243 research outputs found

    The EPR study of Mn2+ ion doped DADT single crystal produced under high pressure and temperature

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    ceylan, umit/0000-0002-1461-9889WOS: 000365367100085PubMed: 26137878An EPR study on Cu2+ and VO2+ doped di ammonium D-tartrate single crystals has been reported in previous papers, but the same host did not accept Mn2+ ion at the same reaction conditions in previous trials. In this study EPR study of Mn2+ ion doped di ammonium D tartrate single crystal, (DADT) [(NH4)(2)C4H4O6], produced in a reactor under high pressure and high temperature. The electronic transitions were determined by the optical absorption spectrum. Hyperfine splitting and g values of the Mn2+ ion forming a complex in the lattice were measured from experimental spectra and spin spin dipolar splitting parameters D and E were found by the spectrum simulation techniques. (C) 2015 Elsevier B.V. All rights reserved.BAP, Ondokuz Mayis University (Samsun)Ondokuz Mayis University [PYO. FEN. 1904.09.017, FEN 1901-10.001]This work was financially supported by the BAP, Ondokuz Mayis University (Samsun) (Project numbers: PYO. FEN. 1904.09.017 and FEN 1901-10.001)

    Crystal structure, spectroscopic investigations and quantum chemical computational study of 5-(diethylamino)-2-((3-nitrophenylimino)methyl)phenol

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    13th International Conference on Molecular Spectroscopy (ICMS) - From Molecules to Molecular Materials, Biological Molecular Systems and Nanostructures -- SEP 09-12, 2015 -- Wroclaw, POLANDceylan, umit/0000-0002-1461-9889; ozdemir tari, gonca/0000-0001-5919-1778WOS: 000385605800010The Schiff base compound, 5-(diethylamino)-2-((3-nitrophenylimino)methyl)phenol, C17H11O3N3, was synthesized and characterized by IR, UV-Vis and single-crystal X-ray diffraction (XRD) technique. The title compound prefers enol tautomeric form in solid state as to X-ray, IR and UV-Vis spectra results. Also, using the TD-DFT method, the electronic absorption spectra of the title compound was computed in both the gas phase and ethanol solvent. The calculated results support that the enol form is more stable than keto form. The molecular geometry from the X-ray single-crystal determination of the title compound in the ground state was compared at the B3LYP and B3PW91 levels of the density functional method (DFT) with the 6-311 + G(d,p) basis set. The harmonic vibrational frequencies of the title compound were calculated using the B3LYP and B3PW91 methods with the 6-311G+(d,p) basis set. The calculated results were compared with the experimental determination results of the compound. The potential energy surface scans about important torsion angels were performed by B3LYP/6-311 + G(d,p) level of theory for the title compound. The energetic behaviors of the title compound in the solvent media were also examined using the B3LYP and B3PW91 methods with the 6-311 + G(d,p) basis set applying the Onsager and the polarizable continuum model (PCM). Besides, the molecular electrostatic potential map (MEP), frontier molecular orbitals (FMO) analysis and thermodynamic properties for the title compound were obtained with the same levels of theory. The nonlinear optical properties (NLO) of the title compound were performed in the solvent media using the B3LYP and B3PW91 methods with the 6-311 + G(d,p) level using the PCM model. (C) 2016 Elsevier B.V. All rights reserved.Mayor Wroclaw, European Acad Scie, Arts & Humanitie

