1,721,206 research outputs found
Cross-diffusion-driven hydrodynamic instabilities in a double-layer system: General classification and nonlinear simulations
Full text linkCross diffusion, whereby a flux of a given species entrains the diffusive transport of another species, can trigger buoyancy-driven hydrodynamic instabilities at the interface of initially stable stratifications. Starting from a simple three-component case, we introduce a theoretical framework to classify cross-diffusion-induced hydrodynamic phenomena in two-layer stratifications under the action of the gravitational field. A cross-diffusion-convection (CDC) model is derived by coupling the fickian diffusion formalism to Stokes equations. In order to isolate the effect of cross-diffusion in the convective destabilization of a double-layer system, we impose a starting concentration jump of one species in the bottom layer while the other one is homogeneously distributed over the spatial domain. This initial configuration avoids the concurrence of classic Rayleigh-Taylor or differential-diffusion convective instabilities, and it also allows us to activate selectively the cross-diffusion feedback by which the heterogeneously distributed species influences the diffusive transport of the other species. We identify two types of hydrodynamic modes [the negative cross-diffusion-driven convection (NCC) and the positive cross-diffusion-driven convection (PCC)], corresponding to the sign of this operational cross-diffusion term. By studying the space-time density profiles along the gravitational axis we obtain analytical conditions for the onset of convection in terms of two important parameters only: the operational cross-diffusivity and the buoyancy ratio, giving the relative contribution of the two species to the global density. The general classification of the NCC and PCC scenarios in such parameter space is supported by numerical simulations of the fully nonlinear CDC problem. The resulting convective patterns compare favorably with recent experimental results found in microemulsion systems
Transport-driven chemical oscillations: a review
No full textChemical oscillators attract transversal interest not only as useful models for understanding and controlling (bio)chemical complexity far from the equilibrium, but also as a promising means to design smart materials and power synthetic functional behaviors. We review and classify oscillatory phenomena in systems where a periodic variation in the concentration of the constitutive chemical species is induced by transport instabilities either triggered by simple reactions or without any reactive process at play. These phenomena, where the origin of the dynamical complexity is shifted from chemical to physical nonlinearities, can facilitate a variety of processes commonly encountered in chemistry and chemical engineering. We present an excursus through the main examples, discussing phenomenology, properties and modeling of different mechanisms that can lead to these kinds of oscillations. In particular, we reproduce the relevant results reported in the pertinent literature and, in parallel, propose new kinds of proof-of-concept systems substantiated by preliminary studies which can inspire new research lines. In the landscape of physically driven chemical oscillations, we devote particular attention to transport phenomena, actively or passively combined to (reactive or nonreactive) chemical species, which provide multiple pathways towards spontaneous oscillatory instabilities. Though with different specificities, the great part of these systems can be reduced to a common theoretical description. We finally overview possible perspectives in the study of physically driven oscillatory instabilities, showing how the related control can impact fundamental and applied open problems, ranging from origin of life studies to the optimization of processes with environmental relevance
Transport-driven chemical oscillations: a review
No full textChemical oscillators attract transversal interest not only as useful models for understanding and controlling (bio)chemical complexity far from the equilibrium, but also as a promising means to design smart materials and power synthetic functional behaviors. We review and classify oscillatory phenomena in systems where a periodic variation in the concentration of the constitutive chemical species is induced by transport instabilities either triggered by simple reactions or without any reactive process at play. These phenomena, where the origin of the dynamical complexity is shifted from chemical to physical nonlinearities, can facilitate a variety of processes commonly encountered in chemistry and chemical engineering. We present an excursus through the main examples, discussing phenomenology, properties and modeling of different mechanisms that can lead to these kinds of oscillations. In particular, we reproduce the relevant results reported in the pertinent literature and, in parallel, propose new kinds of proof-of-concept systems substantiated by preliminary studies which can inspire new research lines. In the landscape of physically driven chemical oscillations, we devote particular attention to transport phenomena, actively or passively combined to (reactive or nonreactive) chemical species, which provide multiple pathways towards spontaneous oscillatory instabilities. Though with different specificities, the great part of these systems can be reduced to a common theoretical description. We finally overview possible perspectives in the study of physically driven oscillatory instabilities, showing how the related control can impact fundamental and applied open problems, ranging from origin of life studies to the optimization of processes with environmental relevance
Making a Simple A+B→C Reaction Oscillate by Coupling to Hydrodynamic Effect
No full textWe present a new mechanism through which chemical oscillations and waves can be induced in batch conditions with a simple A+B→C reaction in the absence of any nonlinear chemical feedback or external trigger. Two reactants A and B, initially separated in space, react upon diffusive contact and the product actively fuels in situ convective Marangoni flows by locally increasing the surface tension at the mixing interface. These flows combine in turn with the reaction-diffusion dynamics, inducing damped spatiotemporal oscillations of the chemical concentrations and the velocity field. By means of numerical simulations, we single out the detailed mechanism and minimal conditions for the onset of this periodic behavior. We show how the antagonistic coupling with buoyancy convection, due to concurrent chemically induced density changes, can control the oscillation properties, sustaining or suppressing this phenomenon depending on the relative strength of buoyancy- and surface-tension-driven forces. The oscillatory instability is characterized in the relevant parametric space spanned by the reactor height, the Marangoni (Mai) and the Rayleigh (Rai) numbers of the ith chemical species, the latter ruling the surface tension and buoyancy contributions to convection, respectively
Exploring Gas Evolution Oscillators: Mechanisms and Applications
No full textWe review an iconic class of chemical oscillators driven by phase transition instabilities, namely Gas Evolution Oscillators (GEOs). These systems show oscillatory dynamics in the delivery of gas sustained simple reactions yielding gaseous products in a liquid mixture, due to nucleation and supersaturation phenomena. After presenting the main features and properties of these systems, we deepen the underlying mechanism through a unified picture of the various models that have been proposed to describe this kind of oscillations. We finally discuss a concrete example of how such instabilities can impact chemical processes with applied relevance
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