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Tailoring the critical temperature of Ca/K-1144 superconductors: The effect of aliovalent substitution on tetragonality
No full textAmong the iron-based superconductors, the so-called 1144 family has, in recent years, attracted significant interest due to its stoichiometric nature, with materials robust towards chemical inhomogeneities and characterized by a well-defined critical temperature. The most studied 1144 compounds are characterized by the A1AE1Fe4As4 chemical composition, where A and AE constitute an appropriate combination of alkaline and alkaline-earth metals, respectively. The 1144 structure is in fact formed only when the A and AE elements respect specific requirements in terms of relative size and parent compound structure. The stoichiometric aspect, one of their strong points, has represented, however, up to today a restriction, limiting the conceptualization of 1144 structures to quaternary compounds. In this work, we demonstrate that to obtain the 1144 crystalline phase it may be sufficient to maintain a 1:1 ratio between ions of different size that intercalate the Fe-As planes, and that in selected conditions an opportunely tailored cation substitution is possible. Using a simple mechanochemically assisted synthesis route 1144 compounds where Ca is substituted by Na, K by Ba, and both simultaneously, are obtained. We demonstrate that the critical temperature of doped compounds is not simply related to the substitution amount or to the resulting Fe valence. We show that the superconducting transition is in fact linked to the structural distortion induced by the chemical composition variation: by tailoring the chemical composition we obtain doubly substituted samples - with substitution levels up to 20% - characterized by a tetragonality ratio c/a similar to the pristine compound and critical temperatures of approximately 34 K
Pinning Properties of 1144 Polycrystalline Samples With Aliovalent Doping
No full textThe 1144 Iron-Based Superconductors (IBSC), characterized by the A1AE1Fe4As4 chemical composition (A = Alkaline, AE = Alkaline-Earth), has gained significant interest in the recent years due to their crystalline structure characterized by an intrinsic modulation of the strain along the c-axis and by the proneness in forming crystalline defects with a positive impact on flux pinning. Moreover, it has been proved that the compound is compatible with the cost-effective powder-in-tube (PIT) manufacturing process. In our recent experiments, we have showed that the A1AE1Fe4As4 structure can be tailored to obtain a 1144 compound characterized by different (AxAE1-x)(AEyA1-y)Fe4As4 chemical formulae without any depression in the critical temperature value. On the other hand, it has been recently shown that the doping with selected elements on both A and AE sites has a clear influence on the pinning and the grain boundary properties of poly-crystalline samples. In this work we report the results of the extensive magnetic characterization performed on pristine Ca1K1Fe4As4 and doped (AxCa1-x)(AEyK1-y)Fe4As4 with Ba as dopant on the K site and either La or Na as dopant on the Ca site. In particular, the magnetization hysteresis loops recorded at different temperatures M(H, T) and the critical current density dependences extracted from the M(H) using the Bean model, Jc(B, T), have been analyzed in order to assess the effect of aliovalent doping on the quality of the produced samples in terms of grain boundary properties and pinning efficiency
Pinning Properties of 1144 Polycrystalline Samples With Aliovalent Doping
No full textThe 1144 Iron-Based Superconductors (IBSC), characterized by the A(1)AE(1)Fe(4)As(4) chemical composition (A = Alkaline, AE = Alkaline-Earth), has gained significant interest in the recent years due to their crystalline structure characterized by an intrinsic modulation of the strain along the c-axis and by the proneness in forming crystalline defects with a positive impact on flux pinning. Moreover, it has been proved that the compound is compatible with the cost-effective powder-in-tube (PIT) manufacturing process. In our recent experiments, we have showed that the A(1)AE(1)Fe(4)As(4) structure can be tailored to obtain a 1144 compound characterized by different (A(x)AE(1-x))(AE(y)A(1-y))Fe4As4 chemical formulae without any depression in the critical temperature value. On the other hand, it has been recently shown that the doping with selected elements on both A and AE sites has a clear influence on the pinning and the grain boundary properties of poly-crystalline samples. In this work we report the results of the extensive magnetic characterization performed on pristine Ca1K1Fe4As4 and doped (A(x)Ca(1-x))(AE(y)K(1-y))Fe4As4 with Ba as dopant on the K site and either La or Na as dopant on the Ca site. In particular, the magnetization hysteresis loops recorded at different temperatures M(H, T) and the critical current density dependences extracted from the M(H) using the Bean model, J(c)(B, T), have been analyzed in order to assess the effect of aliovalent doping on the quality of the produced samples in terms of grain boundary properties and pinning efficiency
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Oxidation in Ca/K-1144 iron-based superconductors polycrystalline compounds
Full text linkIron-based superconductors (IBSCs) are a class of material under investigation for the development of superconducting wires in the low-temperature-high magnetic fields power application. Among the various families of IBSCs, the 1144 CaKFe4As4 compound is a promising material able to achieve outstanding superconducting properties with a cheap and simple chemical composition. Oxidation, in these compounds, is considered an obstacle for high intergranular critical current density, Jc,GB. A study devoted to the evaluation of oxidation phenomena and their effects on the superconducting properties is thus needed in order to fully understand the involved mechanisms. From the evaluation of polycrystalline samples obtained by a mechanochemically assisted synthesis route, a degradation of the critical temperature and critical currents has been observed concurrently with oxygen accumulation at grain boundaries in open porosities. However, the crystalline structure at an atomic level seems not affected, as well as intragranular superconducting properties assessed by means of calorimetric methods. These results suggest that loss of superconducting properties in Ca/K-1144 compounds following oxidation is significantly associated with the worsening of grain connectivity
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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