linearly (up to 2.2 kg/d) with increasing CM percentage in the diet, whereas milk production efficiency averaged 1.63 kg of ECM/kg of DM intake and was unaffected by CM inclusion in the diet. Daily CH4 production decreased linearly with increasing CM percentage in the diet (489, 475, 463, and 461 g/d for 0%CM, 8%CM, 16%CM and 24%CM diets, respectively). As a consequence, CH4 emission intensity (g of CH4/kg of ECM) also declined linearly by up to 10% as the amount of CM increased in the diet. Methane production also decreased linearly when expressed relative to GE intake (5.7, 5.2, 5.1, and 4.9% for 0%CM, 8%CM, 16%CM and 24%CM diet, respectively). Quantity of manure N excretion was not affected by replacing SBM with CM; however, N excretion shifted from urine to feces as dietary percentage of CM increased, suggesting reduced potential for N volatilization. Results from this study show that replacing SBM with CM as a protein source in dairy cow diets reduced enteric CH4 emissions (g/d, % of GE intake, and adjusted for milk production) and increased milk production. The study indicates that CM can successfully, partially or fully, replace SBM in lactating dairy cow diets, with positive effects on animal productivity and the environment (i.e., less enteric CH4 emission and urinary N excreted). We conclude that compared with SBM, inclusion of CM meal in dairy cow diets can play a key role in reducing the environmental footprint of milk production
Use of active carbon for the removal of sulphur impurities from a biogas stream for SOFC application
No full textAn interesting application of solid oxide fuel cell (SOFC) technology is the micro-cogeneration (μ-CHP) in the residential area fed with a sustainable (renewable) source such as biogas produced from anaerobic digestion (AD) of organic waste. Even though the major components of biogas are CH4 and CO2, several contaminants can be inside the biogas and have to be removed before entering the cell. Sulphur compounds are the most harmful for SOFC systems. The aim of this work is to study the removal of sulphur compounds using activated carbon adsorption trapping and test the obtained results in a SOFC single cell. Two different carbon filters were tested under the following sulphur contaminants: H2S, THT, COS, DMS and single cells were performed with a simulated biogas enriched with a selected small amounts of the contaminants in order to evaluate tolerance and degradation process
Nitrogen farm balance and efficiency in mountain dairy farms
No full textThe study showed poor sustainability characteristics of dairy farming systems in the considered Lombardy mountain area, particularly in terms of low feed self-sufficiency, high stocking density and, in a number of cases, high farm N balance
Milk quality and milking practices in dairy goat farms in Lombardy
No full textAim of this work was to study the relationship between goat milk quality and milking management practices. The study was conducted on 148 dairy goat farms in Lombardy (Italy), with particular focus on milk somatic cell count (SCC) and milk fat/protein reversion syndrome. Direct interviews to the farmers were collected. Monthly bulk milk analyses in 1 year (fat, protein, casein and lactose percentages, somatic cell and standard plate count) were used for quality evaluation of goat milk. Individual milk production was on average 1.26 ± 0.44 kg/d, collected during 1.94 ± 0.18 milkings a day. Average number of dairy goats was 74.3 ± 95.8; most of farms reared Alpine goats (38%), 36.5% Saanen, 16.3% Alpine and Saanen, and 9.2% local breeds. Milk quality was quite good (3.52 ± 0.73%
fat, 3.40 ± 0.46% protein, 2.62 ± 0.40% casein). Milking was performed on bedded area in 13.8% of farms, inside the barn in 53.6% and in a separate milking room in 32.6%. A multiple correspondence analysis was performed and high correlations were found (the first two dimensions explained 31.5% of variance) among farms characterized by local breeds, small size (70 dairy goats), presence of official milk recording, milking inside the barn (but out of bedded area) or in a separate room, udder cleaning before milking, forestripping, teat post-dipping and use of gloves by milkers. A second multiple correspondence analysis was performed and high correlations were found among farms characterized by local breeds, low milk fat (70 dairy goats), high milk fat content, no milk fat/protein reversion syndrome and milk delivered to dairies, probably due to a special care in ration formulation and attention to milk quality. The study demonstrates the importance of milking and farming strategies to improve goat milk quality
Effect of vacuum level on milk flow and vacuum stability in Alpine goat milking
No full textMilking routine and settings of milking machine are crucial factors in influencing milk production, milking labour and teat condition. The aim of the study was to evaluate if different vacuum levels applied during goat milking can affect milk emission, vacuum stability, and teat measurements. At the university experimental farm, 29 Alpine dairy goats were milked once a day testing three different milking vacuum levels (30, 36 and 42 kPa). The study was divided in 4 periods during lactation, 3 weeks each, changing milking vacuum every week. Milk flow measurements were performed using Lactocorder devices (about 700 observations), while, to verify vacuum stability, Vadia devices were used collecting a total of 220 vacuum curves. Teat dimensions before and after milking were measured once a week. Classification of teat shapes was based on the ratio between diameter and length before milking. Milk flow curves were influenced by milking vacuum level. The highest values of peak and average milk flow were recorded using the highest vacuum level. Vacuum level affected the percentage of milk emitted in the first three minutes of milking; in particular, using the highest milking vacuum level, 92.5% of milk was released in the first three minutes. No differences were found in total milk production and milk somatic cell count using different vacuum levels. Both vacuum level at the short milk tube and vacuum level at mouthpiece chamber were significantly influenced by system vacuum level: as the system vacuum level raised, the first parameter increased while the second decreased. The percentage of curves characterized by irregular vacuum fluctuations, calculated as difference between maximum and minimum vacuum level (kPa) measured in the short milk tube during the main milking phase, was not different among vacuum levels (P = 0.562). Milk flow decreased from the first to the last period of trial, as lactation advanced, by 36.8%; 22.7%; 17.3% for 30, 36 and 42 kPa, respectively; this result impacts on milking performances in terms of duration of milking time and of the time in which teat is under vacuum force. The highest and lowest vacuum levels tested (42 and 30 kPa) caused more evident changes in teat dimensions pre and post milking in comparison with medium vacuum (36 kPa). Moreover, teat shape significantly influenced vacuum at the teat-end. In conclusion, medium vacuum level of 36 kPa seems to be less stressful for teat tissue and more efficient in terms of milking performances than the extreme vacuum levels
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