1,721,074 research outputs found

    Parameters of the Earth’s Free Core Nutation from Diurnal Strain Tides

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    Earth deformation at the diurnal tidal frequencies includes the resonant tidal-forcing response caused by the Free Core Nutation (FCN), a retrograde mode related to the slight misalignment of the rotation axes of the outer core and mantle. We analyse data from four underground high-sensitivity laser extensometers, whose signal-to-noise ratio in the diurnal tidal band is particularly high, and provide an alternative independent estimate of the FCN complex frequency with respect to more usual techniques (nutation and gravity). Firstly, we differentiate displacements due to diurnal solid tides to obtain extension along any azimuthal direction in terms of three complex parameters (A, S, C) which depend on latitude and frequency. Then, we demonstrate that we can invert the FCN complex frequency and the sensitivity of Im(A) and Re(S) to the resonance from our data. Lastly we obtain the probability distributions of those four parameters. Our results are in full agreement with those from nutation and gravity, as well as with reference IERS (International Earth Rotation and Reference Systems Service) values. Sensitivities of Im(A) and Re(S) to the resonance are estimated here for the first time and are in agreement with values computed using reference Love and Shida numbers from IERS

    On the Initial Phase of the Ongoing Unrest at Campi Flegrei and Its Relation with Subsidence at Vesuvio (Italy)

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    The densely inhabited area of Naples (Italy), between the Campi Flegrei and Vesuvio volcanoes, is one of the most hazardous regions in the world. After two decades of sustained subsidence, Campi Flegrei has been experiencing an accelerating uplift since 2005. The uplift is currently associated with unusual seismicity and increased degassing. To try to identify the cause of the shift from subsidence to uplift and explore any connection between Campi Flegrei and Vesuvio, we analysed the ground displacement time series of the two volcanoes from 1993 to 2010, obtained from ERS/ENVISAT Synthetic Aperture Radar imagery. To distinguish between the various sources of deformation, we used simple scatter plots and a blind source separation technique called variational Bayesian independent component analysis (vbICA). We obtained consistent results using both approaches. Specifically, with vbICA, we identified two significant independent components (ICs). IC1 describes the subsidence that occurred at Campi Flegrei prior to 2000, including the mini-uplifts of 2000 and 2005, and part of the post-2005 uplift. The expansion and contraction of two volumes beneath Campi Flegrei satisfy IC1: a sill-shaped volume at a depth of approximately 3 km and a small volume at a depth of 1–2 km, respectively. The two sources of deformation reproduce the large-scale deformation in the Campi Flegrei area and the local deformation in the Solfatara area, respectively. In the Campi Flegrei area, IC2 exhibits primarily uplift, which is concentrated in the eastern part of the caldera. The deformation pattern is complex and difficult to interpret. If we model it using simple spheroidal deformation sources, the pattern suggests that two volumes at depths of approximately 9 and 8 km are experiencing opposite activity, namely contraction (beneath the southwestern part of the caldera) and expansion (beneath the central part of the caldera). In the Vesuvio area, IC2 is consistent with the deformation induced by the contraction of a volume at a depth of around 9 km. The contraction beneath Vesuvio is smaller in magnitude than the expansion/contraction beneath Campi Flegrei. The correlation observed after 2002 between uplift at Campi Flegrei and subsidence at Vesuvio suggests the transfer of magma and/or magmatic fluids between the two plumbing systems at 8–9 km depth. This implies that part of the ongoing unrest at Campi Flegrei may have been promoted by mass transfer from below Vesuvio

    Clues of Ongoing Deep Magma Inflation at Campi Flegrei Caldera (Italy) from Empirical Orthogonal Function Analysis of SAR Data

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    Understanding the characteristics of a volcanic system is always important and becomes crucial when the volcano is in pluri-decadal unrest and located in a densely populated area, such as Campi Flegrei caldera, Italy. Ground deformation is a powerful source of information for studying the activity of magmatic sources and hydrothermal systems, even when difficult to detect otherwise. Here, we use ground displacement from ERS-ENVISAT and Sentinel-1A SAR images to investigate the 1993–2000 subsidence and part (2015–2022) of the present unrest. For each of the two time periods, we combine the line-of-sight displacements to obtain vertical and eastward displacements, and apply the empirical orthogonal function analysis to these latter time series—treated as a single data set—to decompose space-time fields into separated modes, consisting of uncorrelated spatial patterns and associated temporal evolutions. We only retain the first mode, since it captures the main deformation during both investigated periods, is the sole mode related to long-lasting (years) processes, and is less affected by noise than original data. Our analyses: (i) Confirm that most of the deformation is related to the activity of a 3–4 km deep sill-like source, which is inflated by magma and/or magmatic fluids during periods of unrest and deflates during periods of subsidence; (ii) Evidence ongoing deformation linked to local fluid migration in the Solfatara area; (iii) Identify persistent deformation features where peculiar fluid migration processes occurred during the 1982–1984 unrest; (iv) Most importantly, provide direct evidence of deep magma inflation at least since 2015, thus giving a strong warning of increasing risk at Campi Flegrei. Results demonstrate the capability of our approach to disclose hardly detectable processes and suggest a tool to monitor the activity of the deep magmatic source. Our approach can be useful also in other volcanic systems

    DInSAR Data Reveal an Intriguing Contemporaneous Onset of Deep Deflation below Vesuvio and the Ongoing Campi Flegrei Uplift

