1,720,954 research outputs found
Tailoring transition metal complexes for non linear optics applications - A theoretical investigation of the electronic structure of M(CO)(x)ClyL complexes (M = Cr, W, Re, Ru, Os, Rh, Ir; L = Pyz, PyzBF(3), BPE, BPEBF3)
No full textDensity functional theory (DFT) investigations of title organometallic compounds led to identification of electronic features which determine the magnitude and the orientation of the dipole moment. The analysis of our theoretical results shows that the presence of a strong acidic BF3 group, or more generally, the substitution of ligands in the M(CO)xCl yL complexes can affect the orientation of the dipole moments, out of the direction of the first charge transfer (CT) excitation and, as a consequence, the magnitude of the vector part of the second order hyperpolarizabilities
Organometallic Counterparts of Push−Pull Aromatic Chromophores for Nonlinear Optics: Push−Pull Heteronuclear Bimetallic Complexes with Pyrazine andtrans-1,2-Bis(4-pyridyl)ethylene as Linkers
No full textWe report the synthesis, electronic properties, and second-order nonlinear optical (NLO) response of asymmetric heteronuclear push-pull bimetallic complexes with pyrazine (pyz) and trans-1,2-bis(4-pyridyl)ethylene (BPE) as polarizable linkers, connecting the "W(CO)5" fragment (acting as donor group) and "cis-Rh(CO)2Cl", "cis-Re(CO)4Cl", and BF3 fragments (acting as acceptor groups). The second-order NLO response was assessed by the EFISH technique (βvec), working with a nonresonant incident wavelength of 1.907 μm and by solvatochromic studies (βCT). These results are compared with the behavior of mononuclear [W(CO)5L] complexes (L = pyridine or torss-stilbazole para substituted with acceptor groups) and of classical structurally related organic push-pull aromatic chromophores. The second-order NLO response of asymmetric chromophores with BPE as linker is comparable, with the exception of the sign, to classical push-pull stilbenic compounds. However when pyrazine is the linker, the response can be higher (BF3 as acceptor group) or higher but with opposite sign ("cis-Rh(CO)2Cl" as acceptor group) than the related push-pull benzenic chromophores. Only with a pyrazine linker and "cis-Re(CO)4Cl" as acceptor does the second-order NLO response becomes irrelevant. The above results are interpreted assuming that the MLCT (W → π*L) transition, originating from the "W(CO)5" moiety, dominates the second-order response of these push-pull heteronuclear dimeric chromophores
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
Dispelling the Myths Behind First-author Citation Counts
Full text linkWe conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued
use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation
counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more
sophisticated methods
koamabayili/VECTRON-author-checklist: VECTRON author checklist
No full textWe have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
Author-wise bibliometric analysis based on entropy.
No full textAuthor-wise bibliometric analysis based on entropy.</p
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