1,354,219 research outputs found
Successione imprenditoriale e prospettive di continuità nelle piccole e medie imprese
Il volume espone i risultati di una ricerca che ha coinvolto oltre trecento imprese di piccola e media dimensione dell’area giuliana, con l’obiettivo di evidenziare le cause e i problemi che possono ostacolare i processi di successione imprenditoriale e, più in generale, la continuità d’impresa.
L’analisi mette in evidenza che la rimozione dei numerosi fattori di potenziale ostacolo o rallentamento del passaggio generazionale passa necessariamente attraverso significativi interventi sull’orientamento, le aspettative, i profili e le competenze dei soggetti coinvolti: imprenditore uscente e successore.
La ricerca conferma inoltre che la successione d’impresa non costituisce soltanto una delle principali cause di mortalità aziendale, ma rappresenta anche un possibile momento di svolta e di sviluppo per l’impresa minore, che proprio in questa sua fase così delicata può acquisire quegli elementi di innovazione che ne possono segnare il rilancio strategico ed organizzativo
Konstruksi Sosial Terhadap Ampo Di Desa Bektiharjo Kecamatan Semanding, Kabupaten Tuban
Penelitian ini mengkaji tentang konstruksi sosial masyarakat Bektiharjo terhadap
Ampo. Mengingat Ampo merupakan fenomena sosial yang ada di masyarakat
bahwasanya Ampo dibuat dari tanah liat dan dikonsumsi baik sebagai camialan atau obat
alternatif. Tujuan penelitian ini untuk mendiskripsikan bagaimana konstruksi sosial
masyarakat desa Bektiharjo terhadap Ampo.
Penelitian ini menggunakan teori yang digagas oleh Peter L. Berger untuk\ud
menganalisis konstruksi sosial masyarakat Bektiharjo terhadap Ampo. Berger
mengemukakan bahwa konstruksi sosial terbentuk karena adnya realitas obyektif yang
tidak bisa terlepas dari sejarah keberadaan masyarakat, dan realitas subyektif dalam
hubunganya dengan pemaknaan atas pengetahuan individu. Tujuan dari penelitian ini
untuk memahami konstruksi sosial masyarakat des Bektiharjo terhadap Ampo, serta
bagaimana pengetahuan masyarakat Bektiharjo terhadap Ampo. Metode yang digunakan
dalam penelitian ini adalah kualitatif deksriptif. Teknik pengumpulan data yang
digunakan adalah observasi, dokumentasi, serta wawancara dengan satu informan kunci
dua informan utama dan empat informan pendukung.
Hasil penelitian menunjukan bahwasanya ada pengetahuan yang diwariskan dan
dikonstruksikan pada masyarakat Bektiharjo. Dimana pengetahuan itu membentuk
pemaknaan masyarakat tentang Ampo dan tindakan apa yang diambil masyarakat dalam
menggunakan Ampo. Dari sebuah pengetahuan yang diwariskan terdapat nilai dan norma
pengetahuan yang terus dikomunikasikan dari generasi ke generasi selanjutnya. Dalam
konstruksi sosial sendiri terdapat proses eksternalisasi, yaitu penyesuaian diri terhadap
adat setempat dan pemikitan yang berkembang dalam masyarakat. Proses selanjutnya
adalah obyektivasi yaitu proses penyadaran individu baru tentang dunia sosial, pemimpin
dan kelembagaan. Sedangkan internalisasi merupakan pemahaman atau penafsiran yang
langsung dari peristiwa obyektif sebagai pengungkapan suatu makna yang didalamnya
juga ada proses sosialisasi, menciptakan identitas diri masing-masing individu sebagai
orang Bektiharjo yang berpartisipasi dalam menggunakan Ampo baik sebagai sesajen,
camilan dan obat
Pengaruh OH/Fe Pada Pembuatan Ampo Terpilar Besi Oksida Terhadap Penjerapan Deterjen Dalam Air
The direct disposal of detergent waste by the commercial laundry service into environment can cause water
pollutions. Therefore, the efforts of eliminating pollutions through treatments using an adsorption method are
required. One of the materials that can be used as alternative adsorbent is a pillaried ampo. Objective of this
research is to find out the effect of ampo pillarization, variation in ratios of OH/Fe on the performance of ampo
in a detergent adsorption in water, to compare a maximum capacity of pillared and unpillared ampo. The making
of pillared ampo was started by washing ampo, followed by the makings of ampo suspension, of the pillarizing
solution with variation in OH/Fe ratio of 0.5; 1; 1.5; 2, and 2.5 while at the same time being stirred until it is
clear, and then aged for 24 hours. The second step is ampo pillarization, followed by filtering and washing to
eliminate Cl and drying. The dried pillared ampo is calcinated at 400oC for four hours. Products of pillared and
unpillared ampos resulted from the calcinations are used to adsorb detergents in water. Result of the research
indicates that ampo pillarization could increase the performance of ampo in the adsorption of detergents in water.
