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    Application of Cowdung and Sawdust as Biostimulants for Enhanced Bioremediation of Diesel Contaminated Soil

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    The study was aimed at exploring the use of cow dung (CD) and sawdust (SD) as bio stimulants for enhanced ex-situ bioremediation of diesel fuel contaminated soil. Results of the microbial populations in a gram of soil showed that diesel polluted soil amended with CD had the highest total culturable heterotrophic bacterial (TCHB) population range (1.42 x 106 - 1.56 x 107Cfu/g), total fungal (TF) (1.0 x 106 \u2013 1.60x107Cfu/g), hydrocarbon utilizing bacteria (HUB) (4.5 x 106 \u2013 2.05 x 107Cfu/g) and hydrocarbon utilizing fungi (HUF) (3.5 x 106 \u2013 1.3 x 107Cfu/g) respectively during the study. Diesel polluted soil amended with SD had lower TCHB populations (1.32 x 106 \u2013 2.0 x 107Cfu/g), TF (6.0 x 106 \u2013 3.6 x 107 Cfu/g), HUB (5.4 x 106 \u2013 1.28 x 107Cfu/g) and HUF (1.2 x 106 \u2013 2.0 x 106Cfu/g) respectively, while the microbial populations in option C (control) were TCHB (1.14 x 106 \u2013 1.18 x 107Cfu/g), TF (1.7 x 106 \u2013 7.0 x 106Cfu/g), HUB (4.2 x 106 \u2013 7.8 x 106Cfu/g) and HUF (1.1 x 106 \u2013 5.0 x 107Cfu/g) respectively. Changes in pH values showed reductions in CD (7.10 \u2013 6.20) and SD (5.78 \u2013 4.88) amended soils. Percentage losses in TPH from chromatography results showed diesel polluted soil amended with CD (61.30%), SD (41%) and control (4.11%) respectively. Characterization and identification tests of bacterial isolates revealed that a microbial consortium comprising of the following HUB genera; Bacillus, Pseudomonas, Proteus, Alcaligenes, Klebsiella, Enterobacter, Citrobacter, Corynebacterium and Escherichia coli was implicated in the biodegradation process. Similarly, the HUF encountered were Fusarium, Aspergillus, Microsporium, Penicilium and Mucor. The results suggest that the application of cow dung as biostimulant will enhance the bioremediation of diesel contaminated soil than the application of sawdust

    Market Town Household Solid Waste Management: A Case Study of Embu, Kenya

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    Household solid waste management directly impacts human health and the environment. Globally, increasing quantities and complexity of household solid waste has become a menace in many market towns. The aim of this study was to establish the status of household solid waste management in the market town of Embu in Kenya. The objectives were to identify the methods used by households to manage solid waste and to establish the factors that influenced the households\u2019 choice of solid waste management method. A survey design was deployed and questionnaires were used in data collection. Data analysis was done using the Statistical Package for Social Sciences software. 37% of the households discarded their solid waste in open places, 32% burnt and 24% recycled it. About 8% households reused the solid waste. Employment, education and access to waste collection services were the major factors influencing household solid waste management strategy. Sustainability of household solid waste management depended on awareness on health and environmental benefits of improved household solid waste management, reduction in household solid waste generation and establishment of a household solid waste management policy for Embu market Town. It was concluded that the current practices for household solid waste management are inadequate. High level of unemployment and low education level hinder proper household solid waste management. Awareness on the health and environmental benefits and policy could improve household waste management in the market town

    Magnetic Pollution of Soil Samples at Some Industrial Sites in Jos Metropolis, Plateau State, Nigeria

