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Telomerization reaction of isoprene and cyclic ketones catalyzed by palladium phosphine complexes in the presence of water
No full textTelomerization of isoprene with cyclopentanone (I) or cyclohexanone (II) in the presence of H2O and tertiary phosphine Pd(0) complexes gave the tail-to-tail telomers III (n = 0, 1), resp. Thus, treatment of I or II with isoprene in the presence of H2O, PEt3, and [LPd(OAc)]2 (L = η3-2-methylallyl) at 80° for 20 h gave the dienes III (n = 0, 1), resp
Reaction of trans-{PtH2[P(C6H11)3]2} with carbon disulphide. Kinetic study of the insertion reaction and X-ray structure of trans-{PtH(S2CH)[P(C6H11)3]2}
No full textCarbon disulphide inserts into the PtH bond of trans-{PtH2[P(C6H11)3]2} to give trans-{PtH(S2CH) [P(C6H11)3]2}. The X-ray structure shows that the -S2CH group is bonded to the metal through a sulfur atom as a monodentate thioformate anion. The kinetics of the carbon disulfide insertion have been investigated. The results account for a mechanism involving CS2 addition to trans-{PtH2[P(C6H113]2} to give a five-coordinate intermediate, which collapses to trans-{PtH(S2CH)[P(C6H11)3]2}
Going Beyond Counting First Authors in Author Co-citation Analysis
Full text linkThe present study examines one of the fundamental aspects of author co-citation analysis (ACA) - the way co-citation
counts are defined. Co-citation counting provides the data on which all subsequent statistical analyses and mappings
are based, and we compare ACA results based on two different types of co-citation counting - the traditional type that
only counts the first one among a cited work's authors on the one hand and a non-traditional type that takes into
account the first 5 authors of a cited work on the other hand. Results indicate that the picture produced through this non-traditional author co-citation counting contains more coherent author groups and is therefore considerably clearer. However, this picture represents fewer specialties in the research field being studied than that produced through the traditional first-author co-citation counting when the same number of top-ranked authors is selected and analyzed. Reasons for these effects are discussed
Variations on the Author
Full text link“Variations on the Author” discusses two of Eduardo Coutinho’s recent films (Um Dia na Vida, from 2010, and Últimas Conversas, posthumously released in 2015) and their contribution to the general question of documentary authorship. The director’s filmography is characterized by a consistent yet self-effacing form of authorial self-inscription: Coutinho often features as an interviewer that rather than express opinions propels discourses; an interviewer that is good at listening. This mode of self-inscription characterizes him as an author who is not expressive but who is nonetheless markedly present on the screen. In Um Dia na Vida, however, Coutinho is completely absent form the image, while Últimas Conversas, on the contrary, includes a confessional prologue that moves the director from the margins to the center of his films. This article examines the ways in which these works stand out in the filmography of a director who offers new insights into the notion of cinematic authorship
Appropriate Similarity Measures for Author Cocitation Analysis
Full text linkWe provide a number of new insights into the methodological discussion about author cocitation analysis. We first argue that the use of the Pearson correlation for measuring the similarity between authors’ cocitation profiles is not very satisfactory. We then discuss what kind of similarity measures may be used as an alternative to the Pearson correlation. We consider three similarity measures in particular. One is the well-known cosine. The other two similarity measures have not been used before in the bibliometric literature. Finally, we show by means of an example that our findings have a high practical relevance.information science;Pearson correlation;cosine;similarity measure;author cocitation analysis
The dynamic behaviur of η3 – allyl palladium and platinum complexes containing the SnCl3 ligand.
No full textMgH2 as a reducing agent. Part II. Reduction of organic halides in presence of Ni (0) and Pd (0) complexes
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