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    Particle geochemistry in the Rainbow hydrothermal plume, Mid-Atlantic Ridge1

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    We report the analysis of 18 large volume (500-1500 L) in situ filtered samples of particulate material from the largest hydrothermal plume on the Mid-Atlantic Ridge, overlying the ultramafic-hosted Rainbow hydrothermal field at 36[deg] 14'N. Measured particulate iron concentrations reach 614 nM. High concentrations of particulate Fe oxyhydroxides result from the extremely high Fe concentration (~24 mM) and Fe/H2S ratio (~24) of the vent fluids, and persist to at least 10 km away from the vent site due to the advection of plume material with the ambient along-axis flow. Two of the nine pairs of pump deployments appear to have intercepted the buoyant or otherwise very young portion of the hydrothermal plume. These samples are characterized by anomalously (compared to neutrally buoyant plume samples) high concentrations of Mg, U, and chalcophile elements, and low concentrations of Mn, Ca, V, Y, and the rare earth elements (REE). Within the neutrally buoyant plume, elemental distributions are largely consistent with previously observed behaviors: preferential removal of chalcophile elements, conservative behavior of oxyanions (P, V, and U), and continuous scavenging of Y and the REE. This consistency is particularly significant in light of the underlying differences in fluid chemistry between Rainbow and other studied sites. Chalcophile elements are preferentially removed from the plume in the order Cd>Zn>Co>Cu. Phosphorus/iron and vanadium/iron ratios for the neutrally buoyant plume are consistent with global trends with respect to the concentration of dissolved phosphate in ambient seawater. Comparison of buoyant and neutrally buoyant plume ratios with data from hydrothermal sediments underlying the Rainbow plume (Cave et al., 2002) indicates, however, that while P/Fe ratios are indeed constant V/Fe ratios increase progressively from early stage plume particles to sediments. REE distributions in the buoyant and neutrally buoyant plume appear most consistent with a continuous scavenging process during dispersion through the water colum

    The effect of plume processes on the Fe-isotope composition of hydrothermally derived Fe in the deep ocean as inferred from the Rainbow vent site, Mid-Atlantic Ridge, 36,14'N

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    The Rainbow hydrothermal vent site, which is the largest known point source for dissolved Fe delivered to the deep North Atlantic ocean, has remained invariant in its Fe isotope composition over at least the past 16,000 years, based on analysis of metalliferous sediments beneath the plume. Because of the conservative behavior of Fe in the Rainbow plume, 56Fe values of particles in the neutrally buoyant plume (?0.18±0.05‰) and underlying sediments (?0.19±0.05‰) are indistinguishable from the 56Fe values of the high-temperature fluid sources (?0.23±0.04‰). Particles from the near-vent, buoyant stage of the plume, however, have higher 56Fe values (+0.15‰ to +1.20‰) relative to the original vent fluid, consistent with fractionation during oxidation of Fe(II)aq to Fe(III)aq. Isotope compositions become invariant in the plume once all Fe(II)aq is fully oxidized, preserving the original composition of the vent fluid. The constant Fe isotope compositions of the vent fluids over time implies that changes in seawater Fe isotope composition of the North Atlantic ocean, as they are recorded in Fe–Mn crusts, requires changes in the relative fluxes of Fe to the ocean

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
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