110 research outputs found
Groin pain in athletes: a novel diagnostic approach
No full textGroin pain in a performing athlete can be very challenging to diagnose and treat. The differential diagnosis includes intra-articular causes, extra-articular causes and non-musculoskeletal causes. A detailed clinical and radiological assessment of groin pain in this group is critical and can identify the underlying pathology. Diagnostic hip block is a valuable tool to differentiate intra-articular causes from extra-articular causes. Hip arthroscopy can help in identifying some of the elusive intra-articular conditions, which were once undiagnosed and therefore, left untreated, resulting in premature ending of competitive careers. This article attempts to explore current thinking on evaluation of groin pain, particularly in young individuals, and to establish a simple protocol for a clinical and diagnostic approach to this difficult problem
Effect of roughness, microstructure, and chemistry on the environmental durability of structural alloys
No full textUnlike functional materials where one design property is usually optimized, structural materials need to meet several design requirements including but not limited to excellent mechanical properties and environmental tolerance. However, more often than not, the metallurgical principles used to improve mechanical properties result in a decrease in the environmental tolerance. Though it is difficult to design materials that can thrive in extreme environments like high temperature, high pressure, and harsh chemicals, these conditions are often where the biggest scientific and economic opportunities lie. Aeroengines, and oil refineries are two example applications that encounter these issues. This study specifically focusses on improving the environmental tolerance of NiCrAl films a common bond coat used in aeroengines, and ferrous alloys used in petroleum production. The goal was to develop solutions that improve the environmental tolerance while minimally affecting other properties of these alloys.
The oxidation behavior of a model sputtered NiCrAl system was studied in various time and oxygen partial pressure (pO2) regimes. Low pO2 conditions seemed to favor the formation of protective oxides. However, tuning the composition of the base alloy was an effective way to limit the oxidation rate in high pO2 conditions. Thermal destabilization of the sputtered microstructure was found to take place on similar timescales to the transient oxide formation. Thus dilute Y additions were made to temporarily stabilize the sputtered microstructure and manipulate the transient stages of oxidation.
Yttrium addition not only retarded grain growth through nanoclustering and kinetically pinning grains, but also helped nucleate and grow dense, and slow-growing oxides. In some cases, the improvement in oxidation resistance via. Y addition was similar to reducing the pO2 by several orders of magnitude. Robust α-alumina oxides formed on Y doped NiCrAl films at temperatures as low as 900 oC by oxidation in an air environment which is unprecedented and could be of major commercial importance. An attempt was made to understand this anomalous oxidation behavior by using unconventional diffusion-triples comprising of a sputtered NiCr (undoped and Y doped) top layer, Al middle layer, and a sintered (micrograined) NiCr bottom layer. Annealing experiments conducted on the diffusion-triples proved that Al diffusion in sputtered NiCr is more rapid than that in sintered NiCr. Through the use of profile processing techniques, Al was shown to follow type B kinetics for grain boundary diffusion in sputtered NiCr. It also revealed that Y addition to sputtered NiCr further accelerates Al diffusion through a non-Fickian mechanism involving Al clustering.
The baseline fouling and corrosion behavior of ferrous alloys in a high temperature, high pressure, and an asphaltenic environment was also evaluated. Key insights were generated on the interplay between the thermochemical properties of the asphaltene, the environmental conditions, surface preparation of the alloys, and the chemistry of the deposits. X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy allowed for the first time to pinpoint mechanisms for high temperature model asphaltene deposition on ferrous alloys. Improving surface roughness alone was found to be a good strategy to mitigate asphaltenic fouling at lower temperatures where the asphaltene remains intact. However, at temperatures where reactive asphaltene decomposition products become present in solution, surface chemistry control becomes important. Specifically, a protective atomic layer deposition alumina chemistry on steels was found to significantly reduce asphaltenic fouling.