Variation in ratios OH/ Fe increased a capacity of pillared ampo in adsorbing detergents in water. The highest
maximum adsorption capacity was obtained at the Fe/ampo ratio of 2 and OH/Fe ratio of 2 where of unpillared
ampo was 17.24 mg MBAS/g. The unpillared ampo has maximum adsorption capacity of 11.76 mg MBAS/g.
Key word: ampo, pilarisation, adsorption, detergen
Desain Aplikasi Restoran Bakmi Ampo Berbasis Web
In this study, we will to solve the problem in a bakmi ampo restaurant that still uses manual methods to accept orders. As a result, many orders that come to customers are not suitable. We designed a web-based restaurant application to solve this problem. The method we use is the waterfall method, which is a systematic method for building software through various stages in SDLC. The reason for using the Waterfall method is because this method emphasizes the order in the software development process, after we tried to design the application design, the results were very effective in helping a bakmi ampo restaurant so that orders from customers were not wrong.In this study, we will to solve the problem in a bakmi ampo restaurant that still uses manual methods to accept orders. As a result, many orders that come to customers are not suitable. We designed a web-based restaurant application to solve this problem. The method we use is the waterfall method, which is a systematic method for building software through various stages in SDLC. The reason for using the Waterfall method is because this method emphasizes the order in the software development process, after we tried to design the application design, the results were very effective in helping a bakmi ampo restaurant so that orders from customers were not wrong
Pembuatan dan Karakterisasi Ampo Terpilar Besi Oksida [Kajian Rasio Hidrolisis Agen Pemilar (OH/Fe]
Ampo is one of nature material that by public benefit as remover bitter taste at papain leaf. Ability of ampo in
adsorption of bitter taste of papain leaf indicates that ampo has adequate surface area causing is concluded
that ampo potency as adsorbent. Usage of ampo nature directly as adsorbent has constraint that is when
staying in water would be brittle and swelling as a result ability of the adsorption not optimal. To increase
ability of the adsorption and resilience in water hence done modification ampo with pilarisation method.
Pilarisation is done with interkalation polioksokation Fe3+ into between interlayers ampo then is calcination.
At research is studied hydrolysis ratio influence OH/Fe { 1 ; 15; 2 ; 25} at Fe/ampo 2 with calcination
temperature 400 oC during 4 hour. Product of Fe2O3 pillared ampo will be characterized of physical
properties that is basal spacing using X-ray difraction, surface area with surface area analyzer NOVA 2000
using BET method, pore size distribution analysis with two method are De Boer and Modified Horvath
Kawazoe, structural morphology with SEM and adsorption capacities methyl violet with Langmuir isotherm
model. Result of research indicates that pilarisation can increase surface area for ratio OH/Fe [ 1= 19.68; 15=
38.86; 2 = 65.53 and 2.5 = 57.67] m2/g, surfacea area ampo 34.0273 m2/g. At comparison [ OH/Fe = 2]
shows higher value from all variables with basal spacing 15.79 oA, surface area 99.5618 m2/g, pore diameter
4.815 oA and total pore volume 61.02 cc/g. Structural morphology from SEM indicates that surface structure
pillared ampo to be more porous than ampo without pillar.
