122,118 research outputs found

    Non-Catalyzed and Pt/gamma-Al2O3 Catalyzed Hydrothermal Cellulose Dissolution-Conversion: Influence of the Reaction Parameters

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    Jollet, Veronique Chambon, Flora Rataboul, Franck Cabiac, Amandine Pinel, Catherine Guillon, Emmanuelle Essayem, NadineThe dissolution of cellulose under 5 MPa of H-2 in the absence of catalyst is temperature and time dependant. The presence of Pt/gamma-Al2O3 increases the initial rate of dissolution. The presence of H-2/Pt is essential although its exact role has not been well elucidated

    A Multi-Language Comparison of Influences on Author Verification using Character N-Grams

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    We create a new multi-language corpus for author verification based on Wikipedia talkpages, and evaluate the influence that differences in topic and time have on character n-gram author profiles. Topic alignment between two texts is found to increase author verification precision, and an authors writing style is found to change over time, but not more significantly after 3 years than after 1 year.Information ArchitectureWISElectrical Engineering, Mathematics and Computer Scienc

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    The vanishing author in computer-generated works: a critical analysis of recent Australian case law

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    Abstract The use of software is ubiquitous in the creation of many copyright works, yet the requirement in copyright law that every work have a human author who engages in independent intellectual effort means that its use may prevent copyright subsistence. Several recent Australian cases have refocused attention on authorship as an essential criterion of copyright subsistence, and these cases suggest that much computer-produced output may be authorless and thus lack copyright protection. This article, the first in a two-part series, analyses how each case deals with the question of authorship of computer-produced works and why the use of software diminishes copyright protection for a significant number of computer-generated works. The article critiques the application of conventional notions of human authorship developed in the pre-computer age to modern productions and suggests alternative approaches to authorship that satisfy both the major objectives of copyright policy and the need to adapt to the computer age. The article argues that, without a broader judicial approach to authorship of computer-generated works, Parliament must remedy the lacuna in protection for these ‘authorless’ works. Possible solutions for reform are suggested. In a forthcoming article, the author comprehensively examines those reform proposals

    Studies on MeAPSO-5: An investigation of physicochemical and acidic properties

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    Oliveira, Alcineia C. Essayem, Nadine Tuel, Alain Clacens, Jean-Marc Ben Taarit, Younes 20th Ibero American Catalysis Symposium SEP 17-22, 2006 Gramado, BRAZILThis work reports physicochemical and acidic properties of MeAPSO-5 (Me = chromium or iron), regardless their performance in the production of isobutane. Chromium and iron were partially introduced in SAPO-5 by direct hydrothermal synthesis. The solids were characterized by XRD, chemical analysis, N-2 adsorption isotherms, EPR, XPS, and calorimetry of ammonia adsorption. Their activity was also evaluated in the isomerization of n-butane. The purity of hydrothermally synthesized SAPO-5 was identified in all solids. EPR and XPS showed that chromium and iron exist as Cr2O3 and Fe2O3, respectively, mostly distributed on the solid surface. However, no reflections characteristic of these oxides were found in the XRD patterns. The chromium and iron cause different effects on the acidity: chromium increases the solid acidity whereas iron reduces drastically the acidic features. While distinct activity were observed between CrSAPO-5 and the FeSAPO-5 in n-butane isomerization, it is noteworthy that the pure SAPO-5 is not active in the reaction due to the too low strength of its acid sites. Results suggest that the n-C-4 isomerization activity of CrSAPO-5 may be ascribed to its enhanced acidity while, contrary to what was observed in the case of mordenite or sulfated zirconia, Iron addition to SAPO-5 did not enhance the catalytic activity via a possible participation of redox steps. (c) 2007 Elsevier B.V. All rights reserved

    Diffusive author(s), cohesive author: Analysis of S/N (1994)

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    This study indicates the ways in which various aspects of the author(s) are brought forth in Dumb type’s performance art, the S/N production. Previous research has suggested a non-hierarchical organization of Dumb type and the absence of a “privileged author” in Dumb type’s collaborative work, S/N. However, the results that I have investigated from member’s interviews on the creative process of S/N along with my analysis of the recorded images of S/N, indicate a different aspect of the author(s). First, S/N was created through, so to speak, the collective ideas of the members of Dumb type. Further, S/N has at least nine quotations from previous performances, installations, and printed writings, besides the work-in-progress technique. Explicating one of the “author functions” as given by Michel Foucault, each text has plural subjects of the author. However, it has been revealed from members’ interviews that Teiji Furuhashi had a decision-making role in selecting the members’ ideas within the performance. Since then, S/N has had plural subjects of creation; however, Furuhashi is one of the subjects of creation along with the “privileged author.” S/N has plural authors (diffusive authors) yet at the same time, it has a “privileged author,” Teiji Furuhashi (cohesive author)