In order to evaluate whether a protective alumina chemistry could be generated on components with more complex geometries, low temperature pack cementation of ferrous alloys was conducted. Preliminary data did show an improvement in anti-fouling properties with both model asphaltenes in a static environment, as well as with crude oil in a hydrodynamic environment. However, XPS revealed a mixed alumina-hematite oxide on the surface that may be limiting the anti-fouling properties of these surfaces. Finally, new insights gained from developing low temperature pack cementation for ferrous alloys allowed for the modification of low thermal stability, functional metallic structures like Ni inverse opals. It resulted in a thermal stability enhancement by 500 oC, comparable to refractory metals in the same configuration. And also improved both the modulus and hardness of these structures.Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2021-05-01The student, Pralav Shetty, accepted the attached license on 2019-02-20 at 15:57.The student, Pralav Shetty, submitted this Dissertation for approval on 2019-02-20 at 16:17.This Dissertation was approved for publication on 2019-02-22 at 10:53.DSpace SAF Submission Ingestion Package generated from Vireo submission #13398 on 2019-08-22 at 16:19:59Made available in DSpace on 2019-08-23T20:44:32Z (GMT). No. of bitstreams: 3
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Effect of beneficial microorganisms on nutrient profile of Moringa oleifera leaves.
No full textThis Dissertation / Report is the outcome of investigation carried out by the creator(s) / author(s) at the department/division of Central Food Technological Research Institute (CFTRI), Mysore mentioned below in this page
Trienzyme extraction and quantification of total folate from underutilized fruits.
No full textThis Dissertation / Report is the outcome of investigation carried out by the creator(s) / author(s) at the department/division of Central Food Technological Research Institute (CFTRI), Mysore mentioned below in this page
Patellar instability in Indian population: relevance of tibial tuberosity and trochlear groove distance
No full textIntroduction: The tibial tuberosity to trochlear groove (TTTG) distance in the western population is extensively studied through various modalities such as X-rays, computerised tomography and magnetic resonance imaging. However, to our knowledge there is very little or no literature support to indicate that TTTG distance has been studied in the Indian population.
Methods: We therefore undertook a study to measure the TTTG distance in 100 MRI scans of normal Indian knees. Patients with the following co-morbidities were excluded from the study; ligamentous laxity, patellofemoral instability, mal-alignment and osteoarthritis. We measured TTTG distance on the axial MRI slices using OsiriX software.
Results: The mean value for females was found to be 14.07 mm and that for male was found to be 13.34 mm. Our study indicates that the TTTG distance, using MRI scans as measurement modality, in the Indian population is significantly different when compared to the published western data.
Discussion: We believe that this study can form the basis for future studies on the relationship between TTTG distance and patellar instability in Indian population
Chromium(III) and chromium(IV) bis(trimethylsilyl) amido complexes as ethylene polymerisation catalysts
No full textOxidation of Cr[N(SiMe3)(2)](2)(THF)(2) with iodine and dicumyl peroxide results in tetrahedral Cr(IV)Cr[N(SiMe3)(2)](2)I-2 and trigonal planar Cr(III) Cr[N(SiMe3)(2)](OCMe2Ph)(2), respectively; both complexes have been characterised by single-crystal X-ray diffraction, and both are active for ethylene polymerisation with alkylaluminium co-catalysts.PT: J; CR: AJJOU JAN, 1997, ORGANOMETALLICS, V16, P86 AJJOU JAN, 2000, J AM CHEM SOC, V122, P8968 ALONSO PJ, 2002, CHEM-EUR J, V8, P4056 BASI JS, 1971, J CHEM SOC A, P1433 BEAUDOIN MC, 2002, J MOL CATAL A-CHEM, V190, P159 BERNO P, 1994, ORGANOMETALLICS, V13, P1052 BLANCHARD H, 1988, J ORGANOMET