Jurnal Riset Kimia
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PENGARUH PENGGUNAAN PENYALUT BIOBLEND PS/PCL TERHADAP PELEPASAN ZAT AKTIF UREA GRANUL
Get PDFThe most widely used surfactant is an anionic surfactant which is synthesized from petroleum namely Linear Alkylbenzene sulphonate (LABS). Methyl Ester Sulfonate which is currently being developed. Surfactant can produced from palm oil methyl ester via sulfonation sulfonate. When in this research using sodium metabisulphite. The aims of this work is to synthesize Methyl Ester Sulfonate surfactant from Palm Oil Methyl Ester using Sodium Metabisulphite and a catalyst Calcium Oxide. The effects of time and the mole ratio are also investigated. Sulfonation process carried out in 4, 5, 6 hours with mole ratio of 1: 0,5, 1:1, 1: 1,5, temperature of 80° C and with stirring speed of 450 rpm. It haven been found that the surfactant produced has density of (0.89490 g/cm3 - 0.89545 g/cm3), viscosity (2.0323 cP - 2.1329 cP), pH (2,03 - 2,48), surface tension (32.60 mN/m - 33.60 mN/m), interfacial tension (30.45 mN/m - 30.94 mN/m), and the stability emulsion (59.17% - 89, 17%)
STUDI HANTARAN LISTRIK SENYAWA SRN+1TINO3N+1 (N = 1 DAN 2) FASA RUDDLESDEN-POPPER YANG DISINTESIS DENGAN METODE LELEHAN GARAM
Get PDFSrn+1TinO3n+1 (n = 1, 2,...n)Ruddlesden-Popper phase is a metal oxide compound with a layered structure consisting of SrTiO3 perovskite layers and strontium oxide (SrO) layers, thus this material has a potential as termoeletrik compounds that could be developed as an alternative material for renewable energy. In this study, we examine one of the 3 parameters of termoelectric properties, namely the electrical conductivity. Srn+1TinO3n+1 (n = 1 and 2)Ruddlesden-Popper phases were synthesized using molten salt method. The synthesis was carried out at 950 °C for 10 hours with a ratio of precursor and salt were 1: 0.5. Structural analysis by X-Ray Diffractometer (XRD) confirmed that all synthesized compounds formed Srn+1TinO3n+1 (n = 1, and 2) Ruddlesden-Popper phase with the characteristic peaks at 2q = 31o, 32o, and 46o. The morphology analysis by Scanning Electron Microscope (SEM) showed that the particles have plate-shaped with crystallites size were 20 nm. The electrical properties were measured using LCR meter with the highest electrical conductivity of 2.25x10-7 S / cm which showed the semiconductors behaviour
PEMBUATAN LAPISAN TIPIS TiO2 -DOPED LOGAM M (M= Ni, Cu dan Zn) DENGAN METODA DIP-COATING DAN APLIKASI SIFAT KATALITIKNYA PADA PENJERNIHAN AIR RAWA GAMBUT
Get PDF ABSTRACT Preparation of TiO2-doped M (M = Ni, Zn and Cu) has been prepared on glass substrate using dip-coating technique. Titanium isopropoxide (TIP), Ni(OAct)2.4H2O, Zn(OAct)2.2H2O dan Cu(OAct)2 were used as starting materials and diethanolamine (DEA) as additive in isopropanol solution. Solutions were prepared by mixing of various concentration of metals (1, 3 and 5 mol %)  in 0.5 M TIP solution. Thin films were performed by immersion of glass substrate into solution by withdraw speed of 20 cm/min. Coated glass were dried at 100 – 110°C and heated at 500°C the process were repeated for several time. The product was characterized by XRD and showing TiO2 layer of anatase structure. EDX analysis has shown that thin films have found of Ti and doped-metal. Their crystallized sizes were calculated by Scherrer formula shown that it obtained in various in range of 12-21 nm. According to transformation effectively of titania doped M in peat swam water shown that catalytic activity 34.4 – 53.7% for the irradiation during 24 hours. Keywords : titania, thin films, photocatalytic propertie
PEMANFAATAN FUNGSI ANTI OKSIDAN GAMBIR (Uncaria gambir) SEBAGAI HEPATOPROTEKTOR
