1,721,025 research outputs found
Walls comparative evaluation for the thermal performance improvement of low-rise residential buildings in warm Mediterranean climate
No full textBuildings built in warm climates are affected by severe overheating problems in summer, which negatively affects people's comfort and health. For these reasons, many users are forced to install cooling systems, leading to an increase in costs, consumption and a meaning impact on the environment. This study gives a valid method to monitor the overheating problems in buildings located in Mediterranean climates, without the use of cooling systems, but just with an accurate design of the envelope. The main challenge is to demonstrate that the hourly monitoring of the internal operative temperature (TOP), in accordance with the UNI EN ISO 52016, is able of defining univocally the performances of the building, taking into consideration the characteristics of the envelope. The optimization of this parameter permits to reach high level of internal comfort in a building, ensuring the designer to identify the best choice of building materials that compose the envelope. The TOP trends, for a whole year, are tested on a single-residential building model located in a warm Mediterranean climate, considering different configurations of the external walls. The results put in evidence that the best solutions are characterized by the presence of the double layer of tuff, with a very massive layer in the internal side and resistive layer outside. At the end, this study demonstrates that once optimized the envelope, it is easier to reach good values of internal operative temperature with the only use of a mechanical ventilation system
Organocatalytic Enantioselective Formation of Atropisomers
No full textAsymmetric synthesis of atropisomers is an emerging and challenging field successfully addressed by organocatalysis. The versatility of chiral organic molecules in catalyzing the enantioselective formation of axially chiral compounds is reflected in the enormous number of different classes of atropisomeric structures achievable via a wide range of strategies. This chapter reports an in-depth analysis of covalent and noncovalent organocatalytic methodologies for the synthesis of important axially chiral organic scaffolds, highlighting selected examples of those fundamental strategies that are largely employed in atroposelective synthesis such as desymmetrization, kinetic and dynamic kinetic resolution, alkylation or arylation, cycloaddition, and central-to-axial chirality transfer to name a few
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Enantioselective Strategies for The Synthesis of N−N Atropisomers
Full text linkAxially chiral compounds have been always considered a laboratory curiosity with rare prospects of being applied in asymmetric synthesis. Things have changed very quickly in the last twenty years when it was understood the important role and the enormous impact that these compounds have in medicinal, biological and material chemistry. The asymmetric synthesis of atropisomers became a rapidly expanding field and recent reports on the development of N-N atropisomers strongly prove how this research field is a hot topic open to new challenges and frontiers of asymmetric synthesis. This review focuses on the recent advances in the enantioselective synthesis of N-N atropisomers highlighting the strategies and breakthroughs to obtain this novel and stimulating atropisomeric framework
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
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