14,968 research outputs found
Cationic order versus La-O covalency in LaA (Ca,Ba) VMoO6 double perovskites
No full textWe have investigated the structural and physical properties of double perovskite (DP) LaAVMoO6 (A=Ca2+, Ba2+; abbreviated as LCVMO and LBVMO from now on) compounds, proposed to be possible half-metallic antiferromagnets (HMAFMs). Here we show that within LaAVMoO6 double perovskite structure, La-O covalency competes against B-site as well A-site cationic order and this competition critically influences their physical properties. Evidently, the presence of Ca2+ or Ba2+ at the A site along with La3+ would offer a tool to modify the A-site ordering and consequently influence the La-O covalency as well. Our experimental results reveal that LCVMO lies at the extreme end of this family and accommodates large scale phase separation in terms of La, V, and Ca, Mo-rich phases as a result of dominant La-O covalency. On the other hand, LBVMO is more correctly described as a layered A-site ordered and nearly complete B-site disordered double perovskite where cationic order dominates the La-O covalency. The general trend of our experimental findings is in agreement with the ab initio electronic structure calculations, carried out on realistic structures based on local coordination obtained from extended x-ray-absorption fine-structure study
[Letter from Alex Bradford to Lieutenant and Mrs. Ray Starner - November 4, 1940]
No full textLetter from Alex Bradford to Lieutenant and Mrs. Ray Starner describing the the current state of affairs that the author was experiencing, including: the London blitz, the moral of the troops on the ground, and the collective company of men opposing the Nazi regime
ARCH-COMP22 Category Report: Hybrid Systems with Piecewise Constant Dynamics and Bounded Model Checking
No full textThe student's guide to completing an author study
No full textThe 'Student's guide to completing an author study' emerged during the early development of the school library resource center program at Glen Stewart Elementary School in Stratford Canada on Prince Edward Island. This research process centered on an author study, with direct teaching and clear assignment. The resulting model has been adapted to various grade levels and subject areas in different schools.Source type: Electronic(1)http://proquest.umi.com/pqdweb?did=49237063&Fmt=7&clientId=65345&RQT=309&VName=PQ
Development of half metallicity within mixed magnetic phase of Cu1-xCoxMnSb alloy
No full textCubic half-Heusler Cu1-xCoxMnSb () compounds have been investigated both experimentally and theoretically for their magnetic, transport and electronic properties in search of possible half metallic antiferromagnetism. The systems (Cu,Co)MnSb are of particular interest as the end member alloys CuMnSb and CoMnSb are semi metallic (SM) antiferromagnetic (AFM) and half metallic (HM) ferromagnetic (FM), respectively. Clearly, Co-doping at the Cu-site of CuMnSb introduces changes in the carrier concentration at the Fermi level that may lead to half metallic ground state but there remains a persistent controversy whether the AFM to FM transition occurs simultaneously. Our experimental results reveal that the AFM to FM magnetic transition occurs through a percolation mechanism where Co-substitution gradually suppresses the AFM phase and forces FM polarization around every dopant cobalt. As a result a mixed magnetic phase is realized within this composition range while a nearly HM band structure is developed already at the 10% Co-doping. Absence of T 2 dependence in the resistivity variation at low T-region serves as an indirect proof of opening up an energy gap at the Fermi surface in one of the spin channels. This is further corroborated by the ab initio electronic structure calculations that suggests that a nearly ferromagnetic half-metallic ground state is stabilized by Sb-p holes produced upon Co doping
Active X-ray optics for the next generation of X-ray space telescopes
No full textDescribed within is the design, manufacture, metrology and X-ray testing of an active X-ray
prototype intended for the next generation of X-ray telescopes. One of the challenges faced by
the X-ray telescope community is how to combine high resolution and high sensitivity into one
system, as weight limitations place constraints on the optics that can be launched. Therefore the
mandate of the active X-ray prototype is to provide high sensitivity through the ability of the optics
to be nested and to deliver high angular resolution through the active control of the optic’s form.
Piezoelectric unimorph actuators provide the active component: it is intended that they will correct
for figure errors within the optic and therefore increase the angular resolution capability.
The prototype’s design is based upon an ellipsoidal segment which provides point-to-point
focussing of an X-ray source. The prototype itself is composed of an electroformed nickel optic
where the non-reflective surface is populated with 30 piezoelectric actuators and it is the production
of the prototype that is the core of the presented research. Metrology of the actuators’ influence
functions is presented and highlight the prototype’s ability to deform its optic surface by microns.
In addition, the measured influence functions are compared against finite element models and a
distinct similarity between the functions is observed.
The prototype was tested at an X-ray beamline facility in November 2008 and the results
showed the prototype’s ability to correct the optic to achieve an improved angular resolution: from
0.786 arc-minutes to 0.686 arc-minutes in terms of full width half maximum. Finally, difficulties
in the manufacture of the prototype and X-ray testing shall be presented alongside future work in
conclusion to this thesis
Author, Geraldine Brooks at the National Library of Australia for the 2009 Ray Mathew Lecture, Canberra, 23 October 2009 [picture] /
No full textTitle from acquisitions documentation.; Part of the collection: Portraits of author, Geraldine Brooks during her visit to the National Library of Australia for the 2009 Ray Mathew Lecture, Canberra, 23 October 2009.; Acquired in digital format; access copy available online.; Mode of access: Internet via World Wide Web.; Photographed by a staff member of the National Library of Australia
A 2 h periodic variation in the low-mass X-ray binary Ser X-1
No full textSpectroscopy of the low-mass X-ray binary Ser X-1 using the Gran Telescopio Canarias have revealed a ?2 h periodic variability that is present in the three strongest emission lines. We tentatively interpret this variability as due to orbital motion, making it the first indication of the orbital period of Ser X-1. Together with the fact that the emission lines are remarkably narrow, but still resolved, we show that a main-sequence K dwarf together with a canonical 1.4 M? neutron star gives a good description of the system. In this scenario, the most likely place for the emission lines to arise is the accretion disc, instead of a localized region in the binary (such as the irradiated surface or the stream-impact point), and their narrowness is due instead to the low inclination (?10°) of Ser X-1
X-ray polarization in relativistic jets
No full textWe investigate the polarization properties of Comptonized X-rays from relativistic jets in active galactic nuclei (AGN) using Monte Carlo simulations. We consider three scenarios commonly proposed for the observed X-ray emission in AGN: Compton scattering of blackbody photons emitted from an accretion disc; scattering of cosmic microwave background (CMB) photons and self-Comptonization of intrinsically polarized synchrotron photons emitted by jet electrons. Our simulations show that for Comptonization of disc and CMB photons, the degree of polarization of the scattered photons increases with the viewing inclination angle with respect to the jet axis. In both cases, the maximum linear polarization is ≈20 per cent. In the case of synchrotron self-Comptonization (SSC), we find that the resulting X-ray polarization depends strongly on the seed synchrotron photon injection site, with typical fractional polarizations P≈ 10–20 per cent when synchrotron emission is localized near the jet base, while P≈ 20–70 per cent for the case of uniform emission throughout the jet. These results indicate that X-ray polarimetry may be capable of providing unique clues to identify the location of particle acceleration sites in relativistic jets. In particular, if synchrotron photons are emitted quasi-uniformly throughout a jet, then the observed degree of X-ray polarization may be sufficiently different for each of the competing X-ray emission mechanisms (synchrotron, SSC or external Comptonization) to determine which is the dominant process. However, X-ray polarimetry alone is unlikely to be able to distinguish between disc and CMB Comptonization
Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methy1-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone
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