Get PDF ABSTRACT The aim of the research is to find out the effect of the hepatoprotector from gambier to some rats animal contaminated by carbon tetrachloride (CCl4). The research was done in Biochemistry laboratory Medical Faculty Andalas University Padang applied to 12 galur wistar rats species in about ± 2 months ages with 170-200 g weight, which are separated into 3 groups (clusters). They are cluster in negative control, in positive control (CCl4 2 mg/kgBB inductions), and treated cluster (CCl4  inductions and 10 mg/kgBB gambier given). Statistically analyzed the data by one way Anova test with 95% confidence of degree, the result of the research are pointed to the rate of MDA serum level which is 1.08 ± 0.12 nmol/mL for the cluster in negative control, 4.07 ± 0.45 nmol/mL for positive control cluster, and 3.28 ± 0.46 nmol/mL for treated cluster showed the significant differences between the 3 clusters. The rates of MDA lever level to the cluster in negative control is about 1.80 ± 0.30 nmol/mL, in positive control is about 4.55 ± 0.56 nmol/mL, and the treated cluster is about 3.92 ± 0.22 nmol/mL, from the 3 clusters above shows that there is only the positive control and the treated control has no meaning of purpose. It concluded that the CCl4  has the hepatotoxite effect with gambier could be functionated as the hepatoprotector. Key words : gambier, CCl4, hepatoprotector, MDA   Â
PENENTUAN KANDUNGAN LOGAM ESENSIAL (Fe, Zn DAN Cu) DALAM DAUN SIRIH MERAH (Piper crocatum) SEGAR, AIR REBUSAN DAN AIR SEDUHANNYA DENGAN METODE SPEKTROSKOPI SERAPAN ATOM(SSA)
Get PDFVol 7 No 2ABSTRACTDetermination of essential metals (Fe, Zn and Cu) in red betel leaf has been carried out by usingAtomic Absorption Spectrophotometer (AAS). Fresh and dry red betel leaf extracted in 75 mLby boiled and brewed distilled water for 5, 10, 15 and 20 minutes. In the fresh red betel leafmetal content (Fe, Zn and Cu) were 0,3257 %, 0,173 % and 0,0278 % and the highest metalcontent (Fe, Zn and Cu) found in dry red betel leaf which were boiled for 20 minutes with theconcentration 0,0539 %, 0,0305 % and 0,0128 %. Red betel leaf is a source of essential metalsneeded by the body.Keywords: Atomic Absorption Spectrophotometry (AAS), Red betel leaf (Piper crocatum),decoction water, steeping water, Fe, Zn and C
DIP-COATING SENYAWA KALSIUM FOSFAT DARI BATU KAPUR BUKIT TUI MELALUI METODE SOL-GEL
Get PDF ABSTRACT Preparation of Dip-Coating Calcium Phosphate via sol-gel method using natural limestone Bukit Tui as calcium precursors and diammonium hydrogen phosphate as phosphorus precursors with sol-gel process has been investigated. Ethanol was used as solvent and DEA (diethanolamine) was used stabilizing agent. The powder were prepared by calcinated the sol at 950 oC. The products were characterized by Fourier Transform Infra Red, X-Ray Diffraction and Scanning Electron Microscopy. FTIR results showed that the vibration form was PO43-, P2O74-, O-H and CO2. XRD patterns of powder with various Ca/P mol ratio showed that the product of calcium phosphate was Ca2P2O7 and also found the hydroxyapatite Ca10(PO4)6(OH)2 in Ca/P mol ratio 1,7. SEM images of powder calcium phosphate revealed that their morphology were spheric and homogen. The coating process was done at glass substrate with coating speed 20 cm/min by calcinations at 400 oC. XRD patterns of thin layer showed that the product was Ca2P2O7 and SEM images of thin layer revealed that their morphology were bulk. Keywords: Natural limestone, calcium phosphate, hydroxyapatite, sol-gel, dip-coatin
PENGARUH TEMPERATUR DAN KONSENTRASI KATALIS PADA CRACKING CANGKANG SAWIT MENJADI CRUDE BIO-FUEL
