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Hydrogeochemical changes before and during the 2019 Benevento seismic swarm in central-southern Italy
Insights into seismic precursors have been obtained in the last decades. However, a detailed understanding of hydrogeochemical anomalies prior to earthquakes still remains the aim of many research teams worldwide. In order to investigate the earthquake-groundwater relationship, between 2018 and 2020, we performed sampling surveys coupled with continuous multiparametric monitoring in Grassano spring fed by the Matese aquifer (central-southern Apennines, Italy). Hydrogeochemical changes were observed before the onset and during the 2019 Benevento seismic sequence, including dissolved CO2 increase, pH lowering, and anomalies in major ions (i.e., Ca2+, Na+, HCO3–) that later recovered to their typical concentrations. We suggest that variations in groundwater geochemistry were induced by dilatative preparatory phases of earthquakes, typical of the extensional setting. This condition allowed the deep CO2 upwelling along tectonic discontinuities, as testified by the Cext (carbon from external sources) behaviour detected in Grassano groundwater during the 2019 year. Despite the small-intermediate magnitude of the mainshock, results highlight and confirm the occurrence of a potential pre-seismic geochemical process in the fractured carbonate aquifers, similar to the one proposed in literature for the stronger 2016–2017 Amatrice-Norcia seismic sequence
Groundwater recharge distribution due to snow cover in shortage conditions (2019–22) on the Gran Sasso carbonate aquifer (Central Italy)
Aquifer recharge by the snowpack is relevant to be assessed to evaluate groundwater availability in mountainous karst regions. The recharge due to snowpack in the Gran Sasso aquifer has previously been estimated through an empirical approach using elevation gradients. To validate and quantify the coverage and persistence of the snowpack over time through an objective method, satellite images have been analysed. The Campo Imperatore plain, the endorheic basin acting as a preferential recharge area of the aquifer, plays an important role, both for the snow cover and also for the infiltration and recharge of springs. The identification of recharge areas has been validated by the stable isotope approach with the assessment of computed isotope recharge elevation based on the values and oscillations of the delta O-18 isotope recorded at the springs. The main findings confirm the high infiltration rate of Campo Imperatore plain and its direct influence on snow contribution to aquifer recharge. The extension of snow coverage out of this plain has a minor influence to recharge, highlighting that the main drivers for infiltration rate are fractured networks and karstic forms more than snow coverage on carbonate outcrops
Geothermometry and water–rock interaction modelling at Hafralækur. Possible implications of temperature and CO2 on hydrogeochemical changes previously linked to earthquakes in northern Iceland
The low enthalpy (T < 150 °C) groundwater in the HA01 borehole at Hafralækur has a long time series (2008–2018) of chemical and isotopic data. In the previous studies, the variations in chemical and isotope parameters were statistically related to seismic activity. However, the possible effect of temperature has not yet been evaluated. To fill this gap, the results obtained from the classical geothermometric equations (silica solid phases, Na/K, Na-K-Ca) were compared. However, considering that the use of classical geothermometry using the Na/K ratio or silica solid phases solubility is limited by the presence of clay minerals and alkaline conditions (i.e., the presence of pH-dependant silicate anions), new equilibria reactions between labradorite, zeolites (analcime, stilbite) and the activity of the dissolved species in the fluid are presented to overcome this problem. In addition, kinetic reaction path models are presented to trace the possible role of both temperature and CO2 during the most evident chemical variations during earthquakes
Understanding the origin and mixing of deep fluids in shallow aquifers and possible implications for crustal deformation studies. San Vittorino plain, Central Apennines
Expanding knowledge about the origin and mixing of deep fluids and the water–rock–gas interactions in aquifer systems can represent an improvement in the comprehension of crustal deformation processes. An analysis of the deep and meteoric fluid contributions to a regional groundwater circulation model in an active seismic area has been carried out. We performed two hydrogeochemical screenings of 15 springs in the San Vittorino Plain (central Italy). Furthermore, we updated the San Vittorino Plain structural setting with a new geological map and cross-sections, highlighting how and where the aquifers are intersected by faults. The application of Na-Li geothermometers, coupled with trace element and gas analyses, agrees in attributing the highest temperatures (>150◦C), the greatest enrichments in Li (124.3 ppb) and Cs (>5 ppb), and traces of mantle-derived He (1–2%) to springs located in correspondence with high-angle faults (i.e., S5, S11, S13, and S15). This evidence points out the role of faults acting as vehicles for deep fluids into regional carbonate aquifers. These results highlight the criteria for identifying the most suitable sites for monitoring variations in groundwater geochemistry due to the uprising of deep fluids modulated by fault activity to be further correlated with crustal deformation and possibly with seismicity
Groundwater–rock interactions and mixing in fault–controlled karstic aquifers. A structural, hydrogeochemical and multi-isotopic review of the Pontina Plain (Central Italy)
Karstic aquifers represent crucial water resources and are categorized as either stratigraphically or fault–controlled. This study investigates groundwater–rock interactions and mixing processes within one of the largest fault–controlled karstic aquifers in Central Italy, adjacent to the Pontina plain, which is a highly populated area where agricultural activities and climate change challenge the groundwater assessment of a complex aquifer. We conducted structural, hydrogeochemical, and multi-isotopic screening of ten selected springs with different degrees of mineralization (ranging from Ca–HCO3 to Na–Cl hydrofacies), incorporating new analyses and modeling of δ34S(SO4), δ18O(SO4), 87Sr/86Sr, and δ11B. Additionally, the reinterpretation of a seismic section provides a more detailed framework extending to depths of approximately 5–7 km that allows the identification of the geometry of normal faults, which act as pathways for upwelling fluids. Our findings reveal that hydrogeochemical compositions result from multiple interactions between karstic water and deeper fluids that have interacted with different rocks. Concentration (Na/Li) and isotope (SO4–H2O) geothermometers, coupled with geochemical modeling and trace element analysis, enabled the estimation of a water temperature equilibrium of approximately 95.5 °C, with Triassic evaporites generally corresponding to a depth of approximately 3 km and a temperature of 40 °C with magmatic rocks at approximately 1 km depth, which is likely associated with ongoing tectonics and the Quaternary tectonically controlled Volsci Volcanic Field. To obtain the latter estimate, we used a new geothermometer activity based on the equilibrium between analcime and pollucite. Furthermore, this multidisciplinary approach enhances the understanding of groundwater behavior in fault–controlled karstic aquifers, where mantle-derived CO2 dissolved in groundwater is the driving force behind water–rock interactions. Given the potential for further variations in mixing, which may worsen water quality and increase aquifer vulnerability, periodic monitoring of these processes is essential in a human-impacted environment amidst ongoing climate change
Hydrogeochemical and isotopic studies of groundwater in the Contursiarea (southern Apennines).
Going Beyond Counting First Authors in Author Co-citation Analysis
The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
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