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    Campi Flegrei and Vesuvio volcanoes are only about 25 km apart, located on opposite sides of the densely inhabited area of Naples (Italy). Since neighbouring volcanoes may influence each other’s activity, it is of great interest to identify signs of any mutual interaction between Campi Flegrei and Vesuvio, or at least note coincidences in their recent deformation dynamics. After a large uplift, Campi Flegrei was generally subsiding from 1985 to 2001, while it has been uplifting—probably driven by deep magma inflation—at an accelerating rate since then. Here, we analysed the ground displacement in the whole Vesuvian area and its surroundings around the early 2000s using 1993–2010 ERS/ENVISAT ascending- and descending-orbit line-of-sight displacements obtained through the Small BAseline Subset Differential Synthetic Aperture Radar Interferometry technique. Although ground deformation is slow—a few millimetres per year—Empirical Orthogonal Function analysis shows a sudden trend change around 2001. Pre-2001 velocity maps confirm previously published results: subsidence mainly occurred inside the caldera rim—probably because of the sliding and compaction of young incoherent materials—and in a few spots around 10 km from the summital crater; eastward displacement occurred in a lobe east of Vesuvio, and westward displacement occurred in a lobe west of Vesuvio, as in the case of the spreading of the volcanic edifice and/or extensional tectonics. We attribute the subsidence spots to the previous high local number of new buildings per year. Post-2002 velocity maps provide evidence of a very different scenario: general subsidence in the whole Vesuvian area, westward displacement in a lobe east of Vesuvio, and eastward displacement in a lobe west of Vesuvio. This last arrangement of the ground displacement field is made even clearer by subtracting the post-2002 velocity from the pre-2001 value. The results of our analyses are consistent with the deflation of a deep pressurised source. Additionally, Vesuvio’s deep seismicity decreased at the beginning of 2002. The coincidence between the transition from deflation to inflation at Campi Flegrei and the onset of deflation below Vesuvio may suggest the possible transfer of magma and/or magmatic fluids between the two plumbing systems

    An Approximate Approach to Nonisothermal Emplacement of Kilometer-Sized Kilometer-Deep Sills at Calderas

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    Caldera unrest is often caused by kilometer-sized kilometer-deep sills. Still unanswered questions include the following: How do sills spread? Why can magma propagate for kilometers without solidifying? Why do ground deformation data rarely, if ever, detect sill propagation? We show that kilometer-sized kilometer-deep magmatic sills spread like hydraulic fractures in an infinite medium. How magma propagates depends on overburden pressure, magma viscosity, injection rate, and difference between magma and rock temperatures. A small lag, filled with vapors from the fluid and/or the rock, exists between the propagating magma and fracture fronts. If the sill spreads along an interface, the lag slightly affects isothermal sill spreading but takes a key role in the case of nonisothermal propagation: A sill would stop after few tens of meters without it, unless magma intrudes rocks that are as hot as the solidification temperature or has unrealistic overpressures, because spreading velocity decreases soon to the critical value at which the tip becomes blocked with solidified magma. The lag defers magma solidification as heat exchange between the magma and the rock is effective only behind the thermal-insulating lag, where magma has some finite thickness and sill opening grows with distance from the tip faster than thickness of solidified magma. Thus, the critical velocity decreases, allowing greater maximum sill sizes. We also show that the ground deformation pattern does not change appreciably over time if the final sill radius is smaller than 2 to 3 km, explaining why deformation is usually attributed to the inflation of a stationary source

    Base or copper promoted annulation reactions of α-aminohydrazones

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    The title compounds, obtained by 1,4-addition of sarcosine or glycine ethyl ester on conjugated azoalkenes, gave the 1-ureido-4-amino-3-methyl-1H-pyrazol-5(2H)-ones through a base promoted heterocyclization process, while in the presence of copper (I) species the 1-ureido-5-methyl-4-imidazolines and the 4-methoxycarbonyl-5-methyl-1-ureidoimidazole were obtained. The mechanism of these reactions is discussed

    Long-period toroidal earth free oscillations from the great Sumatra-Andaman earthquake observed by paired laser extensometers in Gran Sasso, Italy

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    Strain data recorded by two crossed laser extensometers operating in the Gran Sasso underground observatory recorded seismic free oscillations excited by the 2004 December 26 Sumatra–Andaman earthquake. The main source of instrumental noise can be mitigated by differencing data from the crossed strainmeter arms, so that the resulting differential strain data set offers an unprecedented resolution of the seismic toroidal free oscillations with periods T > 1000 s.We reconstruct the time evolution of selected free-oscillations for comparison with synthetic seismograms that include normal-mode coupling effects from Coriolis force, attenuation and ellipticity. Envelopes estimated for the Gran Sasso differential data set for free oscillations with period T < 1000 s (frequencies f > 1 mHz) are approximated adequately by a composite Centroid–Moment–Tensor (CMT) source with five subevents and an aggregate Mw = 9.3 moment-magnitude. Envelopes for several toroidal free oscillations with T > 1000 s are predicted less well. The amplitude of the rarely observed mode 0T 2 is overpredicted at Gran Sasso by roughly a factor of two, and other modes are underpredicted. The amplitude discrepancy for 0T 2 is confirmed at selected exceptionally low-noise seismic stations. Hypothetical explanations include a slow-slip component of the seismic moment release, errors in the composite-CMT source model, unmodelled coupling effects to Earth’s secular modes and feedback from the Sumatra–Andaman tsunami on Indian Ocean coastlines. Of these hypotheses, either an extended-duration strain release or tsunami feedback seem most plausible. The viability of the tsunami-feedback mechansim deserves further investigation
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