Get PDF ABSTRACT One of solid waste that produced by palm industry is palm oil shell. This waste abundant in Riau about 700.5 ton/day. The shell compositions are cellulosa, hemicellulosa, and lignine. That compounds can be cracked into crude biofuel in slurry reactor with NiMo/ZSM-5 catalyst. The objective of research to study the influence of cracking temperature (300, 310, 320, 330 0C) and concentration of catalyst (0.5; 1.5; 2.5; 3.5%) to yield of crude biofuel and to determine physical and chemical properties. Cracking process used 50 gram palm oil shell size -40+60 mesh, 500 mL silinap and rotation speed of mixing 300 rpm. The maximum yield was obtained 68.6% at temperature 330 0C and catalyst concentration NiMo/ZSM-5 2.5%. The physical properties of crude biofuel were calorimetric value (43.84 MJ/kg), density (1.01 g/mL), viscocity (13.27cSt), acid number (76.11 g NaOH/g sample) and flash point (64 0C). The GC-MS analysis result indicated dominant compounds in crude biofuel were acetic acid (33.94%), phenol (31.71%), furancarboxaldehide (7.78%) and methanol (4.93%). Key words : Catalyst, crude biofuel, palm oil shellÂ
STUDI OPTIMASI PENENTUAN UNSUR HARA BESI DALAM CAMPURAN TANAH DAN KOMPOS MENGGUNAKAN METODE SPEKTROFOTOMETRI
Get PDFDetermination of iron nutrient content in a mixture of soil and compost with spectrophotometric method has been carried out. Metal ions Fe(II) complexed with 0.1% ortho-fenantrolin 2 mL, 0.01 M citric acid as reducing agent using acetat buffer at pH 4.5 and its complex was measured by using spectrophotometer UV/Vis at wavelength 515 nm, the complex stability for was 60 minutes . The highest nutrient of iron with content in soil:compost with ratio of 0.8:0.2 was 0.92% at incubation time 30 days. The lowest iron content in the mixture of soil:compost (1:0) at incubation time for 15 days was 0.58% that obtained by the regression equation y = 95.85x + 0.025 with R2=0.992. The level of nutrient iron in compost obtained lower than the maximum regulated by SNI 2.00%
PENGARUH WAKTU REAKSI DAN RASIO MOL ASAM LINOLEAT DENGAN ISOPROPANOL PADA SINTESA PLASTISIZER ISOPROPIL LINOLEAT
Get PDFDiversity of palm oil product in Indonesia is still limited, therefore it is needed to take an advantage of the development of downstream product of crude palm oil by esterification reaction. Esterification reaction is a reaction between carboxylic acid and alcohol to form ester. One of the emerging downstream product fatty acid alkyl ester is plasticizer. Plasticizer is an additive compound added to polymer to improve flexibility and workability. The purpose of this research was conducted to study the effect of reaction time and mole ratio and identify product of plasticizers isopropyl linoleic. In this research, plasticizer was synthesized by esterification of linoleic acid and isopropanol, using activated natural zeolite catalyst. The process was done with a variation of reaction time (4, 6, and 8 hours) and mole ratio (1: 6, 1: 9, and 1:12), with reaction temperature at 80 °C, stirring speed at 200 rpm and 15% of composition of linoleic acid based catalyst as fixed variables. From the analysis of the results showed that the esterification reaction time and mole ratio affect the product conversion. The best operating condition obtained in this research was 4 hours of reaction time and 1:12 of mole ratio which resulted the conversion of reaction was 67.09%. Characteristics of plasticizer produced from this research were viscosity (at 20 °C) 2.405 to 2.803 mPa.s and Specific Gravity (at 20 °C) from 0.863 to 0.872
OKSIDASI SORBITOL MENGGUNAKAN MOLEKUL OKSIGEN YANG DIAKTIFASI KATALIS Pd/-Al2O3 DALAM PELARUT AIR
Get PDF ABSTRACT The sorbitol has been oxidized by molecular oxygen that activated by Pd/g-Al2O3 catalyst in water solvent at 70°C. The product was contained 1.3 g (26%) of the glucaric acid. The product was characterized by FT-IR and 1H-NMR spectrophotometer. The product oxidation was reacted with solution of sodium hydroxide methanol at 70°C during 5 hours produced sodium dicarboxylate in the form yellow gel about 0.3 g (30%). The product was characterized by FT-IR and 1H-NMR spectrophotometer. Keywords: sorbitol, oxidation, catalyst, Pd/g-Al2O3, oxygen molecularÂ