1,721,029 research outputs found

    Spatial distribution and ecological risk of potentially toxic elements in peri-urban soils of a historically industrialised area

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    The spatial distribution and ecological risk of potentially toxic elements (PTEs) were investigated in the topsoil of a peri-urban area surrounding a historical industrial complex in the Scarlino Plain in southwestern Tuscany, Italy. Superficial (0-5 cm) soil samples from 44 sites within a 1.5-km radius of the industrial district were analysed for As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sb, Sn, Tl, V and Zn concentrations after microwave-assisted acid digestion with HNO3 and H2O2. The results revealed significant contamination exceeding regulatory thresholds, predominantly caused by historical pyrite roasting and natural geochemical anomalies. The enrichment of As, Mn, Cu and Zn compared to European baselines was widespread, with As and Zn levels exceeding the Italian screening values in several samples. Principal component analysis identified distinct contamination patterns linked to land use, with the first component (PC1, 49.2% of the variance) associated with pyrite-derived PTEs (As, Cu, Cd, Pb and Zn), whereas PC2 represented geogenic inputs. Despite their combined contribution to soil contamination, this analysis effectively differentiated industrial signatures from those of natural sources. Ecological risk assessment indicated that As and Cd are major concerns in agricultural soils, where anthropogenic and natural sources overlap. These findings underscore the importance of distinguishing between natural and anthropogenic contributions to inform realistic mitigation targets and protect environmental and human health in historically impacted peri-urban areas

    Leaves and Tree Rings as Biomonitoring Archives of Atmospheric Mercury Deposition: An Ecophysiological Perspective

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    Trees mediate critical biogeochemical cycles involving nutrients, pollutants, water, and energy at the interface between terrestrial biosphere and atmosphere. Forest ecosystems significantly influence the global cycling of mercury (Hg), serving as important sinks and potential sources of re-emission through various biotic and abiotic processes. Anthropogenic Hg emissions, predominantly from industrial activities, mining, and fossil fuel combustion, have substantially altered the natural Hg cycle, intensifying ecotoxicological concerns and establishing forests as primary routes for atmospheric Hg deposition into terrestrial reservoirs. This perturbation profoundly affects global atmospheric Hg concentrations, residence times, and spatial distribution patterns. While early investigations focused on forest stands near heavily polluted areas, contemporary research has expanded to diverse ecosystems, revealing that trees provide tissues that function as temporal archives for atmospheric-terrestrial Hg exchange. Leaves capture high-resolution records of contemporary Hg dynamics at sub-annual timescales, whereas annual growth rings preserve multi-decadal chronologies of historical atmospheric exposure. Incorporating this dual temporal perspective is crucial for analysing Hg deposition trends and assessing the efficacy of environmental policies designed to control and mitigate Hg pollution. This review critically evaluates recent developments concerning the ecophysiological determinants of Hg accumulation in trees, highlighting how combined foliar and dendrochemical analytical methods strengthen our mechanistic understanding of vegetation-atmosphere Hg exchange. To enhance biomonitoring approaches, we emphasised the need for methodological standardisation, deeper integration of ecophysiological variables, and consideration of climate change implications as priority research areas. Furthermore, integrating Hg measurements with functional markers (δ13C and δ18O) and Hg isotope analyses strengthens the capacity to differentiate between physiological and environmental influences on Hg accumulation, thereby refining the mechanistic framework underlying effective tree-based Hg biomonitoring

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
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