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Anomalous Dependence of the Reactivity on the Presence of Steps: Dissociation of D-2 on Cu(211)
No full textStepped metal surfaces are usually assumed to exhibit an increased catalytic activity for bond cleavage of small molecules over their flat single-crystal counterparts. We present experimental and theoretical data on the dissociative adsorption of molecular hydrogen on copper that contradicts this notion. We observe hydrogen molecules to be more reactive on the flat Cu(111) than on the stepped Cu(211) surface. We suggest that this exceptional behavior is due to a geometric effect, that is, that bond cleavage on the flat surface does not occur preferentially over a top site
Control-oriented modeling of the plasma particle density in tokamaks and application to real-time density profile reconstruction
No full textA model-based approach to real-time reconstruction of the particle density profile in tokamak plasmas is presented, based on a dynamic state estimator. Traditionally, the density profile is reconstructed in real-time by solving an ill-conditioned inversion problem using a measurement at a single point in time. This approach is sensitive to diagnostics errors and failure. The inclusion of a dynamic model in a real-time estimation algorithm allows for reliable reconstruction despite diagnostic errors. Predictive simulations show that the model can reproduce the density evolution of discharges on TCV and ASDEX-Upgrade after tuning of a few parameters. Offline reconstructions using experimental data from TCV show accurate estimation of the density profile and show examples of fault detection of interferometry signals.</p
Density control in ITER: an iterative learning control and robust control approach
No full textPlasma density control for next generation tokamaks, such as ITER, is challenging because of multiple reasons. The response of the usual gas valve actuators in future, larger fusion devices, might be too slow for feedback control. Both pellet fuelling and the use of feedforward-based control may help to solve this problem. Also, tight density limits arise during ramp-up, due to operational limits related to divertor detachment and radiative collapses. As the number of shots available for controller tuning will be limited in ITER, in this paper, iterative learning control (ILC) is proposed to determine optimal feedforward actuator inputs based on tracking errors, obtained in previous shots. This control method can take the actuator and density limits into account and can deal with large actuator delays. However, a purely feedforward-based density control may not be sufficient due to the presence of disturbances and shot-to-shot differences. Therefore, robust control synthesis is used to construct a robustly stabilizing feedback controller. In simulations, it is shown that this combined controller strategy is able to achieve good tracking performance in the presence of shot-to-shot differences, tight constraints, and model mismatches
Single-crystal and polycrystalline diamond erosion studies in Pilot-PSI
Get PDFDiamond is a promising candidate for enhancing the negative-ion surface production in the ion sources for neutral injection in fusion reactors; hence evaluation of its reactivity towards hydrogen plasma is of high importance. Single crystal and polycrystalline diamond samples were exposed in Pilot-PSI with the D+ flux of (4‒7) 1024 m−2s−1 and the impact energy of 7–9 eV per deuteron at different surface temperatures; under such conditions physical sputtering is negligible, however chemical sputtering is important. Net chemical sputtering yield Y = 9.7 10−3 at/ion at 800 °C was precisely measured ex-situ using a protective platinum mask (5 × 10 × 2 μm) deposited beforehand on a single crystal followed by the post-mortem analysis using Transmission Electron Microscopy (TEM). The structural properties of the exposed diamond surface were analyzed by Raman spectroscopy and X-ray Photoelectron Spectroscopy (XPS). Gross chemical sputtering yields were determined in-situ by means of optical emission spectroscopy of the molecular CH A-X band for several surface temperatures. A bell-shaped dependence of the erosion yield versus temperature between 400 °C and 1200 °C was observed, with a maximum yield of ∼1.5 10−2 at/ion attained at 900 °C. The yields obtained for diamond are relatively high (0.5–1.5) 10−2 at/ion, comparable with those of graphite. XPS analysis shows amorphization of diamond surface within 1 nm depth, in a good agreement with molecular dynamics (MD) simulation. MD was also applied to study the hydrogen impact energy threshold for erosion of [100] diamond surface at different temperatures.</p
TORBEAM 2.0, a paraxial beam tracing code for electron-cyclotron beams in fusion plasmas for extended physics applications
