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    The influence of trace amount of water on the viscosity of rhyolites

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    As a major volatile in volcanic systems, water has a significant influence on the rheological properties of silicic magmas. This is especially so at minor water contents relevant to the emplacement of silicic lavas. To investigate the influence of water on the viscosity of natural rhyolitic obsidians, a novel strategy has been adopted employing parallel-plate and micropenetration techniques. Viscosities have been determined on three types of material: (a) raw water-bearing obsidians; (b) remelted (1650 degrees C, 1 atm) degassed glasses of the obsidians; and (c) hydrothermally hydrated (1300 degrees C, 3 kbar) obsidians. Ten natural rhyolitic obsidians (peraluminous, calc-alkaline and peralkaline) were employed: seven originated from lava flows and contained <0.2 wt.% H2O, two samples were F-rich from pyroclastic successions, and one was an obsidian cobble with 1.5 wt.% water also associated with pyroclastic units. Melt compositions and water contents were stable during viscometry. The measured decreases in activation energies of viscous flow and viscosity with small amounts of water are much greater than the Shaw calculation scheme predicts. In addition, a marked nonlinear decrease in eta exists with increasing water content. In contrast to the case for peralkaline rhyolites, 0.1-0.2 wt.% water decreases activation energies significantly (up to 30%) for calc-alkaline compositions. These results have important implications for the ease of near-surface degassing of silicic magmas during emplacement and permit the testing of calculational models for viscosity, largely based on synthetic systems

    Numerical modelling of stress generation and microfracturing of vesicle walls in glassy rocks

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    In the absence of stress-concentrating flaws such as microfractures, vesicular glassy materials can withstand gas pressures within vesicles in excess of 100 MPa; however, vesicles within such materials are known to decrepitate explosively at much lower internal gas pressures, both in natural systems and in the laboratory. Here we present a model that quantitatively predicts the generation of microfractures in vesicle walls during cooling. Cooling of gas-bearing vesicles in glassy rock has little effect on water solubility in the glass, but leads to a rapid decrease in gas pressure in the vesicles. The drop in pressure causes disequilibrium between the water in the glass and in the vesicle. Dehydration of the glass in a diffusive boundary layer around the vesicle leads to elastic shrinkage. The resulting strain generates large tensile tangential stresses which can exceed the strength of the glass, causing microfracturing. Such microfractures present a possible means by which glassy rock surrounding vesicles could be weakened enough to permit explosive decrepitation at low pore vapor pressures. The results have implications wherever hydrous vesicular glasses are formed. For example rocks formed in shallow subvolcanic intrusions or vent plugs may spontaneously disintegrate with explosive emission of vapor; glassy submarine lavas spontaneously decrepitate upon dredging from the ocean floor (''popping rock''); vesicular glasses produced in laboratory experiments investigating vapor-melt phase equilibria have been observed to contain abundant fractures surrounding vesicles and to dehydrate at anomalously high rates

    Vesiculation processes in a water-rich calc-alkaline obsidian

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    The effect of temperature and viscosity on the kinetics of bubble growth was measured for a natural water-rich rhyolite melt. The change in volume of a natural crystal-poor calc-alkaline rhyolitic obsidian with an initial water content of = 1.8 wt% H,O was determined in the temperature interval 520-624°C. Shear viscosity was measured on the natural sample using the micropenetration method in the temperature interval 450-590°C and water contents before and after viscometry were monitored by FTIR. The time-dependence of the volume increase as a result of vesiculation approximates the Avrami equation: AV(t) = 1 - exp[ -(t/t)°]. At temperatures close to the glass transition temperature (Ts), growing bubbles ruptured the surrounding melt. During diffusion of water from the hydrous melt with = 1.8 wt% H,O into a bubble, the deltaTg of the melt at the bubble wall increases by = 315°C. In addition, the viscosity of the melt at the bubble wall increases by 5-6 orders of magnitude. The increasing elastic component of shear stress on the bubble wall as a result of bubble growth at about Tg may exceed the bubble wall yield strength, resulting in cracking. No time lag in the onset of bubble growth occurred for this water-rich rhyolite. In those parts of volcanic edifices where water contents are of several weight percent (e.g., within the upper parts of volcanic conduits), the probability of melt fracturing due to the degassing of water at about Tg increases

    Going Beyond Counting First Authors in Author Co-citation Analysis

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    The present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed

    Variations on the Author

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    “Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship

    Appropriate Similarity Measures for Author Cocitation Analysis

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    We provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis

    Dispelling the Myths Behind First-author Citation Counts

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    We conducted a full-scale evaluative citation analysis study of scholars in the XML research field to explore just how different from each other author rankings resulting from different citation counting methods actually are, and to demonstrate the capability of emerging data and tools on the Web in supporting more realistic citation counting methods. Our results contest some common arguments for the continued use of first-author citation counts in the evaluation of scholars, such as high correlations between author rankings by first-author citation counts and other citation counting methods, and high costs of using more realistic citation counting methods that are not well-supported by the ISI databases. It is argued that increasingly available digital full text research papers make it possible for citation analysis studies to go beyond what the ISI databases have directly supported and to employ more sophisticated methods

    Author Index

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    koamabayili/VECTRON-author-checklist: VECTRON author checklist

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    We have done our best to complete the author checklist relating to the use of animals in the hut study. Note that the objective for the hut study was to evaluate the IRS treatment applications for residual efficacy against Anopheles mosquitoes, including the local An. coluzzii mosquito population. Cows were only used to attract mosquitoes into the huts and no tests were carried out directly on the cows. The author checklist is intended for use with studies where experiments are carried out on animals, which is why we have had such difficulty in completing this for the hut study, as many of the questions do not relate to how the cows were used
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