38 research outputs found

    Bereiding van fosforzuur (50%P2O5) volgens het hemihydraatproces

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    Document(en) uit de collectie Chemische ProcestechnologieDelftChemTechApplied Science

    Mechanisch dynamisch onderzoek van polyvinylchloride beneden de glasovergangstemperatuur

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    Ons onderzoek was erop gericht de B-relaxatie te onderzoeken, in het bijzonder de invloed van thermische voorbehandeling d.w.z. de invloed van intermolekulaire strukturen op de β-overgang. Dynamische mechanische metingen werden verricht volgens de resonantiemethode, waarbij in tegenstelling tot de gangbare technieken fase-verschillen gemeten weren. De meetgegevens werden door een digitale rekenmachine verwerkt Onderzocht werd de invloed van kristalliniteit, weekmaking en temperen op de β-overgang. Gevonden werd dat de β-relaxatie veroorzaakt wordt door intra-molekulaire bewegingen. Aanwijzingen werden gevonden voor een ɤ-relaxatiegebied bij lage temperatuur ( <- 150 °C.).Applied Science

    Final Report of the DAUFIN project

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    DAUFIN = Data Assimulation within Unifying Framework for Improved river basiN modeling (EC 5th framework Project

    Performance of high-resolution X-band radar for rainfall measurement in The Netherlands

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    This study presents an analysis of 195 rainfall events gathered with the X-band weather radar SOLIDAR and a tipping bucket rain gauge network near Delft, The Netherlands, between May 1993 and April 1994. The aim of this paper is to present a thorough analysis of a climatological dataset using a high spatial (120 m) and temporal (16 s) resolution X-band radar. This makes it a study of the potential for high-resolution rainfall measurements with non-polarimetric X-band radar over flat terrain. An appropriate radar reflectivity – rain rate relation is derived from measurements of raindrop size distributions and compared with radar – rain gauge data. The radar calibration is assessed using a long-term comparison of rain gauge measurements with corresponding radar reflectivities as well as by analyzing the evolution of the stability of ground clutter areas over time. Three different methods for ground clutter correction as well as the effectiveness of forward and backward attenuation correction algorithms have been studied. Five individual rainfall events are discussed in detail to illustrate the strengths and weaknesses of high-resolution X-band radar and the effectiveness of the presented correction methods. X-band radar is found to be able to measure the space-time variation of rainfall at high resolution, far greater than what can be achieved by rain gauge networks or a typical operational C-band weather radar. On the other hand, SOLIDAR can suffer from receiver saturation, wet radome attenuation as well as signal loss along the path. During very strong convective situations the signal can even be lost completely. In combination with several rain gauges for quality control, high resolution X-band radar is considered to be suitable for rainfall monitoring over relatively small (urban) catchments. These results offer great prospects for the new high resolution polarimetric doppler X-band radar IDRA.Remote Sensing of the EnvironmentElectrical Engineering, Mathematics and Computer Scienc

    Biases in Thorpe-scale estimates of turbulence dissipation. Part I : Assessments from large-scale overturns in oceanographic data

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    Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 45 (2015): 2497–2521, doi:10.1175/JPO-D-14-0128.1.Oceanic density overturns are commonly used to parameterize the dissipation rate of turbulent kinetic energy. This method assumes a linear scaling between the Thorpe length scale LT and the Ozmidov length scale LO. Historic evidence supporting LT ~ LO has been shown for relatively weak shear-driven turbulence of the thermocline; however, little support for the method exists in regions of turbulence driven by the convective collapse of topographically influenced overturns that are large by open-ocean standards. This study presents a direct comparison of LT and LO, using vertical profiles of temperature and microstructure shear collected in the Luzon Strait—a site characterized by topographically influenced overturns up to O(100) m in scale. The comparison is also done for open-ocean sites in the Brazil basin and North Atlantic where overturns are generally smaller and due to different processes. A key result is that LT/LO increases with overturn size in a fashion similar to that observed in numerical studies of Kelvin–Helmholtz (K–H) instabilities for all sites but is most clear in data from the Luzon Strait. Resultant bias in parameterized dissipation is mitigated by ensemble averaging; however, a positive bias appears when instantaneous observations are depth and time integrated. For a series of profiles taken during a spring tidal period in the Luzon Strait, the integrated value is nearly an order of magnitude larger than that based on the microstructure observations. Physical arguments supporting LT ~ LO are revisited, and conceptual regimes explaining the relationship between LT/LO and a nondimensional overturn size are proposed. In a companion paper, Scotti obtains similar conclusions from energetics arguments and simulations.B.D.M. and S.K.V. gratefully acknowledge the support of the Office of Naval Research under Grants N00014-12-1-0279, N00014-12-1-0282, and N00014-12-1-0938 (Program Manager: Dr. Terri Paluszkiewicz). S.K.V. also acknowledges support of the National Science Foundation under Grant OCE-1151838. L.S.L. acknowledges support for BBTRE by the National Science Foundation by Contract OCE94-15589 and NATRE and IWISE by the Office of Naval Research by Contracts N00014-92-1323 and N00014-10-10315. J.N.M. was supported through Grant 1256620 from the National Science Foundation and the Office of Naval Research (IWISE Project).2016-04-0

    Parts of speech systems as a basic typological parameter.

