1,720,996 research outputs found
Citric acid bioproduction: the technological innovation change
Full text linkCitric acid is considered one of the most valuable weak organic acids on the market and its production by biotechnological approaches is a very interesting topic. Despite the related scientific research, the literature still lacks a state of the art for the technological innovation change, necessary for a study of the inventions designed for real scale implementation. In this context, the present review looks to account for more than 100 worldwide patents (1929–2018), necessary for the identification of the innovative markets and the most promising fields for economic investments. This deepened study identified an increasing invention number, combined with the current worldwide citric acid export flows, with China as the leader (with an economic contribution of 75%, in 2017). In order to satisfy the requests of the market which has moved toward a circular economy, the possibility to use waste substrates represents one of the main options considered in the recent patents. The discussion highlights the sustainability improvement, achieved by the conversion from a submerged technology to a solid-state fermentation (koji process). The listed results are essential for both a scientific audience and the stakeholders involved in citric acid production, in order to have a complete and updated overview of this topic
Biotechnology for metal recovery from end-of-life printed circuit boards with Aspergillus niger
Full text linkThe growing production and use of electric and electronic components has led to higher rates of metal consumption and waste generation. To solve this double criticality, the old linear management method (in which a product becomes waste to dispose), has evolved towards a circular approach. Printed circuit boards (PCBs) are the brains of many electronic devices. At the end of their life, this equipment represents a valuable scrap for the content of basemetals such as Cu and Zn (25 and 2 wt %, respectively) and precious metals such as Au, Ag, and Pd (250, 1000, and 110 ppm, respectively). Recently, biotechnological approaches have gained increasing prominence in PCB exploitation since they can be more cost-efficient and environmentally friendly than the chemical techniques. In this context, the present paper describes a sustainable process which uses the fungal strain Aspergillus niger for Cu and Zn extraction from PCBs. The best conditions identified were PCB addition after 14 days, Fe3+ as oxidant agent, and a pulp density of 2.5% (w/v). Extraction efficiencies of 60% and 40% for Cu and Zn, respectively, were achieved after 21 days of fermentation. The ecodesign of the process was further enhanced by using milk whey as substrate for the fungal growth and the consequent citric acid production, which was selected as a bioleaching agent
Acetic acid bioproduction: The technological innovation change
No full textAcetic acid is an organic acid of great importance globally and the demand of this product is currently increasing. The production of this acid has consequently aroused more and more interest over the years, especially for more sustainable processes. From a biological point of view, acetic acid can be produced by acetogenesis using inorganic substrates like CO2 or CO (with acetogenic bacteria) and aerobic fermentation (with acetic acid bacteria or fungi). With the aim of investigating the progress of technological innovation, the methodology applied by this review was an analysis of the international patents with the Espacenet platform, which ensured a worldwide invention overview. Another criterion was the selection of a precise period of time, from 1990 to 2020. A patent review is able to create an overview of the inventions designed for the real scale implementation, providing a whole picture of the state of the art of the technological innovation change. In addition, the most representative works of literature, that consider the influence of operating conditions (T, pH, oxygenation), have been analysed for each process. The present review, with an innovative approach focused on the technological innovation change, highlighted the ongoing interest for acetic acid bioproduction by acetogenic and acetic acid bacteria. The number of patents related to acetic acid bacteria was consistent also in the past years, but recently the interest is moving forward the utilization of genetic engineering (36% of the patents) and new substrates, like agriculture waste (26% of the patens), responding to circular economy principles. On the other hand, the acetic acid production by acetogenic bacteria is most recent, with over the 90% of the patents developed in the last 10 years. In this case the interest is mainly focused on the use of synthesis gas as substrate, that could increase the process sustainability
An innovative biotechnology for metal recovery from printed circuit boards
No full textThe increase of waste from electric and electronic equipment has pushed the research towards the development of high sustainability treatments for their exploitation. The end-of-life printed circuit boards (PCBs) represent one of the most significant waste in this class. The interest for these scraps is due to the high Cu and Zn content, with concentrations around 25% and 2% respectively, combined with further precious metals (e.g. Au, Ag, Pd). Currently, the most common approaches developed for PCBs recycling include pyrometallurgical and hydrometallurgical treatments. On the other hand, biohydrometallurgical strategies are gaining increasing prominence, for the possibility to decrease both the environmental and the economic costs. Nevertheless, these techniques show the main limit due to the possibility to treat low quantities of waste, which makes unsustainable the further