    Competency based training needs assessment

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    Soyadı: Zeynep Ümit Ceylan Kamu Yönetimi Human Resources Management & Development Prof.Dr.İnci Artan Erem Tez Türü ve Tarihi : Yüksek Lisans – Temmuz 2006 Yetkinlik, Eğitim İhtiyaçları, İhtiyaç AnaliziYETKİNİLİK BAZLI EĞİTİM İHTİYAÇ ANALİZİ Bu çalışmanın amacı, firmaların eğitim ihtiyaç analizi üzerine olan çalışmalarını değerlendirmek ve bu amaçla eğitim ihtiyaç analizlerini yetkinlik değerlendirmeleri ile yapıp yapmadığını, eğitim ihtiyacının belirlenmesinde kullanılan teknikleri kullanıp kullanmadıklarını ya da hangilerini kullandıklarını, eğitim planlarının kişilerin yetkinlikleri ile örtüşüp örtüşmediğini ve değerlendirmelerin ünvanlara göre spesifik olarak yapılıp yapılmadığı yönündeki görüşleri ortaya çıkarmaktır. Bu çalışmada, eğitim ihtiyaç analizlerinin yetkinliklere dayandırılarak yapılması gerekliliği savunulmuştur. Bu durumu incelemek amacıyla, 116 kişiden geri dönen 21 soruluk bir anket uygulanmıştır. Anket sonuçları, çoğunluğun eğitim ihtiyacı analizi yaptığını ve bu uygulamayı da yetkinlikler bazında değerlendirdiği görüşünü ispatlamıştır. Araştırma aynı zamanda, kişilerin iş tanımlarını yerine getirmek üzere gerekli yetkinlik düzeylerine sahip olduklarını ve iş tanımları kapsamında gerekli mesleki/ teknik eğitimleri aldıklarını da ortaya koymuştur. Ancak eğitim planlaması konusunda herkese eşit fırsat sağlanması konusunda belli bir miktarda inançsızlık tespit edilmekle birlikte, üst düzey çalışan kesiminin öncelik sırası olduğu görüşü de ortaya çıkmıştır. Bu durum, eğitim ihtiyaç analizi uygulaması içindeki bazı sistem aksaklıklarına işaret etmektedir. Name and Surname: Zeynep Ümit Ceylan Field: Kamu Yönetimi Programme:Human Resources Management and Development Supervisor: Prof.Dr.İnci Artan Erdem Degree Awarded and Date: Master – July 2006 Competencies, Training Period, Needs Analysis ABSTRACT COMPETENCY BASED TRAINING NEEDS ASSESSMENT Tha aim of this study is to assess the companys’ works on the training needs assessment and for this purpose to identify whether they determine the training needs according to the competencies, use the techniques in the needs assessment, do the competencies match with training plans individually and assess the competencies related with the job titles. In this study, it’s been defensed that, training needs assessments should be made according to the competencies. To observe this situation, a questionnaire consists of 21 questions were applied and 116 of them came back. The research proved that the majority of all, determine the training needs and base this on to the competencies. The research also exposed that, employees owned the necessary competencies to perform their tasks and got all the technical/ occupational trainings related with their job. Nevertheless, with a small ratio, a disbelief is met against to giving equal opportunity in making the training plans of the employees. They believed executives have priority in the training plans. This exposed that, some application defects exist in the training needs assessment

    Correction to: Micro-encapsulation exhibits better protection than nano-encapsulation on phenolics before and after in vitro digestion (Journal of Food Measurement and Characterization, (2024), 18, 12, (9890-9905), 10.1007/s11694-024-02927-7)

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    The original version of this article unfortunately contained error in co-author’s affiliation. The affiliation of author Ümit Altuntaş were incorrectly given as Department of Food Engineering, Faculty of Chemical and Metallurgical Engineering, Istanbul Technical University, Maslak, Istanbul TR-34469, Turkey but should have been Department of Food Engineering, Gümüşhane University, Gümüşhane, Turkey. The original article has been corrected. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024

    Ümit Kurt

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    Ümit Kurt earned his PhD in history at the Strassler Center for Holocaust and Genocide Studies, Clark University in 2016. He is Polonsky Fellow in the Van Leer Institute in Jerusalem. Dr. Kurt is engaged in his work with examining transfer of Armenian wealth, transformation of space, elite-making processes, ordinary perpetrators, collective violence, microhistories, inter-ethnic conflicts, the Armenian genocide, late Ottoman legal-economic history, and early modern Turkish nationalism. He has taught at Clark University, Fresno State University, Hebrew University of Jerusalem, University of Tel Aviv and Sabancı University. He was the recipient of the prestigious Armenian Studies Scholarship Award from the Calouste Gulbenkian Foundation in Lisbon. He worked as a postdoctoral fellow in 2016–17 at the Center for Middle Eastern Studies at Harvard University. He is the author of Antep 1915: Genocide and Perpetrators (2018) and co-author of The Spirit of the Laws: The Plunder of Wealth in the Armenian Genocide (2015). His forthcoming book, The Armenians of Aintab: The Economics of Genocide in an Ottoman Province, will be published in Spring 2021 by the Harvard University Press.https://commons.erau.edu/genocide-bios/1041/thumbnail.jp

