1,720,989 research outputs found
A logical characterization of coherence for imprecise probabilities
No full textWhilst supported by compelling arguments, the representation of uncertainty by means of (subjective) probability does not enjoy a unanimous consensus. A substantial part of the relevant criticisms point to its alleged inadequacy for representing ignorance as opposed to uncertainty. The purpose of this paper is to show how a strong justification for taking belief as probability, namely the Dutch Book argument, can be extended naturally so as to provide a logical characterization of coherence for imprecise probability, a framework which is widely believed to accommodate some fundamental features of reasoning under ignorance. The appropriate logic for our purposes is an algebraizable logic whose equivalent algebraic semantics is a variety of MV-algebras with an additional internal unary operation representing upper probability (these algebras will be called UMV-algebras)
Integrated electrochemical approach for the investigation of silane pre-treatments for painting copper
No full textCopper surfaces are sometimes protected with an organic coating to improve the durability or the aesthetic properties. Examples of industrial applications are household appliances and heat exchanger components.
In order to extend the service life of the organic coated copper a specific surface pre-treatment is often required. Nevertheless, probably because of the limited market of this application, no specific pre-treatments for copper are industrially developed, with the exception of cleaning procedures, but simply extensions of existing pre-treatments optimised for other metals (aluminium, zinc, magnesium alloys) are used.
The application of silane pre-treatments as adhesion promoters for organic coated metals is remarkably increasing in the last decade, because silanes offer very good performance together with high environmental compatibility.
The idea is therefore to try to develop a specific silane based pre-treatment for copper. The starting point is the existing silane products for aluminium, modifying the composition and the application conditions (concentration, pH of the bath, additives, etc.) in order to develop a high performance copper alloy pretreatment increasing the protective properties and the adhesion of a successively applied organic coating.
The deposits were analysed using FT-IR spectroscopy and optical and electron microscopic observations.
A electrochemical characterization was carried out to highlight the silane properties and to evaluate the performance of the different deposits.
A final powder coating was applied and the properties of the complete protecting cycle was evaluated.
The electrochemical approach is based mainly on electrochemical impedance spectroscopy measurement
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Effect of nitrogen plasma treatment on the crystallinity and self‐bonding of polyetheretherketone (PEEK) for biomedical applications
No full textPolyetheretherketone (PEEK) is a thermoplastic material with outstanding properties and high potential for biomedical applications, including hermetic encapsulation of active implantable devices. Different biomedical grade PEEK films with initial degree of crystallinity ranging from 8% to 32% (with or without mineral filling) were inspected. PEEK surfaces were treated with nitrogen RF plasma and the effects on materials crystallinity and self‐bonding were evaluated. In particular, the relationship between auto‐adhesive properties and crystalline content of PEEK before and after plasma treatment was examined.
PEEK samples showed different bonding strength depending on their degree of crystallinity, with higher self‐bonding performance of mineral‐filled semi‐crystalline films. XRD did not show any modification of the PEEK microstructure as a result of plasma treatment, excluding a significant influence of crystallinity on the self‐bonding mechanisms. Nevertheless, plasma surface treatment successfully improved the self‐bonding strength of all the PEEK films tested, with larger increase in the case of semi‐crystalline unfilled materials. This could be interpreted to the increase in chain mobility that led to interfacial interpenetration of the amorphous phase
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Self-healing epoxy coatings with microencapsulated ionic PDMS oligomers for corrosion protection based on supramolecular acid-base interactions
Full text linkTo obtain a self-healing coating and improve the corrosion resistance of coated low-carbon steel surfaces, a commercial epoxy coating was modified by adding microcapsules composed of a poly(methyl methacrylate) shell and a core of ionic polydimethylsiloxane (PDMS) oligomers. The encapsulation of amino- and carboxylic acid-terminated PDMS was achieved by a solvent evaporation process after the emulsification of core and shell materials, dissolved in CH2Cl2, in a suitable colloidal solution. A high core loading of nearly 50% wt. was successfully obtained by carefully increasing the interfacial tension of oil-in-water emulsion before the solvent evaporation. The microcapsule morphology was evaluated by SEM and optical microscopy analyses, which showed a particle diameter range of 20–70 μm. The presence of ionic PDMS oligomers as core materials was demonstrated by FTIR spectroscopy and thermogravimetric analysis (TGA), which was also employed to determine the core loading. The newly prepared microcapsules were then incorporated into the matrix of a commercial two-component epoxy coating. Corrosion protection abilities were assessed by comparing samples coated with a standard epoxy coating modified with a 20% wt. of microcapsules and the pristine epoxy coating. The corrosion protection performance of the modified coating was evaluated through electrochemical impedance spectroscopy (EIS) tests and potential vs time measurements, which showed that the microcapsules in the coating matrix caused a beneficial increase in barrier properties of a scratched coating. The surface damage triggered the release of functional PDMS oligomers, leading to the formation of a supramolecular ionic network and providing self-healing abilities to the modified coating
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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