1,720,978 research outputs found

    Predictive model for the phase diagrams of ternary mixtures composed of calcium, lithium and sodium/potassium nitrates

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    The study and development of multi-component alkaline nitrates systems is of utmost interest to investigate low melting and low cost HTFs and HSMs, to be used in CSP plants. At this aim, several binary and ternary mixtures have been proposed as feasible and promising materials in the scientific literature. In order to evaluate the most feasible HTF and HSM, the simulation campaign proposed in this work was focused on economical and readily available compounds, ruling out rare and costly species. A semi-predictive model, based on the regular solution theory, was employed to draw the ternary phase diagrams of LiNO3/NaNO3/Ca(NO3)2 and LiNO3/KNO3/Ca(NO3)2, from which it was possible to select the lower melting zones and the compositions. The binary sub-systems were the starting point for the employed approach. The results showed a good agreement with literature experimental data, and new low melting compositions were simulated and experimentally validated. It is noteworthy that it was possible to identify in great detail the zones of the two ternaries presenting the lowest freezing points and this can allow the design of interesting and cost-effective low melting mixtures

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Assessment and perspectives of heat transfer fluids for csp applications

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    Different fluid compositions have been considered as heat transfer fluids (HTF) for concentrating solar power (CSP) applications. In linear focusing CSP systems synthetic oils are prevalently employed; more recently, the use of molten salt mixtures in linear focusing CSP systems has been proposed too. This paper presents a comparative assessment of thermal oils and five four nitrate/nitrite mixtures, among the ones mostly employed or proposed so far for CSP applications. The typical medium-size CSP plant (50 MWe) operating with synthetic oil as HTF and the “solar salt” as TES was considered as a benchmark. In the first part of the paper, physical properties and operation ranges of different HTFs are reviewed; corrosion and environmental issues are highlighted too. Besides an extensive review of HTFs based on data available from the open literature, the authors report their own obtained experimental data needed to thoroughly compare different solutions. In the second part of the paper, the impact of the different HTF options on the design and operation of CSP plants are analyzed from techno-economic perspectives

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Thermophysical, environmental, and compatibility properties of nitrate and nitrite containing molten salts for medium temperature CSP applications: A critical review

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    The production of electric energy from solar radiation is nowadays one of the most investigated and developed “carbon free” technology. A throughout investigation of the ceramics most commonly used as heat transfer fluids and/or heat storage materials for concentrating solar power systems (i.e. alkaline and heart alkaline nitrate/nitrite mixtures) is here reported. The study stems by the need to base materials selection on an accurate and critical knowledge of all their characteristics, including their thermophysical, environmental compatibility, and economic features. At this purpose, a rating criterion have been established, to readily show the advantages and disadvantages of each material, and to highlight which characteristics of the examined materials need to be further investigated and improved. Nitrate/nitrite mixtures have also been compared with other ceramics used for thermal storage, such as solid fillers, liquid metals, other salt mixtures, or phase change materials

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    Modeling the Total Ternary Phase Diagram of NaNO3–KNO3–NaNO2 Using the Binary Subsystems Data

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    When designing a concentrating solar power (CSP) system, selection of a proper heat transfer fluid (HTF) material is a key, especially when employed in parabolic trough CSP plants. In particular, the use of low melting mixtures as an alternative to the widely commonly used “solar salt” can increase the CSP manageably and, as a result, several innovative nitrite/nitrate mixtures have been proposed. However, very few thermodynamics data are available for these compounds, especially regarding ternary compositions. One of the most interesting low freezing mixture is prepared with sodium and potassium nitrate together with sodium nitrite. The aim of this work is to investigate the thermodynamics properties of this ternary system, starting from its binary subunits, studying the phase diagram of this compound both experimentally and by a regular solution model. At this purpose, the literature phase diagrams of the binary subsystem were simulated in order to obtain the fitting parameters necessary for the employed semi-predictive tool. Then, the ternary system was modeled and the results showed very good agreement with the experimental points. It is quite interesting to note that both the theoretical and experimental results showed a low melting zone presenting greater sodium nitrate molar fractions with respect to sodium nitrite than previously reported in literature. This would lead to a decrease in the HTF price and an improvement regarding the fluid toxicity

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

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