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    Magnetic susceptibility of polluted material can give a general view of the degree of heavy metal pollution, prior to a more expensive and time-consuming chemical analyses. In this study, magnetic susceptibility measurements of 40 soil samples collected from some industrial sites of Jos Metropolis, were made using MS2G Sensor connected to Bartington MS 2 susceptibility meter. Volume magnetic susceptibility values ranged from 0.00026 x 10-5 SI to 0.0650 x 10-5 SI while low frequency mass specific susceptibility values ranged from 0.1181 x 10-6 m3kg-1 to 20.3 x 10-6 m3kg-1. In both cases least and highest values are recorded at Zuma Steel and Dilimi respectively. Comparing low frequency mass specific susceptibility values obtained from industrial sites to that obtained from non-industrial sites, it was observed that samples 11 and 12 from JIB and all samples collected from Dilimi recorded values higher than the background soil samples thus indicating magnetic enhancement of soil at these locations by anthropogenic sources. The relationship between the volume magnetic susceptibility and mass specific susceptibility showed correlation of 0.983 implying that volume magnetic susceptibility results can be accepted in the absence of low frequency mass specific susceptibility measurement to assess magnetic pollution. The study also revealed that the magnetic behaviour of the dried soil samples collected from the industrial sites are controlled by concentration of ferrimagnetic minerals

    Facies Architecture Analysis for Paleo-environment Evaluation in \u201cTom\u201d Oil Field, Eastern Niger Delta, Nigeria

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    The cored section of reservoir C, well 4 of the drilled five wells that penetrated three reservoirs A, B and C in \u201cTOM\u201d oil field, Eastern Niger Delta was analysed and described on the basis of lithofacies, sedimentary structures and trace fossil records by using core data and wireline log motifs, with the aim of carrying out thorough geological core analysis to interpret the depositional environment of the oil field. The lithofacies are sandstones with interbedded mudstones and siltstones, the dominant sedimentary structures are parallel to ripple cross laminations, hummocky and swaley cross stratifications, sandy hetherolitics, planar to low angle cross bedding with traces of Teichichnus and Ophiomorpha burrows. The gamma-ray log motifs were noted and used to further constrain the character of the sedimentary facies and depositional environment of the field. A tidal incised \u2013 fluvial dominated shallow marine (lower, middle, upper shoreface) comprises of tidal channel sands and tidal flat of the coastal shelf depositional setting in the marginal marine mega depositional environment had been inferred for the \u201cTOM\u201d field

    Heavy Metal Levels in Vegetables and Soil Cultivated with Industrial Wastewater from Different Sites of Chunian and Jamber, District, Kasur

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    In human diet, vegetables play important role to maintain the physiological conditions. Due to anthropogenic activities and pollution, the food items become contaminated. The present study was performed to evaluate the level of heavy metals in the vegetables irrigated with wastewater across Chunian and Jamber, district, Kasur. Level of heavy metals from the study area like Zinc, Lead and chromium in the soil, water and vegetables was compared. The four sites of each city and 10 vegetables e.g. potato, radish, carrot, fenugreek, spinach, tomato, Onion, Turnip, Cauliflower, Pangalo were selected to conduct the experiment. The vegetables were irrigated with industrial wastewater and the concentration of heavy metals was measured by the atomic absorption spectrophotometer (AAS). We concluded that the level of heavy metals was beyond the FAO limits in irrigated water due to industrial waste. In Jamber and Chunian, the level of Zn and Pb was high and beyond the FAO safe limits in the all water sample, the level of Cr was much higher only in the water sample of one site from Jamber. The concentration of zinc was higher in soil samples as compared to lead and chromium. Zn and Pb in vegetables of study area were labeled as priority pollutants but this concentration was within the safe limits set by FAO. However, constant inspection of heavy metals is recommended to avoid accumulation in the food chain and thus avoid human health risks

    Comparative Study of Response Surface Methodology and Artificial Neural Network for Modeling and Optimization of Extraction Process Parameters on Tetrapleura Tetraptera

