Jurnal Pendidikan Kimia
Not a member yet
236 research outputs found
Sort by
Mesoporous Carbon in the Global World
Get PDFThis review provided information about the development of the synthesis aspect, preparation and application of mesoporous carbon in the global world based on research phenomenon on 100 mesoporous carbon papers published by Elsevier, ACS dan Springer during 25 year. Review results showed that researchers began to leave sucrose and switch to non-sucrose as carbon precursor. Researchers used sucrose about 90% in 1995-2000 and in 2010-2015 decrease to become 40%. Otherwise those using non-sucrose in 1995-2000 only 10%, recently increase to 60%. For the method used to synthesis the mesoporous carbon researchers prefer used soft template (about 75 %) before year 2000 and hard template (about 60%) in 2000-2010, but now the method used with soft templates, hard templates and combinations of both are balanced. From year 1995 until 2015 total researchers used sucrose as carbon precursor about 50% and researchers about 40% using hard template method, 35% using soft template method and the others using combination both of them. Structure form of the amorphous carbons are grown, from wormholes, cubic, until hexagonal, and modification to these fours forms. Physical properties such as pore size, surface area, and structural order were developed for better performance year to year. Mesoporous carbon application up to 60% were used in the fuel production and refineries, but the other using on the communication tenhnologies and medical areas. All of the mesoporous carbon in the global world shows that mesoporous carbon is a future material which has a great opportunity to develop especially in Indonesia and other developing countries. Indonesia have various natural resources as a carbon source, so in the future Indonesia are expected as one of the countries of mesoporous carbon supplier
Determination of Immobilization Optimum Conditions of Trichoderma viride’s Xilanase on Acid-Activated Zeolite Matrix
Get PDFXylanase is an enzyme that catalyzes the reaction of xylan hydrolysis into xylose. The free enzyme can be used only once, therefore it needs to be made in the form of immobilization. This study aims to determine the optimum conditions for immobilization of xylanase using an acid-activated zeolite. The xylanase immobilization was performed on variations of shaking time (1-5) hours, variation of xylanase concentration (2 - 4 mg / mL) using 0.1 g zeolite at room temperature and a shaking rate of 100 rpm. The amount of xylanase adsorbed on the zeolite was determined by spectrophotometry using the Biuret reagent and the immobilized xylanase activity formed was determined spectrophotometrically using a DNS reagent The results showed that the optimum condition of xylanase immobilization at zeolite was achieved at 3 hrs shaking time and xylanase concentration 3.5 mg / mL with xylanase adsorbed of 156.5 mg/g zeolite and activity 26.67 units
Characterization of Cacao Fruit Skin for Active Carbon and Green Chemicals
Get PDFThe potential of cacao fruit skin that has not been widely used by the community are encouraged to develop the cacao fruit skinas bio charcoal. One way to reduce the build up of biomass waste is by pyrolysis derived from combustion products that produce liquid smoke, charcoal and some gases (CO2, H2, and CO2). The purpose of this research is to utilize cacao peel to get the liquid smoke of cacao skin and cacao charcoal. The result of this research showed that the skin of cacao fruit produce hemicellulose content of 21.06%, cellulose of 20.15% and lignin of 51.98%. The analysis result of carbon content of cacao skin activated charcoal from Luwu regency is 55.11%. FT-IR analysis of the cacao skin powder from Luwu regency showed that there were depolymerization for cellulose and hemicellulose contentsat the wave number of 1107.14 cm-1 andfound C-H of lignin at the wave number of 1730.15 cm-1. The hydroxyl group (OH) appeared on the wave number of 3441.01 cm-1 and group of C = CH (Aromatic H) on the wave number of781.17 – 659.66 cm-1. Crystallinity degree of cacao fruits skin from Luwu which was obtained from XRD analysis is 12.66%. The wasteutilization of this cacao fruit skin with pyrolysis technology is able to reduce carbon emissions and can be as a supporter of sustainable development program
Study of The Acid-Base Effect on Zeolite Activation and Its Characterization as Adsorbent of Methylene Blue Dye
Get PDFActivation is one of the processes by which are mostly done to improve the quality of natural zeolite. Activation process by zeolite will change the ratio of the Si/Al and can increase the formation of empty cavities so that the capability of zeolite as an adsorbent be optimal. In this research, natural zeolite from the district of Ende, Nusa Tenggara Timur. Activation Ende natural zeolite done chemically using HCl and NaOH solution, with variations concentrate 0,5 M; 1,5 M; and 3,0 M. Next, zeolite which has activated used to adsorb dye methylene blue. Based on the research results, chemically of activation from natural zeolite can increase the adsorption capacity to substance methylene blue. The adsorption capacity in the Ende natural and after activation is 17,289 mg/g and 19,98 mg/g respectively. The Langmuir model most closely matched the isothermal adsorption of equilibrium process
Making Charcoal Briquettes from Corncobs Organic Waste Using Variation of Type and Percentage of Adhesives
Get PDFThis study aimed to (1) make charcoal briquettes from corncobs organic waste; (2) determine the right type of adhesive to make a corncobs charcoal briquette to produce good quality briquettes; (3) determine the appropriate percentage of adhesive to produce corncobs briquettes to produce good quality briquettes; and (4) know the best characteristics of corncobs charcoal briquettes which include moisture content, volatile content, ash content, carbon content and caloric value. The sample used was corncob obtained from a corn farmer in Pasekan Village, Wonogiri regency. This research used experimental method in laboratory with several stages, namely: (1) preparation of materials; (2) carbonization; (3) crushing and sifting of charcoal (4) mixing charcoal with adhesive and water; (5) briquetting; (6) briquette drying; And (7) analysis of briquette quality. This adhesive types used in this research were tapioca flour and wheat flour and the percentage of adhesive material were 5%, 10% and 15% from total weight of charcoal powder. The result of the research were: (1) charcoal briquettes as alternative energy source can be made from biomass waste (corncobs organic waste); (2) charcoal briquettes from organic corncobs wastes using tapioca flour adhesives have better quality than using wheat flour adhesives; (3) the both charcoal briquettes using 5% of tapioca flour adhesive and 5% wheat flour adhesives have better quality than 10% and 15% in terms of moisture content, volatile content, ash content, carbon content and calorific value; and (4) the best characteristics obtained are for the charcoal briquettes using 5% of tapioca flour adhesive, which have water content of 3,665%; volatile matter amounting of 11.005%; ash content of 4.825%; fixed carbon content of 80.515%; and high heat value of 5661,071%
Synthesis and Characterization of Bioplastic from Chitosan-Ganyong Starch (Canna edulis)
Get PDFThe purpose of this study was to produced bioplastic from chitosan-ganyong starch and compare its quality to commercial biodegradable plastic. This research was carried out by experimental method in laboratory. Making bioplastic film was done by dissolving, blending, printing, drying, and neutralizing process. Characterization of bioplastic film was performed by tensile strength test,% elongation, thickness, swelling, solubility, biodegradability and functional group analysis with FTIR. The produced bioplastic characterizations were compared to commercial biodegradable plastics. The results concluded that the qualities of bioplastic chitosan-ganyong starch are higher than commercial biodegradable plastics on tensile strength parameter (53,9644 Mpa : 18,4109 MPa),% elongation (1,8066 % : 3,7025%), and degradation ability (5 days : 30 days); but lower in thickness parameters (0.0350 mm: 0.0140 mm), % swelling (0.275%: 0.010%), and solubility (0.10%: 0.05%).