1,720,978 research outputs found
Inclusion of multiple climate tipping as a new impact category in life cycle assessment of polyhydroxyalkanoate (PHA)-based plastics
Full text linkThe merits of temporary carbon storage are often debated for bio-based and biodegradable plastics. We employed life cycle assessment (LCA) to assess environmental performance of polyhydroxyalkanoate (PHA)-based plastics, considering multiple climate tipping as a new life cycle impact category. It accounts for the contribution of GHG emissions to trigger climate tipping points in the Earth system, considering in total 13 tipping elements that could pass a tipping point with increasing warming. The PHA was either laminated with poly(lactic acid), or metallized with aluminum or aluminum oxides to lower permeability of the resulting plastics toward oxygen, water vapor and aromas. The assessments were made accounting for potential differences in kinetics of evolution of greenhouse gases (CO2, CH4) from bioplastic degradation in the end-of-life. Results show that: (1) PHA films with high biodegradability perform best in relation to the climate tipping, but are not necessarily the best in relation to radiative forcing increase or global temperature change; (2) sugar beet molasses used as feedstock is an environmental hot spot, contributing significantly to a wide range of environmental problems; (3) increasing PHA production scale from pilot to full commercial scale increases environmental impacts, mainly due to decreasing PHA yield; and (4) further process optimization is necessary for the PHA-based plastics to become attractive alternatives to fossil-based plastics. Our study suggests that multiple climate tipping is a relevant impact category for LCA of biodegradable bioplastics
Multiple Climate Tipping Points Metrics for Improved Sustainability Assessment of Products and Services
Full text linkMounting evidence indicates that climate tipping points can have large, potentially irreversible, impacts on the earth system and human societies. Yet, climate change metrics applied in current sustainability assessment methods generally do not consider these tipping points, with the use of arbitrarily determined time horizons and assumptions that the climate impact of a product or service is independent of emission timing. Here, we propose a new method for calculating climate tipping characterization factors for greenhouse gases (carbon dioxide, methane, and nitrous oxide) at midpoint. It covers 13 projected tipping points, incorporates the effect that the crossing of a given tipping point has on accelerating the crossing of other tipping points, and addresses uncertainties in the temperature thresholds that trigger the tipping points. To demonstrate the added value of the new metric, we apply it to emissions stemming from end-of-life of plastic polymers and compare them with commonly used metrics. This highlights the need to consider climate tipping in sustainability assessment of products and services
Comparative life cycle assessment of coffee jar lids made from biocomposites containing poly(lactic acid) and banana fiber
No full textComposites containing bio-based materials, like banana fiber and poly(lactic acid) (PLA), are potential food-packaging materials. We carried out an environmental life cycle assessment (LCA) of coffee jar lids made from high density polyethylene (HDPE), PLA, and banana fiber to assess their environmental performance. We considered differences in the type of blend (content of PLA and banana fiber in the composite), origin of the banana fiber feedstock (considered as either biowaste or as a co-product from banana production) and banana fiber pretreatment conditions (either no pretreatment or pretreatment using chemicals). Irrespective of the scenario, a lid made from 40% banana fiber and equal amounts of HDPE and PLA performed significantly better in all 18 impact categories when compared to a lid made from 100% PLA. By contrast, the same lid performed significantly better in 3 impact categories only (climate change, photochemical oxidant formation and fossil depletion) when compared to a lid made from 100% HDPE. Thus, environmental performance of the biocomposite strongly depends on which polymer base is replaced by the banana fiber in the composite. Replacing PLA with banana fiber is generally expected to bring environmental benefits
Evaluation of sugar feedstocks for bio-based chemicals:A consequential, regionalized life cycle assessment
Full text linkFermentable sugars are an attractive feedstock for the production of bio-based chemicals. However, little is known about the environmental performance of sugar feedstocks when demand for sugars increases, and when local conditions and sensitivities of receiving ecosystems are taken into account. Production of monosaccharides from various first- and second-generation feedstocks (sugar beet, sugar cane, wheat, maize, wood, residual woodchips, and sawdust) in different geographic locations was assessed and compared as feedstock for monoethylene glycol (MEG) using consequential, regionalized life cycle assessment. Sugar cane grown in Thailand performed best in all three areas of protection, that is, for life cycle impacts on human health, ecosystem quality, and resources (respectively, equal to −7.6 × 10−5 disability-adjusted life years, −1.2 × 10−8 species-years and −0.046 US dollars per amount of feedstock needed to produce 1 kg of MEG). This was mainly due to benefits from by-products—incineration of sugar cane bagasse generating electricity and use of sugar cane molasses for the production of bioethanol. The wood-based feedstocks and maize performed worse than sugar cane and sugar beet, but their evaluation did not consider that sugar extraction technology from lignocellulose is immature, while identification of marginal suppliers of the marginal crop is particularly uncertain for maize. Wheat grown in Russia performed the worst mainly due to low agricultural yields (with impacts equal to 8.9 × 10−5 disability-adjusted life years, 6.9 × 10−7 species-years, and 1.8 US dollars per amount of feedstock required to produce 1 kg of bio-based MEG). Our results suggest that selection of sugar feedstocks for bio-based chemicals should focus on (i) the intended use of by-products and functions they replace and (ii) consideration of geographic differences in parameters that influence life cycle inventories, while spatial differentiation in the life cycle impact assessment was less influential
Development of climate tipping damage metric for life-cycle assessment - the influence of increased warming from the tipping
Full text linkPurpose: The multiple climate tipping points potential (MCTP) is a novel metric in life-cycle assessment (LCA). It addresses the contribution of greenhouse gas emissions to disturb those processes in the Earth system, which could pass a tipping point and thereby trigger large, abrupt and potentially irreversible changes. The MCTP, however, does not represent ecosystems damage. Here, we further develop this midpoint metric by linking it to losses of terrestrial species biodiversity at either local or global scales. Method: A mathematical framework was developed to translate midpoint impacts to temperature increase, first, and then to potential loss of species resulting from the temperature increase, using available data on the potentially disappeared fraction of species due to a unit change in global average temperature. Results and discussion: The resulting damage MCTP expresses the impacts on ecosystems quality in terms of potential loss of terrestrial species resulting from the contribution of GHG emissions to cross climatic tipping points. The MCTP values range from 2.3·10–17 to 1.1·10–15 PDF (potentially disappeared fraction of species) for the global scale and from 2.7·10–17 to 1.1·10–15 PDF per 1 kg of CO2 emitted for the local scale. They are time-dependent, and the largest values are found for emissions occurring between 2030 and 2045, generally declining for emissions occurring toward the end of the century. Conclusions: The developed metric complements existing damage-level metrics used in LCA, and its application is expected to be especially relevant for products where time-differentiation of emissions is possible. To enable direct comparisons between our damage MCTP and the damage caused by other environmental impacts or other climate-related impact categories, further efforts are needed to harmonize MCTP units with those of the compared damage metrics
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Altered connectivity within the cerebello-thalamocortical network in essential tremor: evidence from a resting state fMRI study
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