scale-up. To overcome this criticality, the present paper introduces an innovative bioleaching process carried out by Acidithiobacillus ferrooxidans (At. ferrooxidans) and Leptospirillum ferrooxidans (L. ferrooxidans). The developed technology allows to reach high PCB concentration, up to 5% (w/v), thanks to a high efficiency two-step design, able to reduce the metal toxicity on the bacteria metabolism. The treatment uses the ferric iron generated by bacterial oxidation, as oxidant, to leach Cu and Zn from PCBs. The possibility to overcome the solid concentration criticality is combined with high yield of 94% and 70% for Cu and Zn, respectively. The best selected conditions involve the At. ferrooxidans bacteria use at: 30°C, solid concentration of 5% (w/v), 10 g/L of Fe2+, time of treatment 9 days. The experimental results are further enhanced by the carbon footprint assessment which proved the environmental advantage, compared to both the reference chemical treatment through ferric iron and literature processes (hydrometallurgical and bioleaching approaches). The analysis explained as the PCBs concentration in the solution allows to decrease the bioreactor size with the consequent reduction of energy and raw material demand. This benefit can be translated into a 4 times reduction of the CO2-eq./kg treated PCB emissions, compared to the best bioleaching processes, reported in the literature
Environmental sustainability assessment of remediation alternatives for highly contaminated marine sediments
No full textThis study compares the environmental sustainability of five alternatives for the remediation of marine sediments of one of the most polluted coastal sites in Europe (Bagnoli-Coroglio bay, Mediterranean Sea), using the Life Cycle Assessment (LCA) methodology. The treatments are either in-situ or ex-situ, the latter requiring an initial dredging to transport the contaminated sediments to the management site. More in detail, four ex-situ remediation technologies based on landfilling, bioremediation, electrokinetic technique and soil washing were identified. These technologies are compared to an in-situ strategy currently under validation for enhancing bioremediation of the polluted sediments of the Bagnoli-Coroglio site. Our results indicate that the disposal in landfilling site is the worst option in most categories (e.g., 650 kg CO2 eq./t of treated sediment, considering the nearest landfilling site), followed by the bioremediation, mainly due to the high energy demand. Electrokinetic remediation, soil washing, and innovative in-situ technology represent the most sustainable options. In particular, the new in-situ technology appears to be the least impacting in all categories (e.g., 54 kg CO2 eq./t of treated sediment), although it is expected to require longer treatment time (estimated up to 12 months based on its potential efficiency). It can reduce the impact on climate change more than 12 times compared to the disposal and 7 times compared to bioremediation in addition to the possibility to avoid/reduce the dredging operations and the consequent dispersion of pollutants. The results open relevant perspectives towards more eco-sustainable and costly effective actions for the reclamation of contaminated marine sediments
Sustainable strategies for the exploitation of end-of-life permanent magnets
Full text linkThe growing production of green technologies (such as electric vehicles and systems for renewable electricity production, e.g., wind turbine) is increasing the rare earth element (REE) demands. These metals are considered critical for Europe for their economic relevance and the supply risk. The end-of-life permanent magnets are considered a potential secondary resource of REEs thanks to their content of neodymium (Nd), praseodymium (Pr) or dysprosium (Dy). The scientific literature reports many techniques for permanent magnet recovery. This work used a life cycle assessment (LCA) to identify the most sustainable choice, suggesting the possible improvements to reduce the environmental load. Three different processes are considered: two hydrometallurgical treatments (the first one with HCl and the other one with solid-state chlorination), and a pyrometallurgical technique. The present paper aims to push the stakeholders towards the implementation of sustainable processes for end-of-life permanent magnet exploitation at industrial scale
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Environmental sustainability analysis of case studies of agriculture residue exploitation
No full textThe agriculture sector produces significant amounts of organic residues and the choice of the management strategy of these flows affects the environmental sustainability of the sector. The scientific literature is rich with innovative processes for the production of bio-based products (BBP) from agriculture residues, aimed at the implementation of circular economy principles. Based on literature data, the present paper performed a life cycle assessment and assessed the environmental sustainability of five processes for the exploitation of rice and wheat straw, tomato pomace, and orange peel. The analysis identified as significant issues the high energy demand and the use of high impact organic solvent. The comparison of BBP with conventional products showed higher environmental loads for the innovative processes that used organic residues (except for rice straw case). The obtained results do not want to discourage the circular strategy in the agriculture sector, but rather to draw the attention of all stakeholders to the environmental sustainability aspects, focusing on the necessity to decrease the electricity demand and identify ecological agents to use in BBP manufacturing, in agreement with the most recent European policies
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