1,721,041 research outputs found
Synthesis of easily accessible enantiopure tertiary furyl hydroperoxide and use in asymmetric sulfoxidation
No full textMo(CO)6/TBHP catalyzed autoxidation of 5-alkylidene-4,5-dihydrofurans
No full textMo(CO)(6)/t-butyl hydroperoxide, well known to epoxidize olefins, was shown to be a mild and very efficient system for the autoxidation of 5-alkylidene-4,5-dihydrofurans. High yields of primary, secondary and tertiary furyl hydroperoxides have been achieved employing catalytic amount of Mo(CO)(6). A radical mechanism is in agreement with the experimental data
Enantioselective Aldol Condensation of Masked Acetoacetic Esteres to Aldehydes mediated by Chiral Ti(IV)/BINOL Complex
No full textSynthesis of Chiral Sulfoxides and Application in Enantioselective Allylation of Aldehydes with Allyltrichlorosilane
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