CHEM, V341, P367 BOCHMANN M, 1980, J CHEM SOC DA, P1863 BRADLEY DC, 1972, J CHEM SOC CHEM COMM, P567 BRADLEY DC, 1976, ACCOUNTS CHEM RES, V9, P273 BRADLEY DC, 1978, INORG SYNTH, V18, P112 BRITOVSEK GJP, 1999, ANGEW CHEM INT EDIT, V38, P428 BURGER H, 1964, MONATSH, V95, P1099 CUMMINS CC, 1992, ANGEW CHEM INT EDIT, V31, P1501 CUMMINS CC, 1998, PROG INORG CHEM, V47, P685 DRYKACZ G, 1973, J AM CHEM SOC, V95, P4756 ELLER PG, 1977, COORDIN CHEM REV, V24, P1 FILIPPOU AC, 2002, EUR J INORG CHEM NOV, P2928 FILIPPOU AC, 2003, ANGEW CHEM INT EDIT, V42, P4486 FILIPPOU AC, 2003, ORGANOMETALLICS, V22, P3010 FIRMAN TK, 2001, J ORGANOMET CHEM, V635, P153 FRYZUK MD, 1995, ORGANOMETALLICS, V14, P5193 GIBSON VC, 1998, CHEM COMMUN 0821, P1651 GIBSON VC, 1999, J CHEM SOC DALT 0321, P827 GIBSON VC, 2000, J CHEM SOC DALTON, P1969 GIBSON VC, 2001, EUR J INORG CHEM JUL, P1895 GIBSON VC, 2002, J CHEM SOC DALTON, P4017 GIBSON VC, 2003, CHEM REV, V103, P283 HAGIHARA N, 1959, J AM CHEM SOC, V81, P3160 IKEDA H, 2001, MACROMOL CHEM PHYSIC, V202, P1806 IKEDA H, 2002, J ORGANOMET CHEM, V642, P156 KAYAL A, 2002, INORG CHEM, V41, P321 LAPLAZA CE, 1996, J AM CHEM SOC, V118, P8623 MESSERE R, 2000, EUR J INORG CHEM JUN, P1151 MINDIOLA DJ, 1998, ANGEW CHEM INT EDIT, V37, P945 MOWAT W, 1972, J CHEM SOC DA, P533 MOWAT W, 1973, J CHEM SOC DA, P770 ROBERTSON NJ, 2003, INORG CHEM, V42, P6876 SCHMID R, 2000, CAN J CHEM, V78, P265 SCHMID R, 2000, ORGANOMETALLICS, V19, P2756 SCHNEIDER S, 2001, INORG CHEM, V40, P4674 SCHULZKE C, 2002, ORGANOMETALLICS, V21, P3810 SCOTT SL, 2001, CHEM ENG SCI, V56, P4155 SEIDEL W, 1976, Z ANORG ALLG CHEM, V426, P150 SEIDEL W, 1976, Z ANORG ALLG CHEM, V426, P155 SMALL BL, 2004, MACROMOLECULES, V37, P4375 THEOPOLD KH, 1998, EUR J INORG CHEM JAN, P15 VANRENSBURG WJ, 2004, ORGANOMETALLICS, V23, P1207; NR: 48; TC: 3; J9: DALTON TRANS; PG: 3; GA: 865WTSource type: Electronic(1
Reply to comment on: Patellar instability in Indian population: relevance of tibial tuberosity and trochlear groove distance
No full textEmvolio Instrument test reports and The ARRIVE guidelines 2.0 - Author checklist.pdf,
No full textThis also includes the details (1) test reports of Emvolio, as per the regulatory compliences (WHO/PQS/E003/TS01.1) and (2) Reports of Internal testing.
The file contains the ARRIVE2.0 Author Checklist for experiments carried out using rats.</p
Retraining displaced workers : what can developing countries learn from OECD nations?
No full textThe governments of most industrial countries provide financial support for adult training programs intended to retrain displaced workers. The author draws lessons from the experience of six industrial countries (Australia, Britain, Canada, Japan, Sweden, and the United States) on how to design and implement such retraining programs in low-income developing nations and middle-income countries. By retraining, the author means both improving job skills and remediating deficiencies in basic education. These are the lessons he emphasizes: Training programs should be independent of the educational system, with its rigid ties to degree requirements and academic schedules; links to employers must be developed and maintained so that trainees have marketable skills on completing the program. Training programs should be designed to minimize trainees'foregone earnings; basic education should be relevant to the jobs the trainees might seek. External providers of education must be made accountable - but with care; the system of accountability should also ensure that the needs of displaced workers most likely to suffer long-term unemployment are met. Not all displaced workers require relatively expansive retraining; some may need only inexpensive job-search assistance services. A permanent, institutionalized training system is preferable to short-term intervention.Labor Standards,Tertiary Education,ICT Policy and Strategies,Health Monitoring&Evaluation,Teaching and Learning
Third order nonlinear optical properties of graphene quantum dots under continuous wavelength regime at 532 nm
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