Keywords: Ampo, Pillared ampo, pillarization, hydrolisise
Analisis Potensi Pengembangan Idle Asset Infrastruktur Pelabuhan: Studi Kasus Pelabuhan Tanah Ampo, Karangasem, Bali
Berdasarkan Rencana Tata Ruang Wilayah Kabupaten Karangasem tahun 2012 – 2032 Pasal 5 ayat E menyatakan rencana pengembangan Pelabuhan Pariwisata di Tanah Ampo untuk mendukung pengembangan pariwisata di Kabupaten Karangasem. Pelabuhan Tanah Ampo dibangun pada tahun 2006, beroperasi tahun 2011 – 2013, lalu mangkrak hingga saat ini. Penelitian ini bertujuan untuk mengetahui kondisi eksisting serta potensi hinterland disekitar Tanah Ampo sehingga menemukan alternatif terbaik untuk pengembangan Pelabuhan Tanah Ampo. Metode yang digunakan yaitu regresi, analisis gap, dan analisis biaya manfaat (BCR). Kondisi saat ini dari Pelabuhan Tanah Ampo yaitu memerlukan perbaikan pada bollard, rubber fender, dan diperlukan maintenance dredging. Untuk mendapatkan alternatif pengembangan, dilakukan analisis gap terhadap potensi hinterland disekitar Pelabuhan Tanah Ampo yaitu Pelabuhan Padang Bai dengan hasil BOR(%) 63,39% ditahun 2040, TBBM Manggis dengan BOR(%) yang melebihi standar pada Jetty 1 (72,4% ditahun 2025), Jetty 2 (72,3% ditahun 2028) dan Jetty 3 (71,6% ditahun 2030), serta 4 dari 7 tangki muatan yang melebihi SOR(%) yaitu Fame (67% ditahun 2031), Avtur (93,2% ditahun 2024), MFO (67,6% ditahun 2032), Pertamax (82,9% ditahun 2024), dan MDO (97,8% ditahun 2024), lalu potensi sandar kapal LCT dengan BOR(%) sebesar 4% ditahun 2041, potensi cruise pada sektor pariwisata yang ternyata tidak kompatibel dengan Pelabuhan Tanah Ampo, dan sektor perikanan dengan proyeksi total produksi ikan 40.096 ton ditahun 2041. Didapatkan 4 pilihan alternatif, dimana alternatif 1 tidak melakukan pengembangan sehingga muncul sunk cost sebesar Rp 261.533.866.520, dan 3 alternatif lainnya pengembangan menjadi TBBM, sandar LCT, dan SKPT. Dengan analisis BCR, maka yang terpilih adalah alternatif 4 yaitu pengembangan menjadi SKPT dengan rasio BCR 1,02.
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Based on the Spatial Plan of Karangasem Regency in 2012 - 2032 chapter 5 paragraph e mentions the plan to develop a Tourism Port in Tanah Ampo to support tourism development in Karangasem Regency". Tanah Ampo Port has been built since 2006, operated in 2011 – 2013, and then stalled. This research aims to find out the existing conditions and potential hinterland around Tanah Ampo Port so that the best alternative solution can be found for the development of Tanah Ampo Port. Methods that are used are regression, gap analysis, and BCR. Currently the existing condition of Tanah Ampo Port requires repairs to bollards, rubber fenders, and maintenance dredging. To obtain alternative development, used gap analysis of the potential hinterland around Tanah Ampo port, that is Padang Bai Port with BOR(%) 63.39% in 2040, TBBM Manggis with BOR(%) which exceeds the BOR(%) standard in Jetty 1 (72.4% in 2025), Jetty 2 (72.3% in 2028) and Jetty 3 (71.6% in 2030), and 4 of 7 cargo tanks that exceed SOR(%) standard are Fame (67% in 2031), Avtur (93.2% in 2024), MFO (67.6% in 2032), Pertamax (82.9% in 2024), and MDO (97.8% in 2024), then the potential of LCT ship with BOR(%) 4% in 2041, the potential of cruises in the tourism sector that turned out to be incompatible with Tanah Ampo Port, and the fisheries sector with a projected total fish production of 40,096 tons in 2041. There are 4 alternatives studied in this analysis: alternative 1 is business as usual which incurred sunk cost of Rp 261,533,866,520, and 3 other options are to develop Tanah Ampo Port into TBBM, , port LCT’s berth, and SKPT. Alternative 4 is the most suitable, where Tanah Ampo Port will develop into a Marine and Fisheries Center (SKPT) with a BCR ratio of 1.02
Spin Trapping by 5-Carbamoyl-5-methyl-1-pyrroline <i>N</i>-Oxide (AMPO): Theoretical and Experimental Studies
The nitrone 5-carbamoyl-5-methyl-1-pyrroline N-oxide (AMPO) was synthesized and characterized.
Spin trapping of various radicals by AMPO was demonstrated for the first time by electron
paramagnetic resonance (EPR) spectroscopy. The resulting spin adducts for each of these radicals
gave unique spectral profiles. The hyperfine splitting constants for the superoxide adduct are as
follows: isomer I (80%), anitronyl-N = 13.0 G and aβ-H = 10.8 G; isomer II (20%), anitronyl-N = 13.1 G,
aβ-H = 12.5 G, and aγ-H = 1.75 G. The half-life of the AMPO−O2H was about 8 min, similar to that
observed for EMPO but significantly shorter than that of the DEPMPO−O2H with t1/2 ∼16 min.
