27 research outputs found
Wear resistance of HVOF- and HVAF-sprayed (Ti,Mo)(C,N)–Ni coatings from an agglomerated and sintered powder
No full textInfluence of hardmetal feedstock powder on the sliding wear and impact resistance of High Velocity Air-Fuel (HVAF)sprayed coatings
No full textThe present work aimed to clarify how the characteristics of WC-CoCr hardmetal feedstock powders, namely the grain size of the WC carbides and of the binder and the compressive strength of the sintered aggregates, affect the dry sliding wear and impact resistance of coatings deposited by High Velocity Air-Fuel (HVAF)spraying. Ball-on-Disc tests, which mimic a sliding wear process in the presence of hard asperities as it may occur e.g. in hydraulic seal joints or papermaking components, resulted in mild wear through near-surface microscale plastic flow, the exact nature of which was significantly affected by WC size. Finite element simulations of a single-asperity sliding process indeed showed that large WC grains concentrate contact stresses, thus undergoing very localised deformation. It is experimentally seen that repeated deformation of the carbide grains resulted in their cracking and pull-out. Uniformly distributed, fine carbides allowed the matrix to take on some stress, thus undergoing more homogeneous plastic flow. Block-on-Ring tests elicited adhesive wear as it may happen e.g. in metal-to-metal contacts (e.g. petrochemical valves). This could be effectively restrained by low matrix mean free path. Cyclic impact resistance of coarse-grained coatings was better than that of fine-grained ones, because of better large-scale cohesive strength
Sliding and abrasive wear behaviour of HVOF- and HVAF-sprayed Cr3C2-NiCr hardmetal coatings
No full textThis paper provides a comprehensive characterisation of HVOF- and HVAF-sprayed Cr3C2-25 wt.% NiCr hardmetal coatings. One commercial powder composition with two different particle size distributions was processed using five HVOF and HVAF thermal spray systems. All coatings contain less Cr3C2 than the feedstock powder, possibly due to the rebound of some Cr3C2-rich particles during high-velocity impact onto the substrate. Dry sand-rubber wheel abrasive wear testing causes both grooving and pull-out of splat fragments. Mass losses depend on inter- and intra-lamellar cohesion, being higher (≥70 mg after a wear distance of 5904 m) for the coatings deposited with the coarser feedstock powder or with one type of HVAF torch. Sliding wear at room temperature against alumina involves shallower abrasive grooving, small-scale delamination and carbide pull-outs, and it is controlled by intra-lamellar cohesion. The coatings obtained from the fine feedstock powder exhibit the lowest wear rates (≈5×10-6 mm3/(Nm)). At 400 °C, abrasive grooving dominates the sliding wear behaviour; wear rates increase by one order of magnitude but friction coefficients decrease from ≈0.7 to ≈0.5. The thermal expansion coefficient of the coatings (11.08×10-6 °C-1 in the 30-400 °C range) is sufficiently close to that of the steel substrate (14.23×10-6 °C-1) to avoid macro-cracking
Tribological Properties of Hard Metal Coatings Sprayed by High-Velocity Air Fuel Process
No full textLowering the thermal energy and increasing the kinetic energyof hard metal particles sprayed by the newly developed HVAF systems can significantly reduce their decarburization, and increases the sliding wear and corrosion resistance of the resulting coatings, making the HVAF technique attractive, both economically and environmentally, over its HVOF predecessors. Two agglomerated and sintered feedstock powder chemistries, WC-Co (88/12) and WC-CoCr (86/10/4), respectively, with increasing primary carbides grain size from 0.2 to 4.0 microns, have been deposited by the latest HVAF-M3 process onto carbon steel substrates. Their dry sliding wear behaviors and friction coefficients were evaluated at room temperature via Ball-on-disk (ASTM G99-90) wear tests against Al2O3 counterparts, and via Pin-on-disk (ASTM G77-05) wear tests against modified martensitic steel counterparts in both dry and lubricated conditions. Sliding wear mechanisms, with the formation of wavy surface morphology and brittle cracking, are discussed regarding the distribution and size of primary carbides. Corrosion behaviors were evaluated via standard Neutral Salt Spray, Acetic Acid Salt Spray, accelerated corrosion test, and electrochemical polarization test at room temperature. The optimization of the tribological properties of the coatings is discussed, focusing on the suitable selection of primary carbide size for different working load applications
