Hochschule Bonn-Rhein-Sieg
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Analytische Chemie für Dummies
No full textDie Analytik ist zwar ein grundlegendes Thema innerhalb der Chemie, hat es aber ganz schön in sich. Aber keine Sorge, Ulf Ritgen erklärt Ihnen in diesem Buch was Sie zur Analytischen Chemie Wissen sollten. Wie erhält man eigentlich analytische Infos? Welche Standards gibt es? Und wie sollte man überhaupt mit den Stoffgemischen umgehen? All diese Grundlagen werden ausführlich erläutert. Aber auch die Anwendungsgebiete und Methoden kommen keinesfalls zu kurz. Egal ob Gravimetrie, Titration, Fällung oder Konduktometrie, endlich wird alles verständlich erklärt. Jetzt können Prüfung und Praktikum kommen! (Verlagsangaben
Improvement of Solvent Exchange for Supercritical Dried Aerogels
No full textThe solvent exchange as one of the most important steps during the manufacturing process of organic aerogels was investigated. This step is crucial as a preparatory step for the supercritical drying, since the pore solvent must be soluble in supercritical carbon dioxide to enable solvent extraction. The development and subsequent optimization of a suitable system with a peristaltic pump for automatic solvent exchange proved to be a suitable approach. In addition, the influence of zeolites on the acceleration of the process was found to be beneficial. To investigate the process, the water content in acetone was determined at different times using Karl Fischer titration. The shrinkage, densities, as well as the surface areas of the aerogels were analyzed. Based on these, the influence of various process parameters on the final structure of the obtained aerogels was investigated and evaluated. Modeling on diffusion in porous materials completes this study
Atomic oxygen in the mesosphere and lower thermosphere measured by terahertz heterodyne spectroscopy
No full textAtomic oxygen is a main component of the mesosphere and lower thermosphere (MLT). The photochemistry and the energy balance of the MLT are governed by atomic oxygen. In addition, it is a tracer for dynamical motions in the MLT. It is difficult to measure with remote sensing techniques. Concentrations can be inferred indirectly from the oxygen air glow or from observations of OH, which is involved in photochemical processes related to atomic oxygen. Such measurements have been performed with several satellite instruments such as SCIAMACHY, SABER, WINDII and OSIRIS. However, the methods are indirect and rely on photochemical models and assumptions such as quenching rates, radiative lifetimes, and reaction coefficients. The results are not always in agreement, particularly when obtained with different instruments
IllumiWand: Improving 3D Interaction with Monoscopic Displays Through a Projected Physical 3D Pointer
No full textTelepräsenz-Roboter im häuslichen Lebens- und Pflegearrangement von Personen mit Demenz im ländlichen Raum (RoboLand): gemeinsamer Abschlussbericht des Verbundvorhabens der Hochschule Fulda und Bonn-Rhein-Sieg, Laufzeit des Vorhabens: 01.12.2016-31.07.2020
No full textA Tabletop for the Natural Inspection of Decorative Surfaces
No full textDesigns for decorative surfaces, such as flooring, must cover several square meters to avoid visible repeats. While the use of desktop systems is feasible to support the designer, it is challenging for a non-domain expert to get the right impression of the appearances of surfaces due to limited display sizes and a potentially unnatural interaction with digital designs. At the same time, large-format editing of structure and gloss is becoming increasingly important. Advances in the printing industry allow for more faithful reproduction of such surface details. Unfortunately, existing systems for visualizing surface designs cannot adequately account for gloss, especially for non-domain experts. Here, the complex interaction of light sources and the camera position must be controlled using software controls. As a result, only small parts of the data set can be properly inspected at a time. Also, real-world lighting is not considered here. This work presents a system for the processing and realistic visualization of large decorative surface designs. To this end, we present a tabletop solution that is coupled to a live 360° video feed and a spatial tracking system. This allows for reproducing natural view-dependent effects like real-world reflections, live image-based lighting, and the interaction with the design using virtual light sources employing natural interaction techniques that allow for a more accurate inspection even for non-domain experts
Go - know your position, set your course, keep your stance
No full textThe year 2020 was dominated by the Corona pandemic, which abruptly changed everyday life at the university. Bonn-Rhein-Sieg University of Applied Sciences (H-BRS) succeeded not only in maintaining operations under these difficult circumstances, but also in enriching them with new ideas and insights. This difficult year 2020 has opened up new perspectives, especially for teaching, but also for research and administration. This annual report, to which we have given the motto "Walking - knowing the point of view, taking direction, showing attitude", tells of this. It shows which paths the H-BRS has taken in the past year. Some routes were rocky, and some slopes could only be overcome with combined efforts. Often, however, new terrain was opened up. The aim was always to find answers to the multi-layered, complex questions of our time - whether with regard to digitalisation, climate change or the social responsibility of science
The Effects of Chain-Extending Cross-Linkers on the Mechanical and Thermal Properties of Poly(butylene adipate terephthalate)/Poly(lactic acid) Blown Films
No full textThis study investigates the effects of four multifunctional chain-extending cross-linkers (CECL) on the processability, mechanical performance, and structure of polybutylene adipate terephthalate (PBAT) and polylactic acid (PLA) blends produced using film blowing technology. The newly developed reference compound (M·VERA® B5029) and the CECL modified blends are characterized with respect to the initial properties and the corresponding properties after aging at 50 °C for 1 and 2 months. The tensile strength, seal strength, and melt volume rate (MVR) are markedly changed after thermal aging, whereas the storage modulus, elongation at the break, and tear resistance remain constant. The degradation of the polymer chains and crosslinking with increased and decreased MVR, respectively, is examined thoroughly with differential scanning calorimetry (DSC), with the results indicating that the CECL-modified blends do not generally endure thermo-oxidation over time. Further, DSC measurements of 25 µm and 100 µm films reveal that film blowing pronouncedly changes the structures of the compounds. These findings are also confirmed by dynamic mechanical analysis, with the conclusion that tris(2,4-di-tert-butylphenyl)phosphite barely affects the glass transition temperature, while with the other changes in CECL are seen. Cross-linking is found for aromatic polycarbodiimide and poly(4,4-dicyclohexylmethanecarbodiimide) CECL after melting of granules and films, although overall the most synergetic effect of the CECL is shown by 1,3-phenylenebisoxazoline
Evaluation of Practical Applicability and Synergistic Effects of Bio-Based Food Packaging Materials Combined with Plant-Based Stabilisers
No full textDifferent analyses and feasibility studies have been conducted on the plant extracts of thyme (Thymus vulgaris), European horse chestnut (Aesculus hippocastanum), Nordmann fir (Abies nordmanniana), and snowdrop (Galanthus elwesii) to evaluate bio‐based alternatives to common petrol‐based stabilisers. For this purpose, in this study, plant extracts were incorporated into poly‐lactic acid films (PLA) at different concentrations. The films’ UV absorbance and migration into packed food was analysed via photometric assays (ABTS radical cation scavenging capacity assay, β‐carotene assay) and GC–MS analysis. Furthermore, the synergistic antioxidant effects of various combinations of extracts and isolated active compounds were determined. This way, antioxidant effects can be increased, allowing for a highly effective use of resources. All extracts were successfully incorporated into PLA films and showed notable photoabsorbing effects, while no migration risk was observed. Depending on extract combinations, high synergistic effects of up to 726% can be utilised to improve the effectiveness of bio‐based extracts. This applies particularly to tomato paste and Aesculus hippocastanum extracts, which overall show high synergistic and antioxidant effects in combination with each other and with isolated active compounds. The study shows that it is possible to create safe bio‐based antioxidant films which show even improved properties when using highlighted target combinations