    Symbolic Reflections Of The Soul In Nuri Bilge Ceylan's Cinema: Representation Of Trees And Quest For Meaning

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    İnsanın en kadim dostu olan ağaç, dünya kültürlerinde ortak unsurlardan biridir. Eski insanlar ağaçları, toprak altından gökyüzüne ulaşan boyu, uzun yaşamı ve yüceliği nedeniyle Tanrı ile bağ kurmaya aracı olabilecek yüce bir varlık olarak düşünmüşlerdir. Hayat ağacı kavramı, bütün inanç sistemlerinde yer almıştır. Efsanelere, mitolojilere konu olan ağaç; doğaldır ki sanatta da yer bulmuştur. Edebiyattan resme, şiirden felsefeye; fotoğraftan sinemaya, ağaç ya doğrudan ya da metaforik olarak anlam katmanları oluşturmuştur. Türk sinemasının önemli isimlerinden olan fotoğraf kökenli sinemacı, auteur yönetmen Nuri Bilge Ceylan filmlerinde doğaya ve doğanın karakterlerle olan ilişkisine önem vermiştir. Yönetmen, anlatım dilini güçlendiren bir öğe olarak da özellikle ağaç görselini kullanmayı tercih etmektedir. Ağaç, doğanın döngüsü, hayatın geçiciliği ve aynı zamanda insanların içsel yolculuklarını temsil etmektedir. Ceylan’ın filmlerinde yansıtmak istediği derin melankoli, yalnızlık ve boşluk hissi; boş yollar, kar yağışı ve ağaç temasıyla örülmüştür. Mevsim geçişleri ve dolayısıyla zamanın geçişi çoğu sahnede ağacın temsiliyeti ile görülmektedir. Onun sinemasında ağaçların temsili ve anlamı, sadece görsel bir motif olarak kalmaz; aynı zamanda anlatısını destekleyen ve güçlendiren bir unsurdur. Bu eksende çalışmanın amacı, Ceylan’ın görsel anlatıda sıklıkla kullandığı motiflerden biri olan ağaçların sinemasındaki yerini ve anlamını analiz etmek ve metaforik olarak kullanımını irdelemektir. Bunun için konuyla ilişkili doküman incelemesi, film taraması ve betimsel analiz tekniği birlikte kullanılmıştır. Bu yöntemlerin birlikte kullanılmasının çalışmanın metodolojisi açısından uygun olacağı düşünülmektedir. Dolayısıyla çalışma, sinema ve sanat alanındaki ilgili araştırmalara yeni bir bakış açısı sunarak, Ceylan sinemasının özgün ve etkileyici yönlerini daha iyi anlamamıza katkı sağlayacağı düşünülmektedir.The tree, which is humanity's most ancient companion, is a common element in world cultures. Ancient peoples considered trees to be noble entities capable of connecting with the divine due to their towering height reaching from the ground to the sky, long lifespan, and grandeur. The concept of the tree of life has appeared in all belief systems. Trees, which are subjects of legends and mythology, naturally found their place in art. From literature to painting, poetry to philosophy, from photography to cinema, trees have created layers of meaning either directly or metaphorically. Nuri Bilge Ceylan, a auteur director in Turkish cinema and a filmmaker with a background in photography, has emphasized the relationship between nature and characters in his films. The director particularly prefers to use the visual imagery of trees as a storytelling device, which strengthens the narrative language. Trees symbolize the cycle of nature, the transience of life, and simultaneously represent the inner journeys of individuals. The profound melancholy, loneliness, and sense of emptiness that Ceylan aims to reflect in his films are woven with themes of empty roads, snowfall, and the motif of trees. The transitions of seasons and hence the passage of time are often depicted through the representation of trees in many scenes. In his cinema, the representation and significance of trees go beyond being merely visual motifs; they are elements that support and reinforce the narrative. In this context, the aim of this study is to analyze the place and meaning of trees in Ceylan’s cinema, one of the motifs frequently used in his visual narrative, and to examine their metaphorical use. For this purpose, document analysis, film scanning, and descriptive analysis techniques related to the subject have been used together. It is believed that the combination of these methods is appropriate for the methodology of the study. Therefore, the study is expected to offer a new perspective on relevant research in cinema and art, contributing to a better understanding of the unique and impactful aspects of Ceylan’s cinema