Tribology of HVOF- and HVAF-sprayed WC-10Co4Cr hardmetal coatings: A comparative assessment
No full textThis paper provides a comprehensive assessment of the sliding and abrasive wear behaviour of WC-10Co4Cr hardmetal coatings, representative of the existing state-of-the-art. A commercial feedstock powder with two different particle size distributions was sprayed onto carbon steel substrates using two HVOF and two HVAF spray processes. Mild wear rates of <10-7mm3/(Nm) and friction coefficients of ≈0.5 were obtained for all samples in ball-on-disk sliding wear tests at room temperature against Al2O3 counterparts. WC-10Co4Cr coatings definitely outperform a reference electrolytic hard chromium coating under these test conditions. Their wear mechanisms include extrusion and removal of the binder matrix, with the formation of a wavy surface morphology, and brittle cracking. The balance of such phenomena is closely related to intra-lamellar features, and rather independent of those properties (e.g. indentation fracture toughness, elastic modulus) which mainly reflect large-scale inter-lamellar cohesion, as quantitatively confirmed by a principal component analysis. Intra-lamellar dissolution of WC into the matrix indeed increases the incidence of brittle cracking, resulting in slightly higher wear rates. At 400°C, some of the hardmetal coatings fail because of the superposition between tensile residual stresses and thermal expansion mismatch stresses (due to the difference between the thermal expansion coefficients of the steel substrate and of the hardmetal coating). Those which do not fail, on account of lower residual stresses, exhibit higher wear rates than at room temperature, due to oxidation of the WC grains.The resistance of the coatings against abrasive wear, assessed by dry sand-rubber wheel testing, is related to inter-lamellar cohesion, as proven by a principal component analysis of the collected dataset. Therefore, coatings deposited from coarse feedstock powders suffer higher wear loss than those obtained from fine powders, as brittle inter-lamellar detachment is caused by their weaker interparticle cohesion, witnessed by their systematically lower fracture toughness as well
Internal Diameter HVAF Spraying for Wear and Corrosion Applications
No full textElectrolytic hard chrome (EHC) methods are still widely utilized in the printing, automotive and off-shore industries. Alternative methods to EHC have been widely developed in the past decade by conventional HVOF processes and more recently HVAF systems, which are processing at higher kinetic energy and more particularly at lower temperature, significantly increasing wear and corrosion resistance properties. A dedicated internal diameter HVAF system is here presented, and coatings characteristics are compared to the one obtained by standard HVAF coatings. Specially R&D designed fixtures with inside bore of 200 mm have been manufactured for this purpose, with a possibility to spray samples at increasing depth up to 400 mm while simulating closed bottom bore spraying. WC-based and Cr3C2-based powder feedstock materials have been deposited onto high-strength steel substrates. Respective coating microstructures, thermally induced stresses and corrosion resistance are discussed for further optimization of coating performances. The fact that the ID-HVAF system is utilized both for spraying and gritblasting procedures is also given a particular interest.</p
Presentations to the emergency department with non-medical use of benzodiazepines and Z-drugs: profiling and relation to sales data.
No full textBACKGROUND: Non-medical use of benzodiazepines and Z-drugs is common; however, there is limited information available on the extent of harm related to this in Europe, as well as the relationship between misuse and availability.
AIM: To describe presentations to the emergency department in Europe related to the recreational use of benzodiazepines and Z-drugs and compare regional differences in these presentations with legal drug sales of benzodiazepines and Z-drugs within each country.
METHODS: Emergency department presentations with recreational misuse of benzodiazepines and Z-drugs were obtained from the Euro-DEN dataset for the period from October 2013 to September 2015; data extracted included demographics, clinical features, reported coused drugs, and outcome data. Sales figures obtained by QuintilesIMS™ (Atlanta, Georgia) were used to compare regional differences in the proportion of benzodiazepines and Z-drugs in the emergency department presentations and legal drug sales across Europe.