    Catalytic Wood Fractionation into Chemicals in Supercritical Ethanol and n-Heptane: Potential and Limitations

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    Direct selective wood fractionation into chemicals is an approach that has attracted recent attention. The application of sub- and supercritical (SC) alcohols to fractionate wood into solid cellulose and liquefy phenolic monomers is a process now widely known as “lignin first”. It is justified to study the potential of other SC organic solvents of variable polarities. Herein, we compare the abilities of SC ethanol and SC n-heptane to fractionate pine wood near their critical point. While near-critical ethanol has more affinity for lignin fraction, we show that near-critical n-heptane has preference for carbohydrate deconstruction. If SC ethanol favors biooil formation which contains important ethyl/ethoxy groups, the alkane greatly favors solid carbon products. The impact of addition of heterogeneous catalysts (acid, basic and Cu-based catalysts) on wood fractionation and light chemicals formation was investigated deeply in SC ethanol. In SC ethanol, catalysts favor light liquid products such as esters at the expense of biooil with a total oxygenates yield of 33 wt% relative to carbohydrates over β zeolite. However, we show that depending on the catalysts’ nature, wood components fractionation was completely changed, and this is particularly true with solid acid catalysts which promote cellulose deconstruction and the formation of solid carbon products. It is proposed that liquid products’ accumulation in the autoclave, in particular water, is at the origin of the wood fractionation changes which preclude its control by the choice of the SC organic solvent and conditions. Moreover, all the catalysts underwent severe leaching, which also contributed to the wood component fractionation changes

    Dissipative Range Scaling of Higher Order Structure Functions for Velocity and Passive Scalars

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    Differently to Kolmogorov's second similarity hypothesis, we find that the 2n-th order velocity and scalar structure functions scale with n-th order moment of the energy dissipation and the scalar dissipation, respectively. The origins of this scaling are analyzed by the transport equations of the fourth order velocity and scalar increment moments and by direct numerical simulations

    Fast implementation of iterative adaptive approach for wideband unambiguous radar detection

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    Accepted author manuscriptMicrowave Sensing, Signals & System

    Ratio of n-6/n-3 in the diets of beef cattle

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    Effects of feeding heat-treated canola (C), soybean (S) and flax (F) or mixtures on growth and slaughter characteristics, taste and fatty acid (FA) composition of beef tissue were investigated using 128 crossbred steers to determine the potential of improving the nutritional quality of beef for humans. For Trial 1 (48 steers), dietary treatments were: roasted C, extruded C, roasted S, extruded S, roasted F and extruded F. For Trial 2 (80 steers), the dietary treatments were: S:F (1:1), S:C (1:1), C:F (1:1) and S:F:C (1:1:1), and the oilseeds were processed either by roasting or extruding before mixing. Soybean meal and soybean oil were used to give equivalent lipid and protein contents to each experimental diet. The basal diet consisted of grass silage, barley grain, vitamins and minerals. Steers were fed for a minimum of 100d then slaughtered at a uniform degree of finish. Growth and slaughter characteristics of the steers were only slightly affected by dietary treatment in that the soybean-fed steers consumed more feed and had a higher average daily gain than the canola or flax-fed animals in Trial 1. There was no difference in taste panel parameters for any of the treatments. Inclusion of flax in the diet increased the total n-3 content of meat. Similar results were found for canola and C18:1n-9 although this was not the case for soybean and the n-6 FA. For the n-6 FA in the PL and neutral lipid fractions of the meat samples, levels were correlated with high dietary levels of n-6 or n-9 with low levels of n-3 while for the n-3 FA, levels were correlated with high dietary n-3 levels and low n-6 levels. Oilseed processing method did not have an effect on any fatty acid levels. It is possible to modify the FA composition of beef meat toward a healthier profile by including heat-treated oilseeds in the diet to influence the degree of lipid metabolism in the rumen.ID: S0377840111004007; M3: Article; Accession Number: S0377840111004007; Author: M.A. McNiven (a, ⁎); Author: J.L. Duynisveld (b); Author: T. Turner (a); Author: A.W. Mitchell (a); Affiliation: Department of Health Management, Atlantic Veterinary College, University of PEI, Charlottetown, PEI, Canada C1A 4P3; Affiliation: Agriculture and Agri-Food Canada, Nappan, NS, Canada B0L 1C0; Keyword: Oilseeds; Keyword: Roasted; Keyword: Extruded; Keyword: Fatty acids; Keyword: Healthy fat; Number of Pages: 11; Language: English
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