    The Microbiological Quality of Tantuni

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    Objective:In this study microbiological quality of tantuni that have been consumed in the province of Van was examined. Materials and Methods:For this purpose; a total of 100 tantuni samples, whose 79 of them were red meat tantuni (raw and cooked) and 21 of them chicken tantuni (raw and cooked) were used as material. Results:According to analysis findings with regard to aerobic mesophilic organisms, coliform group micro-organisms, E. coli, micrococcus/staphylococcus, S. aureus, C. perfringens and yeast-mould at the samples of raw and cooked red meat tantuni were found to be 5.67 and 3.98, 2.88 and 0.21, 0.87 and <2.00, 2.99 and 2.27, 1.33 and 0.25, 0.05 and <1.00, 4.43 and 0.63 log cfu/g respectively. In the same order, at the samples of raw and cooked chicken tantuni were found to be; 4.35 and 3.77, 2.84 and <1.00, 1.15 and <2.00, 0.95 and 1.22, <2.00 and <2.00, <1.00 and <1.00, 4.05 and 0.11 log cfu/g respectively. Salmonella spp. could not be isolated in the tantuni samples that had been investigated. In the raw red meat tantuni samples 5.26% (1/19) had S. aureus, in the cooked red meat tantuni samples 1.66% (1/60) had S. aureus, and 3.33% (2/60) yeast-mould which were not compatible with the limit values that were stated at the Turkish Food Codex were found. However values obtained from this study show that during preparation and production of the goods and in the other stages; hygienic rules have not been carried out. Conclusion: In conclusion to secure the product safety, it is essential to be cautious for the temperature and time during preparation, reservation temperature and GMP/GHP based applications in the preparation of tantuni.[No abstract available