RESULTS: Over the 2 years, there were 2119 presentations to the Euro-DEN project associated with recreational use of benzodiazepines and/or Z-drugs (19.3% of all Euro-DEN presentations). Presentations with 25 different benzodiazepines and Z-drugs were registered in all countries, most (1809/2340 registered benzodiazepines and Z-drugs, 77.3%) of which were prescription drugs. In 24.9%, the benzodiazepine was not specified. Where the benzodiazepine/Z-drug was known, the most frequently used benzodiazepines and Z-drugs were respectively clonazepam (29.5% of presentations), diazepam (19.9%), alprazolam (11.7%), and zopiclone (9.4%). The proportions of types of benzodiazepines/Z-drugs related to ED-presentations varied between countries. There was a moderate (Spain, UK, Switzerland) to high (France, Ireland, Norway) positive correlation between ED presentations and sales data (Spearman Row's correlation 0.66-0.80, p < 0.005), with higher correlation in countries with higher ED presentation rates.
CONCLUSION: Presentations to the emergency department associated with the non-medical use of benzodiazepines and/or Z-drugs are common, with variation in the benzodiazepines and/or Z-drugs between countries. There was a moderate to high correlation with sales data, with higher correlation in countries with higher ED presentation rates. However, this is not the only explanation for the variation in non-medical use and in the harm associated with the non-medical use of benzodiazepines/Z-drugs
Wear resistance of HVOF- and HVAF-sprayed (Ti,Mo)(C,N)-Ni coatings from an agglomerated and sintered powder
No full text(Ti,Mo)(C,N)-25 wt% Ni coatings obtained by spraying an agglomerated and sintered feedstock powder using different high velocity air-fuel (HVAF) and high velocity oxygen-fuel (HVOF) deposition processes are comparatively analysed for their sliding, abrasion and impact resistance. All HVOF-sprayed coatings are particularly dense, with ≈800 HV hardness (tested at 100 gf, 300 gf and 500 gf). In-flight oxidation resulted in some embrittlement, as revealed by scratch tests. In ball-on-disk sliding against an Al2O3 counterpart, they maintained a mild wear regime (wear rates ≤10−6 mm3/(N⋅m)) from room temperature up to 600 °C, with better performance in comparison to Cr3C2–NiCr reference coatings. At room temperature, the Ti(C,N) hard phase limited the abrasive cutting by counterbody asperities. At 400 °C and 600 °C, the coatings developed a thin, protective oxide tribofilm. They also exhibited no interface delamination in cyclic impact tests. However, they suffered higher wear (≈3–5 × 10−3 mm3/(N⋅m)) in high-stress particle abrasion testing, particularly when compared to HVAF-sprayed Cr3C2–NiCr. Gaining improved control over in-flight oxidation of (Ti,Mo)(C,N)–Ni during spraying is probably the key to overcome this limitation. The HVAF-sprayed (Ti,Mo)(C,N)–Ni coating exhibited severe interlamellar decohesion under all test conditions, as the limited melting degree of the feedstock did not compensate for the intrinsic microstructural inhomogeneity of the powder particles.512-51
Residual Stresses Distribution Through Thick HVOF Sprayed Inconel 718 Coatings
No full textResidual stress build up in thick thermal spray coatings is a property of concern. Coating adhesion to the substrate
is influenced by residual stresses that are generated during the coating deposition process. In the HVOF spray
process, significant peening stresses are generated during impact of semi molten particles on the substrate. The
combination of these peening stresses together with quenching and thermal mismatch stresses can be of
significant importance. Both numerical Finite Element Method (FEM), to calculate peening, quenching stresses, and
experimental methods, i.e. Modified Layer Removal Method (MLRM) and Neutron Diffraction, have been utilised in this work. The investigation was performed on thick Inconel 718 coatings on Inconel 718 substrates. Combined, these numerical and experimental techniques yield a deeper understanding of residual stress formation in the HVOF process and thus a tool for process optimisation. The relationship between the stress state and deposit/substrate thickness ratio is given particular interest