However, the spectral profile of AMPO−O2H at high S/N ratio is distinguishable from the spectrum
of the •OH adduct. Theoretical analyses using density functional theory calculations at the B3LYP/6-31+G**//B3LYP/6-31G* level were performed on AMPO and its corresponding superoxide adduct.
Calculations predicted the presence of intramolecular H-bonding in both AMPO and its superoxide
adduct. The H-bonding interaction was further confirmed by an X-ray structure of AMPO, and of
the novel and analogous amido nitrone 2-amino-5-carbamoyl-5-methyl-1-pyrroline N-oxide (NH2−AMPO). The thermodynamic quantities for superoxide radical trapping by various nitrones have
been found to predict favorable formation of certain isomers. The measured partition coefficient in
an n-octanol/buffer system of AMPO was similar to those of DMPO and DEPMPO. This study
demonstrates the suitability of the AMPO nitrone for use as a spin trap to study radical production
in aqueous systems
AMPO: Automatic Multi-Branched Prompt Optimization
Prompt engineering is very important to enhance the performance of large language models (LLMs). When dealing with complex issues, prompt engineers tend to distill multiple patterns from examples and inject relevant solutions to optimize the prompts, achieving satisfying results. However, existing automatic prompt optimization techniques are only limited to producing single flow instructions, struggling with handling diverse patterns. In this paper, we present AMPO, an automatic prompt optimization method that can iteratively develop a multi-branched prompt using failure cases as feedback. Our goal is to explore a novel way of structuring prompts with multi-branches to better handle multiple patterns in complex tasks, for which we introduce three modules: Pattern Recognition, Branch Adjustment, and Branch Pruning. In experiments across five tasks, AMPO consistently achieves the best results. Additionally, our approach demonstrates significant optimization efficiency due to our adoption of a minimal search strategy.13 pages, 7 figures, 6 table
Synthesis, characterization and supramolecular structure of three new Cu(II) and Ni(II) complexes with the potentially bidentate ligand 2-amino-6-methylpyrimidin-4(1H)-one (AMPO)
Three binuclear Cu(II) and Ni(II) perchlorate complexes with the potentially bidentate ligand 2-amino-6-methylpyrimidin-4(1H)-one (AMPO) [Cu(AMPO) 4][Cu(H 2O) 5](ClO 4) 4·6H 2O (1), [Cu 2(AMPO) 4(H 2O) 3](ClO 4) 4·1/2H 2O (2) and[Ni(AMPO) 4][Ni(H 2O) 6](ClO 4) 4·5H 2O (3), have been prepared and were characterized by single crystal X-ray diffraction, IR spectroscopy and elemental analysis. Structural and IR data indicate that the ligand is present in its tautomeric form protonated at nitrogen in position one and metal coordinated at position three. The basic coordination pattern of the AMPO coordinated metal cations in all three complexes is square planar by four pyrimidyl nitrogen atoms of four different AMPO ligands. The coordination sphere is augmented by weak ṀO interactions between the metal centers and AMPO keto oxygen atoms. Bond valence calculations indicate the ṀO interactions to be most pronounced for nickel compound (3), and least for copper complex (2). The structural and geometrical differences between compounds (1) and (3) on the one hand and compound (2) on the other can to a large part be traced back to the lack of available water in the crystallization solvent in (2) which starves the cation not coordinated to AMPO nitrogen atoms of water molecules to saturate its coordination sphere, thus forcing two of the AMPO ligands in (2) to act as a bridging ligands, while the other AMPO ligands in the three structures are mostly monodentate with the coordination mode of the AMPO ligand being completed by weak secondary chelating ṀO interactions
A ti digo ampo de fuego
Este trabajo se inscribe dentro del Proyecto de Investigación «Digital “Música Poética”. Base de datos integrada del Teatro Clásico Español» (FFI2015-65197-C3-2-P) (MINECO/FEDER, UE).El documento contiene la composición a cuatro voces titulada “A ti digo ampo de fuego” del compositor Manuel Machado y de poeta anónimo, perteneciente al Libro de Tonos Humanos (LTH, nº 172), cancionero poético-musical del siglo XVII que se conserva en la Biblioteca Nacional de España (BNE) bajo la signatura M/1262. Se ofrece la transcripción a notación moderna de la música, el texto poético debidamente puntuado y con algunas notas a los versos, varios datos de interés musical y musicológico, y la crítica de la edición cuando es necesario. Esta composición forma parte de la edición completa de este importante cancionero que llevan a término Lola Josa (filóloga) y Mariano Lambea (musicólogo).Consejo Superior de Investigaciones Científicas (CSIC)Universitat de Barcelona (UB)N
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