85 research outputs found
Synthesis and Physico Chemical Properties of some Bio Active Heterocyclic Entities
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Vanillin Schiff bases: Molecular interactions in methanol and THF solutions
Get PDFEn este trabajo se estudiaron la densidad, la velocidad ultrasónica y la viscosidad desoluciones de algunas bases de Schiff derivadas de la vainillina en metanol y tetrahidrofurano(THF) a 308,15 K. A partir de los datos experimentales, se evaluarondiversos parámetros acústicos, como la compresibilidad isentrópica (κs), la funciónacústica molar de Rao (Rm), la constante de Van der Waals (b), la fuerza de relajación(r), la longitud intermolecular libre (Lf), la compresibilidad molar aparente,etc., todo lo cual ayuda a comprender las interacciones moleculares que ocurren enestas soluciones.</jats:p
Ultrasonic behavior of various chalcones in some solvents at different temperatures
Get PDFUltrasonic velocity, density and viscosity of some synthesized chalcones were measured in N,N-dimethyl formamide and chloroform at different temperatures (298.15 to 318.15 K). From these experimental data, various acoustical parameters such as specific impedance (Z), adiabatic compressibility (κs), Rao’s molar sound function (Rm), intermolecular free path length (Lf), solvation number (Sn), internal pressure (π) have been calculated in order to understand the molecular interactionsin the studied solutions. The results are interpreted in terms of molecular interactions occurring in the solutions.La velocidad ultrasónica, la densidad y la viscosidad de soluciones de algunas chalconas sintéticas se midieron en N, N-dimetilformamida y cloroformo a diferentes temperaturas (desde 298,15 hasta 318,15 K). A partir de estos datos experimentales, se calcularon diversos parámetros acústicos tales como la impedancia específica (Z), la compresibilidad adiabática (ks), la función de sonido molar de Rao (Rm), la longitud de trayecto libre intermolecular (Lf), el número de solvatación (Sn) y la presión interna (Π), para comprender las interacciones moleculares en las soluciones estudiadas. Los resultados se interpretan en términos de las posibles interacciones moleculares que ocurren en las soluciones
Synthesis, characterization and antibacterial screening of some Schiff bases derived from pyrazole and 4-amino antipyrine
Get PDFSome Schiff bases of pyrazole and 4-amino antipyrine have been synthesized. The antibacterial screening of these synthesized compounds was done in dimethyl forma-mide against four Gram positive bacteria viz. Bacillus cereus, Staphylococcus aureus, Staphylococcus epidermidids and Micrococcus luteus, and three Gram negative bacteria viz. Proteus mirabilis, Escherichia coli and Klebsiella aerogenes. It is observed that in comparison to Schiff bases of 4-amino antipyrine, pyrazole Schiff bases are better for inhibition for these selected Gram positive and Gram negative bacterial strains.Se sintetizaron algunas bases de Schiff a partir de pirazol y 4-amino antipirina. La evaluación de la actividad antibacteriana de estos compuestos en dimetil formamida se realizó frente a cuatro bacterias Gram positivas, Bacillus cereus, Staphylococcus aureus, Staphylococcus epidermidids y Micrococcus luteus, y frente a tres bacterias Gram negativas, Proteus mirabilis, Escherichia coli y Klebsiella aerogenes. Se observó mejor inhibición bacteriana frente a las diferentes cepas para las bases de Schiff basadas en pirazol comparadas con aquellas basadas en 4-amino antipirina
Study of some properties of cyanopyridine derivatives in solutions
Get PDFSome new cyanopyridine derivatives have been synthesized and their characterization was done by IR, 1H NMR and mass spectral data. Further, some physicochemical properties such as density, refractive index, conductance etc. have been studied for these synthesized compounds, in different solvents at 308.15 K.Some new cyanopyridine derivatives have been synthesized and their characterization was done by IR, 1H NMR and mass spectral data. Further, some physicochemical properties such as density, refractive index, conductance etc. have been studied for these synthesized compounds, in different solvents at 308.15 K
Fortissat Science Alliance: Shipra Nagar
No full textShipra Nagar was a PhD student from Trinity College Dublin studying pharmaceuticals and their natural products from Indian botanicals. She took part in the Fortissat Science Alliance podcast recordings in October 2023.What is the Fortissat Science Alliance?The Fortissat Science Alliance was a Wellcome Trust & Children In Need "Curiosity" project. This scheme provided informal STEM learning opportunities for young people who attended the community centre Getting Better Together Shotts (GBT Shotts) between 2019 and 2023. Due to the COVID-19 pandemic, deliveries had to pivot online so the podcast was founded. These recordings were made via Zoom with warm-up STEM activities sent to every young person in advance, along with a profile page for each researcher, so that they were relaxed and able to ask excellent questions.Link to episode on Spotify.Depending on the broadcast date, podcast deliveries were co-sponsored by Glasgow Science Festival, EXPLORATHON 2021, or EXPLORATHON 2022/23.For the duration of the project, it was supported jointly by Children in Need and the Wellcome Trust. In 2021, EXPLORATHON episodes were supported by the European Commission [grant agreement ID 101036101]. In 2022-23, EXPLORATHON episodes were supported by the Engineering & Physical Sciences Research Council [grant number EP/X020894/1].Author contributions to contentShipra Nagar was the guest featured on this episode. Rebecca Hay was the youth worker coordinating the young people who conducted the interviews as well as co-editing and broadcasting the recordings. Iain Hamilton co-edited the episodes. Kirsty Ross was the STEM consultant for the project and uploaded completed episodes to Figshare.</p
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