    The effect of 8-week basic movement skills on child body coordination

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    Amaç: 8 haftalık temel hareket becerilerinin Çocuk Beden Koordinasyonu üzerine etkisi incelenmiştir. Materyal ve Metot: Çalışmaya 7-10 yaş arası toplam 40, 20 kız 20 erkek öğrenci gönüllü olarak katılmıştır. İlk antropometrik ölçümleri yapılan çocukların motor gelişim düzeylerini ölçmek için Çocuk Beden Koordinasyonu motor beceri testi uygulanmıştır. Verilerin İstatistik değerlendirmelerinde IBM SPSS 22 paket programı kullanılmıştır. 8 haftalık süreçte çalışma grubu öğrencilere (10 kız-10 erkek) Fiziksel Etkinlik Kartlarının Sarı kartlar bölümü ile haftada iki gün (salı-cuma) bir saat antrenmanlar yaptırılmıştır. 8 hafta sonunda son test verileri alınarak veriler değerlendirilmiştir. Bulgular: Çocuk Beden Koordinasyonu testinde öğrencilerin almış oldukları puanlar değerlendirildiğinde çalışma grubundaki öğrencilerin performanslarının kontrol grubuna kıyasla anlamlı düzeyde farklılık gösterdiği tespit edilmiştir (p < 0,05). Bu farklılık, hem erkek hem de kız öğrencilerde gözlemlenmiştir. Çalışma grubunda yer alan erkek öğrencilerin genel toplam puanlarında belirgin bir artış kaydedilmiş olup, son test sonuçlarına göre çalışma grubundaki erkek öğrencilerin puan ortalaması 203,90±30,17 olarak ölçülmüştür. Buna karşın, kontrol grubundaki erkek öğrencilerin son test puan ortalaması 141,40±43,79 olarak belirlenmiştir. Bu sonuç, çalışma grubu erkek öğrencilerinin koordinasyon düzeylerinde önemli bir iyileşme olduğunu göstermektedir. Benzer şekilde, çalışma grubundaki kız öğrencilerin toplam puanlarında da dikkat çekici bir artış görülmüştür. Çalışma grubundaki kız öğrencilerin son test puan ortalaması 188,00±25,39 iken, kontrol grubundaki kız öğrencilerin puan ortalaması 162,50±22,70 olarak hesaplanmıştır. Bu bulgu, kız öğrencilerde de çalışma grubunun uygulamalarının koordinasyon becerilerini geliştirme açısından etkili olduğunu göstermektedir. Genel olarak, Çocuk Beden Koordinasyonu testi toplam puanları açısından, çalışma grubu ile kontrol grubu arasında istatistiksel olarak anlamlı bir farklılık olduğu ortaya çıkmıştır (p < 0,05). Elde edilen sonuçlar, çalışma grubunda uygulanan yöntemlerin çocukların koordinasyon becerilerini geliştirmede etkili olduğunu ve bu etkinin hem erkek hem de kız öğrencilerde anlamlı düzeyde iyileşme sağladığını göstermektedir. Sonuç: Fiziksel Etkinlik Kartları ile yapılan temel hareket becerisi uygulamalarının, 7-10 yaş aralığındaki ilkokul öğrencilerinin beden koordinasyonunu geliştirmede etkili olduğu ve bu etkinin çalışma grubu lehine anlamlı bir fark sağladığı sonucuna ulaşılmıştır (p < 0,05).Objective: The effect of 8 weeks of basic movement skills on children's body coordination was examined. Material and Method: A total of 40 students, 20 girls and 20 boys between the ages of 7-10, participated in the study voluntarily. The Child Body Coordination motor skill test was applied to measure the motor development levels of the children whose first anthropometric measurements were made. IBM SPSS 22 package program was used in the statistical evaluations of the data. During the 8-week period, the study group students (10 girls-10 boys) had one hour of training with the Yellow Cards section of the Physical Activity Cards two days a week (Tuesday-Friday). The data was evaluated by taking the post-test data at the end of 8 weeks. Results: When the scores of the students in the Child Body Coordination test were evaluated, it was determined that the performances of the students in the study group were significantly different compared to the control group (p < 0.05). This difference was observed in both male and female students. A significant increase was recorded in the total scores of the male students in the study group, and according to the post-test results, the average score of the male students in the study group was measured as 203.90±30.17. In contrast, the post-test average score of the male students in the control group was determined as 141.40±43.79. This result shows that there was a significant improvement in the coordination levels of the male students in the study group. Similarly, a remarkable increase was also observed in the total scores of the female students in the study group. While the post-test average score of the female students in the study group was 188.00±25.39, the average score of the female students in the control group was calculated as 162.50±22.70. This finding shows that the practices of the study group were effective in developing coordination skills in female students as well. In general, it was revealed that there was a statistically significant difference between the study group and the control group in terms of the total scores of the Child Body Coordination test (p < 0.05). The results obtained show that the methods applied in the study group were effective in developing the coordination skills of children and that this effect provided significant improvement in both male and female students. Conclusion: It was concluded that the basic movement skill practices performed with Physical Activity Cards were effective in developing the body coordination of primary school students between the ages of 7-10 and that this effect provided a significant difference in favor of the study group (p < 0.05)

    Experimental and theoretical studies of (E)-2-(2-hydroxystyryl)-6-(4-methoxybenzoyl)-5-(4-methoxyphenyl)-1,2,4-triazin-3(2H)-one

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    Ozdemir, Namik/0000-0003-3371-9874; ceylan, umit/0000-0003-2888-2378; ceylan, umit/0000-0002-1461-9889WOS: 000352925500041PubMed: 25704130Crystal structure of the title compound, C26H21N3O5, has been synthesized and characterized by Fr-IR, H-1 NMR, C-13 NMR and X-ray single crystal determination. The molecular geometry was also calculated by using Gaussian 03 software and structure was optimized by using HF and DFT/B3LYP method with the 6-31G(d) basis sets in ground state. The comparison of the theoretical and experimental geometries of the title compound indicated that the X-ray parameters agree with the theoretically obtained values. It was seen that R-2 value changes from 0.015 to 0.021 angstrom for bond length and angle. The calculated vibrational frequencies are also in good agreement with the experimental results. The H-1 and C-13 NMR chemical shifts values of (E)-2-(2-hydroxystyryl)-6-(4-methoxybenzoyl)-5-(4-methoxyphenyl)-1,2,4-triazin-3(2H)-one molecule have been calculated by the GIAO method. Besides, molecular electrostatic potential maps (MEP), Mulliken charges and Nonlinear Optical effects (NLO) analysis of the compound have been calculated by the HF and B3LYP/6-31G(d) methods. (C) 2015 Elsevier B.V. All rights reserved
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