117,544 research outputs found

    Simultaneous determination of polyphenolic compounds in red and white grapes grown in Sardinia by high performance liquid chromatography-electron spray ionisation-mass spectrometry

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    A new method for the identification and the quantification of nonanthocyanin phenolic compounds from six Vitis Vinifera grape varieties native to Sardinia (three native: Vermentino, Malvasia and Cannonau and three non-native types: Chardonnay, Sauvignon and Cabernet Sauvignon; Argiolas vineyard) was developed. This rapid and selective method employs LC/ESI-MS in negative mode. Different solvents extraction and different sorbents for purification were compared to the direct analysis of the initial extracts without further sample preparation. A total of 54 phenolic compounds were identified either in the freeze-dried skins or seeds, including nonflavonoids (hydroxybenzoic and hydroxycinnamic acids and their derivatives, stilbenes) and flavonoids (flavanols, flavonols, dihydroxyflavonols). (C) 2009 Elsevier B.V. All rights reserved

    Algorithmic modelling processes in scan-to-BIM workflows

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    The benefits brought by the application of the BIM philosophy to built heritage are now widely recognised, so much so that a closely related methodology, Heritage BIM borned. The HBIM finds practical confirmation in the so-called Scan-to-BIM processes; the data of architectural organisms, in the form of point clouds, are the basis on which the modelling of information is developed, to arrive at geometric models within which all the information necessary for the reading and interpretation of the architectural artefact as well as for its preservation and management is collected. In the paper some of the problems that arise from the application of the Scan-to-BIM processes to complex historical elements are analysed, particularly related to the phases of creation of three-dimensional models. In addition, a reasoning is made about how such problems can be solved or at least mitigated, thanks to the use of algorithmic modelling; the aim is to parameterise the generative process of the models, when the model itself cannot be parametric. In order to do this, a classic typology of historical architecture was examined: late-gothic vaulted systems
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