1,721,207 research outputs found
Optically Active Alkylvinylpyridines: Synthesis of (+)-(S)-6-1-Methylpropyl)-2-vinylpyridine
No full textStereospecific hydrodehalogenation of alkenyl bromides: a new approach to the synthesis of (E)-alkenes
No full textOptically Active 2,2':6',2”-Terpyridine: Synthesis of 6-[6,6-Dimethylnorpynan-2-yl]- and 6,6''-Bis[6,6-Dimethylnorpynan-2-yl]-2,2':6',2”-terpyridine
No full textMetal-complexes of optically active amino- and imino-based pyridine ligands in asymmetric catalysis
No full textSynthesis of Chiral Pyridines by Cobalt(I)-Catalyzed Cocyclotrimerization of Acetylene with Optically Active Nitriles
No full textChiral Ligands Based on the Pyridine Framework: Synthesis and Application in Asymmetric Catalysis
No full textNew Chiral C2-Symmetric Bis(oxazolinylpyridinyl)dioxolane Ligands for Asymmetric Catalysis: Palladium Catalyzed Allylic Substitution
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Synthesis and application in asymmetric catalysis of camphor-based pyridine ligands
No full textThis tutorial review deals with the synthesis and application in asymmetric catalysis of camphor-based pyridine ligands. These ligands can be roughly divided into two groups: those in which the camphor is annulated in the 2,3-positions to the β-face of the pyridine ring and those in which the pyridine is contained as a pendant on the C2 or C3 of the camphor framework. Camphor-based pyridine ligands can also contain other donor centers located on the pyridine ring or camphor skeleton. Some of these ligands have provided interesting enantioselectivities in several asymmetric reactions, such as SN2′ reactions, allylic oxidations, carbonyl additions with organozinc reagents and hydrogenations. This review contains a lot of chemistry on ligand synthesis and readers will find it of value and also perhaps an inspiration for the development of more active and improved versions
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