1,721,063 research outputs found

    Thiol-Yne Coupling: Revisiting Old Concepts as a Breakthrough for Up-to-date Applications

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    Radical thiol–yne coupling (TYC) has emerged as one of the most appealing click chemistry procedures, appearing as a sound candidate for replacing/complementing other popular click reactions such as the thiol–ene coupling (TEC) and the Cu-catalysed azide–alkyne cycloaddition (CuAAC). Radical TYC is indeed a metal-free reaction suitable for biomedical applications, and its mechanistic features often make it more efficient than its TEC sister reaction and more suitable for multifaceted derivatisations in the materials chemistry and bioconjugation realms. This article reviews the fascinating results obtained in those fields in very recent years

    Modellazione numerica preliminare di uno spray turbolento evaporante in aria eseguita attraverso un codice di calcolo commerciale con approccio Eulero-Lagrange

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    In questo lavoro viene illustrata l’attivita' di validazione di un modello numerico per la simulazione di uno spray evaporante in regime turbolento (Re8000). La geometria analizzata e le misurazioni sperimentali prese a riferimento sono tratte dalla bibliografia [Sommerfeld e Qiu, Experimental studies of spray evaporation in turbulent flow, International Journal of Heat and Fluid Flow, 1998]. Per la risoluzione del modello numerico e' stato utilizzato un codice di calcolo commerciale (Fluent), attraverso la tecnica RANS abbinata ad un modello di turbolenza a due equazioni (k-e Realizable). La tracciatura delle gocce e' stata svolta risolvendo in maniera instazionaria le equazioni lagrangiane del moto per gruppi di particelle statisticamente omogenee (parcel ). L’interazione tra le gocce e tra le fasi e' stata modellata al fine di riprodurne accuratamente la dinamica. I risultati numerici si sono rivelati complessivamente piu' che soddisfacenti, sia nel predire gli andamenti di velocita' che i diametri medi delle gocce. La leggera sottostima dell’intensita' dell’evaporazione e' da imputare, in primis, alle modellazioni molto semplificate adottate sia per le proprieta' termofisiche dei materiali coinvolti che per la legge di evaporazione

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

    Author Index

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    koamabayili/VECTRON-author-checklist: VECTRON author checklist

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    We have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used

    A simple and industrially scalable method for making a PANI-modified cellulose touch sensor.

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    A simple and industrially scalable method for making a PANI-modified cellulose touch sensor. Ragazzini a, I. Gualandi a, *, S. Selli b, C. Polizzi a, M.C. Cassani a, D. Nanni a, F. Gambassi a, F. Tarterini a, D. Tonelli a, E. Scavetta a, B. Ballarin a, * a Department of Industrial Chemistry “Toso Montanari”, Bologna University, Viale Risorgimento 4, I-40136, Bologna, Italy; b Cromatos s.r.l., via G. Cardano, 6B/C/D, 47122, Forlì, Italy Nowadays, alternatives to the traditional electronics that should be low cost, degradable, compostable and made from environmentally nontoxic substances are of great interest in research. As candidate, we propose bare fibers of cellulose made conductive by an in situ oxidative polymerization of aniline. The resulting composite fibers were emplojed to fabricate electroactive sheets using a pilot plant of a typical paper industry. The resistivity of the obtained sheets is 14 ± 1 Ω sq-1, a value around 1000 times lower than those reported in literature. The higher electronic performances of the sheets were demonstrated by assembling a capacitive touch sensor device with optimized geometry. The touch sensor shows an increase of 3–4 % of the starting electric capacity after compression and a fast response time of 52 ms. To our knowledge this is the first time that a device is prepared in this way and therefore, the herein presented results can bring a significant improvement in the development of low-cost, green and high-tech electronic devices 1. [1] Ragazzini, I. et al. A simple and industrially scalable method for making a PANI-modified cellulose touch sensor. Carbohydr. Polym. (2020) doi: 10.1016/j.carbpol.2020.117304
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