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    Bioactive compounds in the fruits of Tetrapleura tetraptera is widely used in food as a flavouring agent and for spices. In this study, bioactive compounds were extracted by solid-liquid extraction process and the yield was optimized by response surface methodology (RSM) and artificial neural network (ANN). The process parameters optimized were the extraction temperature, particle size and extraction time. Box-Behnken Design was used to study the effect of the process parameters on the extract yield. A quadratic model was obtained by RSM which was used to predict the extract yield. While for ANN, Bayesian Regularization learning algorithm with hyperbolic function (Tanh) for both hidden and output layers was the best model for predicting the extract yield. The performance of both models was established based on their R2 and RMSE values. (R2 and RMSE values were 0.9391 and 3.10 for RSM and 0.9637 and 0.8193 for ANN respectively). ANN gave the maximum extract yield of 29.15 % higher than that of RSM which evaluated a yield of 27.70 % with optimum conditions at extraction temperature of 90\ub0C, particle size of 3.26 mm and extraction time of 50 mins. It was therefore concluded that ANN is better than RSM in the modeling and optimization of the extraction process parameters

    Adsorption of Cu (II) and Ni (II) Ions from Solution onto Calcium Alginate Beads

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    The objective of this study was to investigate the biosorption of Cu (II) and Ni (II) ions from aqueous solution by calcium alginate beads. The effects of solution pH, contact time and initial metal ion concentration were evaluated. The results showed that maximum Cu (II) removal (93.10%) occurred at pH of 9.0, contact time of 120 minutes and initial ion concentration of 10 mg/L while that of Ni (II) was 94.6%, which was achieved at pH of 8.0, contact time of 120 minutes and initial ion concentration of 10 mg/L. The equilibrium data fitted well to the Langmuir Isotherm indicating that the process is a monolayer adsorption. The coefficients of determination, R2, values for the Langmuir Isotherm were 0.9799 and 0.9822 respectively for Cu (II) and Ni (II) ions. The values of the maximum biosorption capacity, Qo, were 10.79 and 6.25 mgg-1 respectively. The kinetic data also revealed that the sorption process could best be described by the pseudo \u2013 second order kinetic model. The R2 values for the pseudo \u2013 second order kinetic plots for Cu (II) and Ni (II) were 0.9988 and 0.9969 respectively. These values were higher than those for the pseudo \u2013 first order plots. The values of the biosorption capacity qe obtained from the pseudo \u2013 second order plots were very close to the experimental values of qe indicating that the biosorption process follows the second order kinetics. This study has therefore shown that calcium alginate beads can be used for the removal of Cu (II) and Ni (II) ions from wastewaters

    Physicochemical Analysis of Surface and Ground Water in Ugbomro and Iteregbi, Delta State, Nigeria

