17 research outputs found
Photolabile protecting groups: a strategy for making primary amine polymers by RAFT
Photolabile amine protecting groups are combined with RAFT polymerization to create well-defined amine containing polymers, which is typically a challenge for RAFT polymerization.</p
RAFT polymerization of renewable monomers with dithiobenzoates: Effect of Z-group substituents and reaction conditions
ISSN:0014-3057ISSN:1873-1945ISSN:1873-194
Intrinsic and Catalyzed Photochemistry of Phenylvinylketone for Wavelength‐Sensitive Controlled Polymerization
Synthesis and Self-assembly of Limonene Oxide - Lactide Block Copolymers
The reaction of limonene oxide with a zirconium complex led to polymers with a molar mass up to 4.0 kDa, the largest limonene oxide homopolymer reported so far. Diblock, triblock, and tetrablock copolymers of limonene oxide and L-lactide were also prepared using a redox switchable catalyst based on the same zirconium complex; the obtained copolymers are the first-ever reported limonene oxide-lactide block copolymers. The solid-state self-assembly properties of the copolymers were characterized by small angle X-ray scattering and rheology measurements, giving a self-assembly domain radius of 11, 25, and 35 nm for the diblock, triblock, and tetrablock copolymers, respectively
Substituent effects in iniferter photopolymerization: can bond homolysis be enhanced by electronics?
Low temperature thermal RAFT depolymerization: the effect of Z-group substituents on molecular weight control and yield
ISSN:2041-6520ISSN:2041-6539ISSN:2041-653
