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Operational characteristics of the superconducting high flux plasma generator Magnum-PSI
Get PDFThe interaction of intense plasma impacting on the wall of a fusion reactor is an area of high and increasing importance in the development of electricity production from nuclear fusion. In the Magnum-PSI linear device, an axial magnetic field confines a high density, low temperature plasma produced by a wall stabilized DC cascaded arc into an intense magnetized plasma beam directed onto a target. The experiment has shown its capability to reach conditions that enable fundamental studies of plasma-surface interactions in the regime relevant for fusion reactors such as ITER: 1023–1025 m−2s−1 hydrogen plasma flux densities at 1–5 eV for tens of seconds by using conventional electromagnets. Recently the machine was upgraded with a superconducting magnet, enabling steady-state magnetic fields up to 2.5 T, expanding the operational space to high fluence capabilities for the first time. Also the diagnostic suite has been expanded by a new 4-channel resistive bolometer array and ion beam analysis techniques for surface analysis after plasma exposure of the target. A novel collective Thomson scattering system has been developed and will be implemented on Magnum-PSI. In this contribution, the current status, capabilities and performance of Magnum-PSI are presented.</p
Physical and Chemical Defects in WO3 Thin Films and Their Impact on Photoelectrochemical Water Splitting
Get PDFWe evaluate the impact of defects in WO3 thin films on the photoelectrochemical (PEC) properties during water splitting. We study physical defects, such as microsized holes or cracks, by two different deposition techniques: sputtering and atomic layer deposition (ALD). Chemical defects, such as oxygen vacancies, are tailored by different annealing atmospheres, i.e., air, N2, and O2. The results show that the physical defects inside the film increase the resistance for the charge transfer and also result in a higher recombination rate which inhibits the photocurrent generation. Chemical defects yield an increased adsorption of OH groups on the film surface and enhance the PEC efficiency. An excess amount of chemical defects can also inhibit the electron transfer, thus decreasing the photocurrent generation. In this study, the highest performance was obtained for WO3 films deposited by ALD and annealed in air, which have the fewest physical defects and an appropriate amount of oxygen vacancies.</p
Atmospheric-pressure diffuse dielectric barrier discharges in Ar-O2 gas mixture using 200 kHz/13.56 MHz dual frequency excitation
No full textAbstract Atmospheric-pressure diffuse dielectric barrier discharges (DBDs) were obtained in Ar/O2 gas mixture using dual-frequency (DF) excitation at 200 kHz low frequency (LF) and 13.56 MHz radio frequency (RF). The excitation dynamics and the plasma generation mechanism were studied by means of electrical characterization and phase resolved optical emission spectroscopy (PROES). The DF excitation results in a time-varying electric field which is determined by the total LF and RF gas voltage and the spatial ion distribution which only responds to the LF component. By tuning the amplitude ratio of the superimposed LF and RF signals, the effect of each frequency component on the DF discharge mechanism was analysed. The LF excitation results in a transient plasma with the formation of an electrode sheath and therefore a pronounced excitation near the substrate. The RF oscillation allows the electron trapping in the gas gap and helps to improve the plasma uniformity by contributing to the pre-ionization and by controlling the discharge development. The possibility of temporally modifying the electric field and thus the plasma generation mechanism in the DF discharge exhibits potential applications in plasma-assisted surface processing and plasma-assisted gas phase chemical conversion
Porous titania photoelectrodes built on a Ti-web of microfibers for polymeric electrolyte membrane photoelectrochemical (PEM-PEC) cell applications
Get PDFConventional photoelectrochemical (PEC) cells are based on planar photoelectrodes supported on glass substrates and liquid electrolytes. Only few recent studies have examined an alternative PEC design which is robust and scalable, where the key elements are polymeric electrolyte membranes and porous photoelectrodes. This work aims to give further insights on the operation of such cells utilizing titania photoelectrodes and proton and hydroxide ion conducting membranes. Two families of photoelectrodes were developed on Ti porous substrate; TiO2 nanotubes grown by anodization and subsequent oxygen annealing, and TiO2 layers developed under oxygen annealing. Initial screening of the photoanodes for water splitting and (poly)alcohol photo-oxidation took place in conventional PEC cells. We found that the annealing temperature affects the performance of the photoanodes, evidenced by a monotonic increase in the activity for water photo-oxidation with increasing annealing temperature. Moreover it was demonstrated that anatase phase is predominantly active for the (poly)alcohol electro-oxidation, while there is a synergy between rutile and anatase which is beneficial for water splitting. In addition, the most promising photoanodes for water splitting were evaluated in our polymeric electrolyte membrane photoelectrochemical (PEM-PEC) cell during gas phase operation. It was found that PEM-PEC operation is more efficient when OH- conducting membranes are used, while the nature of the carrier gas does not significantly influence the activity. Overall, PEM-PEC operation is more promising than conventional PEC in both acidic and alkaline media, since comparable (or even at some cases higher) photocurrents were obtained while liquid pumping systems are not required for PEM-PEC devices.</p
Scenario development for the observation of alpha-driven instabilities in JET DT plasmas