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    Physicochemical analyses of surface and groundwater samples from eleven different locations in Ugbomro and Iteregbi, Delta State, Nigeria were sampled and analyzed for physicochemical parameters according to standard methods for the examination of water and wastewater. The following mean and standard deviation were obtained from the groundwater of the communities: temp (oC) 22.46 \ub1 0.50 and 23.23 \ub1 0.99, pH 6.63 \ub1 0.68 and 6.69 \ub1 0.24, dissolved oxygen (DO) (mg/L) 5.91 \ub1 0.46 and 5.73 \ub1 0.46, chemical oxygen demand (COD) (mg/L) 4.24 \ub1 0.01 and 4.43 \ub1 0.10, biochemical oxygen demand (BOD) (mg/L) 3.51 \ub1 0.38 and 3.84 \ub1 0.21, Turbidity (NTU) 1.22 \ub1 1.07 and 3.56 \ub1 0.77, electrical conductivity (EC) (\u3bcs/cm) 748.9 \ub1 215.79 and 786.67 \ub1 226.77, color (TCU) 1.22 \ub1 2.12 and 6.11 \ub1 2.11, total alkalinity (TA) (mg/L) 6.22 \ub1 7.38 and 14.11 \ub1 11.19, HCO3- (mg/L) 6.22 \ub1 7.38 and 14.11 \ub1 11.19, NO3- (mg/L) 1.13 \ub1 0.62 and 2.89 \ub1 1.25, total solids (TS) (mg/L) 489.09 \ub1 180.17 and 664.95 \ub1 373.37, total suspended solids (TSS) (mg/L) 32.25 \ub1 24.29 and 123.86 \ub1 82.79, total dissolved solids (TDS) (mg/L) 456.78 \ub1 163.73 and 542.20 \ub1 450.66, Cl- (mg/L) 21.20 \ub1 3.20 and 20.10 \ub1 3.89, total hardness (TH) (mg/L) 26.67 \ub1 22.83 and 46.78 \ub1 36.17, Na (mg/L) 1.26 \ub1 0.06 and 1.16 \ub1 0.04, K (mg/L) 0.04 \ub1 0.01 and 0.06 \ub1 0.03, Mg (mg/L) 4.32 \ub1 3.23 and 6.96 \ub1 5.49, Ca (mg/L) 8.68 \ub1 9.35 and 18.12 \ub1 13.71 respectively. The results obtained were subjected to statistical analysis and compared with the standard set by the Standards Organization of Nigeria (SON) and the World Health Organization (WHO) for water samples. Some of the parameters did not meet the standards, hence the need for treatment. The present physio-chemical analyses of surface and groundwater quality of the two neighboring university areas, Ugbomro and Iteregbi, were done to assess the environmental status of the environment before socio-economic impacts

    Habitats of antlions larvae (Neuroptera: Myrmeleontidae) in the Sudano-Guinean and Sudano-Sahelian zones of Cameroon

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    Antlions (Insecta: Neuroptera) are flying insect associated with sunny weather at adult stage. During larval stage, xerophilous insects they are familiar to arid soils with critical temperature, hygrometry and luminosity. These 3 climatic parameters are used to discriminate among larval habitats of antlions in the Soudano Guinean and Soudano Sahelian Savannah of Cameroon. Investigations made during 3 years from 2015 to 2018, consisted in survey of larvae\u2019s funnels. At the level of each active pit-traps, the 3 parameters were recorded during the whole dry season. Analysis of data computerised pointed out that larvae of Cueta bourborni Navas 1935, and those of Cueta sp, are frequent within sites that are warm (40.57\ub10.64\ub0C to 52.14\ub14.08\ub0C); dry (10.91\ub10.82-16.81\ub12.74%rh) and lighted (94380.2 \ub116109.4 lux) habitats. On the other hand, larvae of Myrmeleon quinquemaculatus Hagen 1853 are associated with sites that are: humid (75.46\ub14.50% RH), cloudy (448.232\ub1300. 491 lux) with tendency to moist (22.11\ub10.88\ub0C to 28.10 \ub12.14\ub0C). Presence of C. bourbonni sometimes in the moisty Soudano Guinean zone could only indicate episode of warming

    Evaluation of Different Rainfall-based Drought Indices Detection of Meteorological Drought Events in Imo State, Nigeria

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    Drought Indices are extensively adopted as a drought detection and monitoring tool in all climatic regions. This study assesses and compares the performance of four rainfall based drought indices, Deciles index (DI), Percent of Normal Index (PNI), Standardized Precipitation Index (SPI) and Z-score Index (ZSI) in detection and classification of drought events in Imo state , a humid environment of Nigeria from (1982 to 2016). The result shows that droughts do occur in humid climatic region of Nigeria. The various indices differ in their detection and classification of drought events in the study area. However, they classified 2007 and 2008 as the year with the most severe drought event in the state. There is high correlation (r > 0.70) among the four indices, with ZSI and PNI showing the highest relationship to SPI (r= 0.97). The differences observed among the drought indices in detecting drought events in the study area can be reduced by using multiple drought indices in addition to the use of SPI in drought assessments especially in Nigeria since technological advancement in drought monitoring software\u2019s has made it easier. Also it is worthwhile to research on why drought detection varies with indices

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