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Seasonal changes in Saturn’s stratosphere inferred from Cassini/CIRS limb observations
No full textInternational audienceWe present temperature and hydrocarbons abundances (C 2 H 6 , C 2 H 2 , C 3 H 8) retrieved from Cassini/CIRS limb spectra, acquired during northern spring in 2010 (L S = 12 •) and 2012 (L S = 31 •). We compare them to the previous limb measurements performed by Guerlet et al. (2009) during northern winter. The latitudinal coverage (from 79 • N to 70 • S) and the sensitivity of our observations to a broad range of pressure levels (from 20 hPa to 0.003 hPa) allow us to probe the meridional and vertical structure of Saturn's stratosphere during northern spring. Our results show that in the northern hemisphere, the lower stratosphere (1 hPa) has experienced the strongest warming from northern winter to spring (11 ± 1.1 0.9 K), while the southern hemisphere exhibits weak variations of temperature at the same pressure level. We investigate the radiative contribution in the thermal seasonal evolution by comparing these results to the radiative-convective model of Guerlet et al. (2014). We show that radiative heating and cooling by atmospheric minor constituents is not always sufficient to reproduce the measured variations of temperature (depending on the pressure level). The measurements of the hydrocarbons abundances and their comparison with the predictions of the 1D photochemical model of Moses and Greathouse (2005) give insights into large scale atmospheric dynamics. At 1 hPa, C 2 H 6 , C 2 H 2 , and C 3 H 8 abundances are remarkably constant from northern winter to spring. At the same pressure level, C 2 H 6 and C 3 H 8 exhibit homogeneous meridional distributions unpredicted by this photochemical model, unlike C 2 H 2. This is consistent with the existence of a meridional circulation at 1 hPa, as suggested by previous studies
Modeling of smart materials with thermal effects: dynamic and quasi-static evolution
No full textInternational audienceWe present a mathematical model for linear magneto-electro-thermo-elastic continua, as sensors and actuators can be thought of, and prove the well-posedness of the dynamic and quasi-static problems. The two proofs are accomplished, respectively, by means of the Hille-Yosida theory and of the Faedo-Galerkin method. A validation of the quasi-static hypothesis is provided by a nondimensionalization of the dynamic problem equations. We also hint at the study of the convergence of the solution to the dynamic problem to that to the quasi-static problem as a small parameter – the ratio of the largest propagation speed for an elastic wave in the body to the speed of light – tends to zero
From Radio to TeV: The surprising Spectral Energy Distribution of AP Librae
No full text13 pages 5 figuresInternational audienceFollowing the discovery of high-energy (HE; E>10\,{\rm MeV}) and very-high-energy (VHE; E>100\,{\rm GeV}) -ray emission from the low-frequency-peaked BL~Lac (LBL) object AP Librae, its electromagnetic spectrum is studied over 60 octaves in energy. Contemporaneous data in radio, optical and UV together with the -ray data are used to construct the most precise spectral energy distribution of this source. The data have been found to be modeled with difficulties with single zone homogeneous leptonic synchrotron self-Compton (SSC) radiative scenarios due to the unprecedented width of the high-energy component when compared to the lower-energy component. The two other LBL objects also detected at VHE appear to have similar modeling difficulties. Nevertheless, VHE rays produced in the extended jet could account for the VHE flux observed by H.E.S.S
Detecting time periods of differential gene expression using Gaussian processes: An application to endothelial cells exposed to radiotherapy dose fraction
No full textInternational audienceMotivation: Identifying the set of genes differentially expressed along time is an important task in two-sample time course experiments. Furthermore, estimating at which time periods the differential expression is present can provide additional insight into temporal gene functions. The current differential detection methods are designed to detect difference along observation time intervals or on single measurement points, warranting dense measurements along time to characterize the full temporal differential expression patterns. Results: We propose a novel Bayesian likelihood ratio test to estimate the differential expression time periods. Applying the ratio test to systems of genes provides the temporal response timings and durations of gene expression to a biological condition. We introduce a novel non-stationary Gaussian process as the underlying expression model, with major improvements on model fitness on perturbation and stress experiments. The method is robust to uneven or sparse measurements along time. We assess the performance of the method on realistically simulated dataset and compare against state-of-the-art methods. We additionally apply the method to the analysis of primary human endothelial cells under an ionizing radiation stress to study the transcriptional perturbations over 283 measured genes in an attempt to better understand the role of endothelium in both normal and cancer tissues during radiotherapy. As a result, using the cascade of differential expression periods, domain literature and gene enrichment analysis, we gain insights into the dynamic response of endothelial cells to irradiation
Homonym Population Protocols, or Providing a Small Space of Computation Using a Few Identifiers
No full textInternational audiencePopulation protocols have been introduced by Angluin et al. as a model in which n passively mobile anonymous finite-state agents stably compute a predicate on the multiset of their inputs via interactions by pairs. The model has been extended by Guerraoui and Ruppert to yield the community protocol models where agents have unique identifiers but may only store a finite number of the identifiers they already heard about. The population protocol models can only compute semi-linear predicates, whereas in the community protocol model the whole community of agents provides collectively the power of a Turing machine with a O(n log n) space. We consider variations on the above models and we obtain a whole landscape that covers and extends already known results: By considering the case of homonyms, that is to say the case when several agents may share the same identifier, we provide a hierarchy that goes from the case of no identifier (i.e. a single one for all, i.e. the population protocol model) to the case of unique identifiers (i.e. community protocol model). We obtain in particular that any Turing Machine on space O(logO(1) n) can be simulated with at least O(logO(1) n) identifiers, a result filling a gap left open in all previous studies. Our results also extend and revisit in particular the hierarchy provided by Chatzigiannakis et al. on population protocols carrying Turing Machines on limited space, solving the problem of the gap left by this work between per-agent space o(log log n) (proved to be equivalent to population protocols) and O(log n) (proved to be equivalent to Turing machines)