No full textIn DT plasmas, toroidal Alfvén eigenmodes (TAEs) can be made unstable by the alpha particles resulting from fusion reactions, and may induce a significant redistribution of fast ions. Recent experiments have been conducted in JET deuterium plasmas in order to prepare scenarios aimed at observing alpha-driven TAEs in a future JET DT campaign. Discharges at low density, large core temperatures associated with the presence of internal transport barriers and characterised by good energetic ion confinement have been performed. ICRH has been used in the hydrogen minority heating regime to probe the TAE stability. The consequent presence of MeV ions has resulted in the observation of TAEs in many instances. The impact of several key parameters on TAE stability could therefore be studied experimentally. Modeling taking into account NBI and ICRH fast ions shows good agreement with the measured neutron rates, and has allowed predictions for DT plasmas to be performed
Soledge2D‐Eirene simulations of the Pilot‐PSI linear plasma device compared to experimental data
Get PDFPredictions for the operation of tokamak divertors are reliant on edge plasma simulations typically utilizing a fluid plasma code in combination with a Monte Carlo code for neutral species. Pilot‐PSI is a linear device operating with a cascaded arc plasma source that produces plasmas comparable to those expected in the ITER divertor (Te ∼ 1 eV, ne ∼ 1021 m−3). In this study, plasma discharges in Pilot‐PSI are modelled using the Soledge2D fluid plasma code coupled to the Eirene neutral Monte Carlo code. The plasma is generated using an external source of plasma density and power. These input parameters are tuned in order to match Thomson scattering (TS) measurements close to the cascaded arc source nozzle. The sensitivity of the simulations to different atomic physics models is explored. It is found that elastic collisions between ions and hydrogen molecules have a strong influence on calculated profiles. Without their inclusion, supersonic flow regimes are obtained with M ∼ 2 close to the target plate. Simulation results are compared with experimental findings using TS close to the target and, in the case of Pilot‐PSI, a Langmuir probe embedded in the target. Comparison between experimental trends observed in a background pressure scan and the simulations show that the inclusion of the elastic collision is mandatory for the trends to be reproduced.</p
Separation of transport in slow and fast time-scales using modulated heat pulse experiments (hysteresis in flux explained)
No full textOld and recent experiments show that there is a direct response to the heating power of transport observed in modulated ECH experiments both in tokamaks and stellarators. This is most apparent for modulated experiments in the Large Helical Device (LHD) and in Wendelstein 7 advanced stellarator (W7-AS). In this paper we show that: 1) This power dependence can be reproduced by linear models and as such hysteresis (in flux) has no relationship to hysteresis as defined in the literature; 2) Observations of "hysteresis" (in flux) and a direct response to power can be perfectly reproduced by introducing an error in the estimated deposition profile as long as the errors redistribute the heat over a large radius; 3) Non-local models depending directly on the heating power can also explain the experimentally observed Lissajous curves (hysteresis); 4) How non-locality and deposition errors can be recognized in experiments and how they affect estimates of transport coefficients; 5) That non-linear-non-local transport models offer a path in discerning deposition errors from non-local fast transport components otherwise experimentally indistinguishable. To show all this, transport needs to be analyzed by separating the transport in a slow (diffusive) time-scale and a fast (heating/non-local) time-scale, which can only be done in the presence of perturbations. (DOI dataset, OA: 10.4121/uuid:5fcf4247-da0e-4119-adcd-fc90b85b7f03)</p
Vibrational Kinetics in Plasma as a Functional Problem: a Flux-Matching Approach
Get PDFA new approach to calculate the vibrational distribution function of molecules in a medium providing energy for vibrational excitation is proposed and demonstrated. The approach is an improvement of solution methods based on the drift-diffusion Fokker-Planck (FP) equation for a double differentiable function representing the vibrational populations on a continuum internal energy scale. A self-consistent numerical solution avoids approximations used in previous analytical solutions. The dissociation flux, a key parameter in the FP equation, is fixed using the kinetics of molecular dissociation from near-continuum levels, so that the vibrational kinetics becomes a functional problem. The approach is demonstrated for the kinetics of asymmetric stretching of CO2, showing that it represents an alternative, potentially much more efficient in computational terms, to the presently usual state-to-state approach which is based on the kinetics of the populations of individual levels, and gives complementary insight into the dissociation process.</p
Time-resolved terahertz time-domain near-field microscopy
No full textWe demonstrate a novel method for measuring terahertz (THz) photoconductivity of semiconductors on length scales smaller than the diffraction limit at THz frequencies. This method is based on a near-field microscope that measures the transmission of a THz pulse through the semiconductor following photoexcitation by an ultrafast laser pulse. Combining back-excitation of the sample using a Dove prism, and a dual lock-in detection scheme, our microscope design offers a flexible platform for near-field time-resolved THz time-domain spectroscopy, using fluences available to typical laser oscillators. Experimental results on a thin film of gallium arsenide grown by metal organic chemical vapor deposition are presented as a proof-of-concept, demonstrating the ability to map the complex conductivity as well as sub-ps dynamics of photoexcited carriers with a resolution of labda / 10 at 0.5 THz