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    Synthesis and characterization of new photoluminescent oxadiazole/carbazole-containing polymers

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    We report on the synthesis and the characterization of a new class of segmented polyethers POC containing the oxadiazole and carbazole units. The polymers exhibit a high thermal stability, high glass transition temperatures, and good solubility in common organic solvents, despite the extended aromatic portion in the main polymer chain. The synthetic procedures are simple, and no acid side-products are obtained. According to previous reports on oxadiazole/carbazole-containing materials, POCs show high photoluminescence activity in the blue region of the visible spectra. The good solubility in chlorinate solvents allows the preparation of films with homogeneous thickness by spin coating. Glass transition temperature in the range 115–125◦C ensures good stability of film morphology at room temperature. The only exception is POC(6), which shows a poor solubility and higher Tg (170◦C), due to its shorter aliphatic chain portion. For these features, polymers POC are potential candidate materials for fabricating blue light-emitting devices

    Antimicrobial Membranes of Bio-Based PA 11 and HNTs Filled with Lysozyme Obtained by an Electrospinning Process

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    Bio-based membranes were obtained using Polyamide 11 (PA11) from renewable sources and a nano-hybrid composed of halloysite nanotubes (HNTs) filled with lysozyme (50 wt % of lysozyme), as a natural antimicrobial molecule. Composites were prepared using an electrospinning process, varying the nano-hybrid loading (i.e., 1.0, 2.5, 5.0 wt %). The morphology of the membranes was investigated through SEM analysis and there was found to be a narrow average fiber diameter (0.3–0.5 μm). The mechanical properties were analyzed and correlated to the nano-hybrid content. Controlled release of lysozyme was followed using UV spectrophotometry and the release kinetics were found to be dependent on HNTs–lysozyme loading. The experimental results were analyzed by a modified Gallagher–Corrigan model. The application of the produced membranes, as bio-based pads, for extending the shelf life of chicken slices has been tested and evaluated

    Nanocomposites Based on PCL and Halloysite Nanotubes Filled with Lysozyme: Effect of Draw Ratio on the Physical Properties and Release Analysis

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    Halloysite nanotubes (HNTs) were loaded with lsozyme, as antimicrobial molecule, at a HNTs/lysozyme ratio of 1:1. Such a nano-hybrid was incorporated into a poly (ε-caprolactone) (PCL) matrix at 10 wt % and films were obtained. The nano-composites were submitted to a cold drawn process at three different draw ratios, λ = 3, 4, and 5, where λ is l(final length)/l0(initial length). Morphology, physical, and barrier properties of the starting nanocomposite and drawn samples were studied, and correlated to the release of the lysozyme molecule. It was demonstrated that with a simple mechanical treatment it is possible to obtain controlled release systems for specific active packaging requirements
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