Difluorinated 6,13-Bis(triisopropylsilylethynyl)pentacene: Synthesis, Crystallinity, and Charge-Transport Properties
No full textInternational audienceFluorination has been demonstrated to improve stability and processing in thiophene-containing small-molecule semiconductors. Here, the impact of partial fluorination on these parameters in a pentacene derivative is examined. Although the improvement in photostability is not as dramatic, there is a clear improvement in the stability of the chromophore upon fluorination. The improvement in processability is more dramatic; devices formed by spin-coating with the fluorinated derivative perform substantially better than those formed from the nonfluorinated compound
Poly(4-vinyl pyridine) radiografted PVDF track etched membranes as sensors for monitoring trace mercury in water
No full textInternational audiencePoly-4-vinyl pyridine chains were radiografted inside the etched-tracks of PVDF nanoporous membrane. P4VP grafting was found to be localized on the solid PVDF surface. Coating of these PVDF-g-P4VP membranes with a very thin layer of gold results in an ASV electrochemical sensor. Functionalized ion track-etched PVDF-g-P4VP sensors were found very selective and highly sensitive for mercury LOD 5 ng/L. a b s t r a c t By a radiation-induced grafting technique, we have functionalized track-etched nanoporous polymer membranes with mercury sensitive poly-4-vinyl pyridine (P4VP). Coating of these membranes with a very thin layer of gold results in an electrochemical sensor that is very selective and highly sensitive for mercury LOD 5 ng/L – well below the norms for water (0.015 mg/L potable water and 0.5 mg/L residual waters-French water norms of 27 October 2011). E-beam irradiation permitted optimization of the radiografting synthesis on PVDF thin films prior to ion-track grafting. Synthesis and characterization by EPR, FESEM and FTIR are described in detail. A comparison between FTIR in ATR and transmission modes enabled us to localize the grafting on the surface of the e-beam irradiated PVDF films allowing us to extrapolate what happens on the etched tracks. Using Square Wave Anodic Stripping Voltammetry (SW-ASV), mercury concentrations of 1 mg/L are detected in 2 h and low ng/L concentrations are detected after 24 h of adsorption. The adsorption is passive so sensors do not require instrumentation and the analysis takes only 3–4 min. Also, the P4VP functionalized sensor appears insensitive to pH variations (pHs 3–9), high salt concentrations (up to 1 g/ L) and the presence of other heavy metals in the same solution.
Geometry Flexibility of Copper Iodide Clusters: Variability in Luminescence Thermochromism.
No full textInternational audienceAn original copper(I) iodide cluster of novel geometry obtained by using a diphosphine ligand is reported and is formulated [Cu6I6(PPh2(CH2)3PPh2)3] (1). Interestingly, this sort of “eared cubane” cluster based on the [Cu6I6] inorganic core can be viewed as a combination of the two known [Cu4I4] units, namely, the cubane and the open-chair isomeric geometries. The synthesis, structural and photophysical characterisations, as well as theoretical study of this copper iodide along with the derived cubane (3) and open-chair (2) [Cu4I4(PPh3)4] forms, were investigated. A new polymorph of the cubane [Cu4I4(PPh3)4] cluster is indeed presented (3). The structural differences of the clusters were analyzed by solid-state nuclear magnetic resonance spectroscopy. Luminescence properties of the three clusters were studied in detail as a function of the temperature showing reversible luminescence thermochromism for 1 with an intense orange emission at room temperature. This behavior presents different feature compared to the cubane cluster and completely contrasts with the open isomer, which is almost nonemissive at room temperature. Indeed, the thermochromism of 1 differs by a concomitant increase of the two emission bands by lowering the temperature, in contrast to an equilibrium phenomenon for 3. The luminescence properties of 2 are very different by exhibiting only one single band when cooled. To rationalize the different optical properties observed, density functional theory calculations were performed for the three clusters giving straightforward explanation for the different luminescence thermochromism observed, which is attributed to different contributions of the ligands to the molecular orbitals. Comparison of 3 with its [Cu4I4(PPh3)4] cubane polymorphs highlights the sensibility of the emission properties to the cuprophilic interactions
Mechanochromic luminescence of copper iodide clusters.
No full textInternational audienceLuminescent mechanochromic materials are particularly appealing for the development of stimuli-responsive materials. Establishing the mechanism responsible for the mechanochromism is always an issue owing to the difficulty in characterizing the ground phase. Herein, the study of real crystalline polymorphs of a mechanochromic and thermochromic luminescent copper iodide cluster permits us to clearly establish the mechanism involved. The local disruption of the crystal packing induces changes in the cluster geometry and in particular the modification of the cuprophilic interactions, which consequently modify the emissive states. This study constitutes a step further toward the understanding of the mechanism involved in the mechanochromic luminescent properties of multimetallic coordination complexes
Integrated Testing Strategies (ITS) for safety assessment.
No full textInternational audienceIntegrated testing strategies (ITS), as opposed to single definitive tests or fixed batteries of tests, are expected to efficiently combine different information sources in a quantifiable fashion to satisfy an information need, in this case for regulatory safety assessments. With increasing awareness of the limitations of each individual tool and the development of highly targeted tests and predictions, the need for combining pieces of evidence increases. The discussions that took place during this workshop, which brought together a group of experts coming from different related areas, illustrate the current state of the art of ITS, as well as promising developments and identifiable challenges. The case of skin sensitization was taken as an example to understand how possible ITS can be constructed, optimized and validated. This will require embracing and developing new concepts such as adverse outcome pathways (AOP), advanced statistical learning algorithms and machine learning, mechanistic validation and "Good ITS Practices"