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    This paper argues that the word order possibilities of a language are partly determined by the parts-of-speech system of that language. In languages in which lexical items are specialized for certain functionally defined syntactic slots (e.g. the modifier slot within a noun phrase), the identifiability of these slots is ensured by the nature of the lexical items (e.g. adjectives) themselves. As a result, word order possibilities are relatively unrestricted in these languages. In languages in which lexical items are not specialized for certain syntactic slots, in that these items combine the functions of two or more of the traditional word classes, other strategies have to be invoked to enhance identifiability. In these languages word order constraints are used to make syntactic slots identifiable on the basis of their position within the clause or phrase. Hence the word order possibilities are rather restricted in these languages. Counterexamples to the latter claim all involve cases in which identifiability is ensured by morphological rather than syntactic means. This shows that there is a balanced trade-off between the syntactic, morphological, and lexical structure of a language

    The regional variation of aboveground live biomass in old-growth Amazonian forests

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    The biomass of tropical forests plays an important role in the global carbon cycle, both as a dynamic reservoir of carbon, and as a source of carbon dioxide to the atmosphere in areas undergoing deforestation. However, the absolute magnitude and environmental determinants of tropical forest biomass are still poorly understood. Here, we present a new synthesis and interpolation of the basal area and aboveground live biomass of old-growth lowland tropical forests across South America, based on data from 227 forest plots, many previously unpublished. Forest biomass was analyzed in terms of two uncorrelated factors: basal area and mean wood density. Basal area is strongly affected by local landscape factors, but is relatively invariant at regional scale in moist tropical forests, and declines significantly at the dry periphery of the forest zone. Mean wood density is inversely correlated with forest dynamics, being lower in the dynamic forests of western Amazonia and high in the slow-growing forests of eastern Amazonia. The combination of these two factors results in biomass being highest in the moderately seasonal, slow growing forests of central Amazonia and the Guyanas (up to 350?Mg?dry weight?ha?1) and declining to 200-250?Mg?dry weight?ha?1 at the western, southern and eastern margins. Overall, we estimate the total aboveground live biomass of intact Amazonian rainforests (area 5.76 × 106?km2 in 2000) to be 93±23?Pg?C, taking into account lianas and small trees. Including dead biomass and belowground biomass would increase this value by approximately 10% and 21%, respectively, but the spatial variation of these additional terms still needs to be quantifie

    A comparative study of software programmes for cross-sectional skeletal muscle and adipose tissue measurements on abdominal computed tomography scans of rectal cancer patients

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    Background: The association between body composition (e.g. sarcopenia or visceral obesity) and treatment outcomes, such as survival, using single-slice computed tomography (CT)-based measurements has recently been studied in various patient groups. These studies have been conducted with different software programmes, each with their specific characteristics, of which the inter-observer, intra-observer, and inter-software correlation are unknown. Therefore, a comparative study was performed. Methods: Fifty abdominal CT scans were randomly selected from 50 different patients and independently assessed by two observers. Cross-sectional muscle area (CSMA, i.e. rectus abdominis, oblique and transverse abdominal muscles, paraspinal muscles, and the psoas muscle), visceral adipose tissue area (VAT), and subcutaneous adipose tissue area (SAT) were segmented by using standard Hounsfield unit ranges and computed for regions of interest. The inter-software, intra-observer, and inter-observer agreement for CSMA, VAT, and SAT measurements using FatSeg, OsiriX, ImageJ, and sliceOmatic were calculated using intra-class correlation coefficients (ICCs) and Bland–Altman analyses. Cohen's κ was calculated for the agreement of sarcopenia and visceral obesity assessment. The Jaccard similarity coefficient was used to compare the similarity and diversity of measurements. Results: Bland–Altman analyses and ICC indicated that the CSMA, VAT, and SAT measurements between the different software programmes were highly comparable (ICC 0.979–1.000, P &lt; 0.001). All programmes adequately distinguished between the presence or absence of sarcopenia (κ = 0.88–0.96 for one observer and all κ = 1.00 for all comparisons of the other observer) and visceral obesity (all κ = 1.00). Furthermore, excellent intra-observer (ICC 0.999–1.000, P &lt; 0.001) and inter-observer (ICC 0.998–0.999, P &lt; 0.001) agreement for all software programmes were found. Accordingly, excellent Jaccard similarity coefficients were found for all comparisons (mean ≥ 0.964). Conclusions: FatSeg, OsiriX, ImageJ, and sliceOmatic showed an excellent agreement for CSMA, VAT, and SAT measurements on abdominal CT scans. Furthermore, excellent inter-observer and intra-observer agreement were achieved. Therefore, results of studies using these different software programmes can reliably be compared.ImPhys/Quantitative Imagin

    Behavioural ecology of the lapwing Vanellus vanellus L. In upper Teesdale

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    From 1993-95, the behavioural ecology of the Lapwing Vanellus vanellus L. was studied in Upper Teesdale, Co. Durham, with the aim of describing the behavioural mechanisms underlying some population characteristics. Significant effects of age and individuals were found in many aspects of Lapwing breeding biology. Older Lapwings returned to the breeding grounds before yearlings, with adult males returning earliest of all. First breeding attempts occurred at one-year-old for most females, but at two-years-old for most males. Males two-years-old and over showed a remarkable degree of consistency in breeding status (breeding or non-breeding) in consecutive years, even where this meant persistent non-breeding. The age of first breeding, and consistency of breeding status among males, indicates intense intermale competition for limited breeding habitat, with some males, perhaps of low quality, apparently permanently prevented from breeding. However, few differences in annual breeding success were found among females of different ages. With the exception of egg size in first clutches, where yearling females laid eggs around 5% smaller than adults, yearling and adult females were similarly fecund. Laying dates and egg volumes in first clutches exhibited high indices of repeatability between years, probably reflecting a high degree of heritability of these traits. High frequencies of polygyny were recorded, despite the traditional view of strict monogamy for this species. The mating success of male Lapwings increased between one and three years-of-age. The distinct parental roles of the sexes facilitated the occurrence of polygyny by reducing activity-budget costs of polygynous associations for both sexes. Polyterritoriality, polyandry and double-brooding were also recorded and discussed
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