Get PDFThe paraxial WKB code TORBEAM (Poli, 2001) is widely used for the description of electron-cyclotron waves in fusion plasmas, retaining diffraction effects through the solution of a set of ordinary differential equations. With respect to its original form, the code has undergone significant transformations and extensions, in terms of both the physical model and the spectrum of applications. The code has been rewritten in Fortran 90 and transformed into a library, which can be called from within different (not necessarily Fortran-based) workflows. The models for both absorption and current drive have been extended, including e.g. fully-relativistic calculation of the absorption coefficient, momentum conservation in electron–electron collisions and the contribution of more than one harmonic to current drive. The code can be run also for reflectometry applications, with relativistic corrections for the electron mass. Formulas that provide the coupling between the reflected beam and the receiver have been developed. Accelerated versions of the code are available, with the reduced physics goal of inferring the location of maximum absorption (including or not the total driven current) for a given setting of the launcher mirrors. Optionally, plasma volumes within given flux surfaces and corresponding values of minimum and maximum magnetic field can be provided externally to speed up the calculation of full driven-current profiles. These can be employed in real-time control algorithms or for fast data analysis.</p
A task analysis approach to quantify bottlenecks in task completion time of telemanipulated maintenance
Get PDFTelemanipulation techniques allow for human-in-the-loop assembly and maintenance tasks in otherwise inaccessible environments. Although it comes with limitations in achieved performance – required strict operator selection and extensive training are widely encountered – there is very little quantitative insight in the exact problems operators encounter during task execution. This paper provides a novel hierarchical task analysis approach to identify the most time-consuming subtask elements and to quantify the potential room for performance improvement during telemanipulated maintenance tasks. The approach is illustrated with a human factors case study in which 5 subjects performed six generic maintenance tasks, using a six degree of freedom master device connected to a simulated task environment. Overall it can be concluded that the proposed three phased task analysis is a useful tool to guide improvements since it is able to relate high-level problems (e.g. large variability) to behaviour on lower task-levels. For the case study, the largest potential for improvement was found for specific subtasks characterized by complex contact transitions and precise control of tool orientation, and in the reduction of variation of the task execution.</p
Thermal behaviour of dicarboxylic ester bithiophene polymers exhibiting a high open-circuit voltage
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Effect of optical damage resistant dopants on the dielectric properties of LiNbO3: Insight from broadband impedance spectroscopy and Raman scattering
No full textOptical damage limits the application range of congruent LiNbO3. This problem is commonly overcome by adding optical-damage-resistant cations. Here, the influence of doping with optical-damage-resistant Mg and Zn on the ionic and piezoelectric contributions to the dielectric permittivity is investigated in a broad frequency range (1 mHz–2 THz). It is shown that the two dopants have radically different influences on the variation of ionic permittivity with doping, in spite of their similarities with respect to the crystallographic structure. Raman spectroscopy reveals that the difference in permittivity can be traced to the effect of Mg and Zn doping on the susceptibility of the phonon modes. Both observations point to differences in the defect incorporation mechanisms
Mechanisms of elementary hydrogen ion-surface interactions during multilayer graphene etching at high surface temperature as a function of flux
Get PDFIn order to optimize the plasma-synthesis and modification process of carbon nanomaterials for applications such as nanoelectronics and energy storage, a deeper understanding of fundamental hydrogen-graphite/graphene interactions is required. Atomistic simulations by Molecular Dynamics have proven to be indispensable to illuminate these phenomena. However, severe time-scale limitations restrict them to very fast processes such as reflection, while slow thermal processes such as surface diffusion and molecular desorption are commonly inaccessible. In this work, we could however reach these thermal processes for the first time at time-scales and surface temperatures (1000 K) similar to high-flux plasma exposure experiments during the simulation of multilayer graphene etching by 5 eV H ions. This was achieved by applying the Collective Variable-Driven Hyperdynamics biasing technique, which extended the inter-impact time over a range of six orders of magnitude, down to a more realistic ion-flux of 1023 m−2s−1. The results show that this not only causes a strong shift from predominant ion-to thermally-induced interactions, but also significantly affects the hydrogen uptake and surface evolution. This study thus elucidates H ion-graphite/graphene interaction mechanisms and stresses the importance of including long time-scales in atomistic simulations at high surface temperatures to understand the dynamics of the ion-surface system.</p