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Overview of physics studies on ASDEX Upgrade
No full textThe ASDEX Upgrade (AUG) programme, jointly run with the EUROfusion MST1 task force, continues to significantly enhance the physics base of ITER and DEMO. Here, the full tungsten wall is a key asset for extrapolating to future devices. The high overall heating power, flexible heating mix and comprehensive diagnostic set allows studies ranging from mimicking the scrape-off-layer and divertor conditions of ITER and DEMO at high density to fully non-inductive operation (q 95 = 5.5, ) at low density. Higher installed electron cyclotron resonance heating power 6 MW, new diagnostics and improved analysis techniques have further enhanced the capabilities of AUG. Stable high-density H-modes with MW m−1 with fully detached strike-points have been demonstrated. The ballooning instability close to the separatrix has been identified as a potential cause leading to the H-mode density limit and is also found to play an important role for the access to small edge-localized modes (ELMs). Density limit disruptions have been successfully avoided using a path-oriented approach to disruption handling and progress has been made in understanding the dissipation and avoidance of runaway electron beams. ELM suppression with resonant magnetic perturbations is now routinely achieved reaching transiently . This gives new insight into the field penetration physics, in particular with respect to plasma flows. Modelling agrees well with plasma response measurements and a helically localised ballooning structure observed prior to the ELM is evidence for the changed edge stability due to the magnetic perturbations. The impact of 3D perturbations on heat load patterns and fast-ion losses have been further elaborated. Progress has also been made in understanding the ELM cycle itself. Here, new fast measurements of and E r allow for inter ELM transport analysis confirming that E r is dominated by the diamagnetic term even for fast timescales. New analysis techniques allow detailed comparison of the ELM crash and are in good agreement with nonlinear MHD modelling. The observation of accelerated ions during the ELM crash can be seen as evidence for the reconnection during the ELM. As type-I ELMs (even mitigated) are likely not a viable operational regime in DEMO studies of ‘natural’ no ELM regimes have been extended. Stable I-modes up to have been characterised using -feedback. Core physics has been advanced by more detailed characterisation of the turbulence with new measurements such as the eddy tilt angle—measured for the first time—or the cross-phase angle of and fluctuations. These new data put strong constraints on gyro-kinetic turbulence modelling. In addition, carefully executed studies in different main species (H, D and He) and with different heating mixes highlight the importance of the collisional energy exchange for interpreting energy confinement. A new regime with a hollow profile now gives access to regimes mimicking aspects of burning plasma conditions and lead to nonlinear interactions of energetic particle modes despite the sub-Alfvénic beam energy. This will help to validate the fast-ion codes for predicting ITER and DEMO
Diagnostics for plasma control - From ITER to DEMO
No full textThe plasma diagnostic and control (D&C) system for a future tokamak demonstration fusion reactor (DEMO) will have to provide reliable operation near technical and physics limits, while its front-end components will be subject to strong adverse effects within the nuclear and high temperature plasma environment. The ongoing developments for the ITER D&C system represent an important starting point for progressing towards DEMO. Requirements for detailed exploration of physics are however pushing the ITER diagnostic design towards using sophisticated methods and aiming for large spatial coverage and high signal intensities, so that many front-end components have to be mounted in forward positions. In many cases this results in a rapid aging of diagnostic components, so that additional measures like protection shutters, plasma based mirror cleaning or modular approaches for frequent maintenance and exchange are being developed. Under the even stronger fluences of plasma particles, neutron/gamma and radiation loads on DEMO, durable and reliable signals for plasma control can only be obtained by selecting diagnostic methods with regard to their robustness, and retracting vulnerable front-end components into protected locations. Based on this approach, an initial DEMO D&C concept is presented, which covers all major control issues by signals to be derived from at least two different diagnostic methods (risk mitigation)
Characterization of the CO2 microwave plasma based on the phenomenon of skin-depth-limited contraction
Get PDFThe subatmospheric CO2 microwave plasma is known to contract to a narrow filament with rising pressure as result of a mode transition. This changing state of contraction is investigated in relation to its dielectric properties, in order to directly relate the discharge parameters to the discharge radius. The electron density and gas temperature are measured, respectively, by 168 GHz microwave interferometry and Doppler broadening of the 777 nm oxygen emission lines. The plasma is operated in steady state with 1400 W at 2.45 GHz, between 100 mbar and 400 mbar. Electron density values in the central region range from 1018 to 1020 m−3 between the discharge modes, while the gas temperature increases from 3000 K to 6500 K, in good agreement with previously reported values. Based on the dielectric properties of the discharge in relation to the plasma radius, it is found that the discharge column constitutes a radius of a single skin depth. Implications of these insights on the conditions of previously reported CO2 dissociation experiments are discussed.</p
Inline ECE measurements for NTM control on ASDEX Upgrade
Get PDFThe successful use of a tokamak for generating fusion power requires an active control of magnetic instabilities, such as neoclassical tearing modes (NTMs). Commonly, the NTM location is determined using electron cyclotron emission (ECE) and this is used to apply electron cyclotron heating (ECH) on the NTM location. In this paper, an inline ECE set-up at ASDEX Upgrade is presented in which ECE is measured and ECH is applied via the same path. First results are presented and a means to interpret the measurement data is given. Amplitude and phase with respect to a reference magnetic signal are calculated. Based on the amplitude and phase, the time of mode crossing is determined and shown to compare well with real-time estimates of the mode crossing time. The ECH launcher and [formula]; flux surface geometries at ASDEX Upgrade, which are optimized for current drive by a beam path that is tangential to the flux surface near deposition, make it difficult to identify the mode crossing without inline ECE launcher movement. Therefore, NTM control based on inline ECE requires launcher movement to determine and maintain a reliable estimate of the NTM location.</p
Atomic layer deposition of cobalt phosphate thin films for the oxygen evolution reaction
No full textElectrodeposited cobalt phosphate has been reported as a valid alternative to noble metals as an electrocatalyst for the Oxygen Evolution Reaction (OER). In parallel, Atomic Layer Deposition (ALD) is increasingly being used in (photo)electrocatalytic applications. In this contribution we report on the electrocatalytic activity towards OER of ALD-prepared cobalt phosphate thin films. The selected ALD approach enables tuning of the Co-to-P atomic ratio, which is found to significantly affect the activity of the prepared electrocatalyst. Specifically, concurrently with a Co-to-P ratio increase from 1.6 to 1.9, the current density for OER increases from 1.77 mA/cm2 at 1.8 V vs. RHE (Reversible Hydrogen Electrode) to 2.89 mA/cm2 at 1.8 V vs. RHE. Moreover the sample with a Co-to-P ratio of 1.9 has superior performance when compared to electrodeposited cobalt phosphate thin films reported in the literature.</p
Why does NiOOH cocatalyst increase the oxygen evolution activity of a-Fe2O3?
Get PDFNickel oxyhydroxide (NiOOH) is known to increase the oxygen evolution reaction (OER) performance of hematite (Fe2O3) photoanodes. In recent experimental studies, it has been reported that the increased OER activity is related to the activation of the hematite (α-Fe2O3) surface by NiOOH rather than the activity of NiOOH itself. In this study, we investigate the reason behind the higher activity and the low overpotentials for NiOOH-Fe2O3 photoanodes using first principles calculations. To study the activity of possible catalytic sites, different geometries with NiOOH as a cluster and as a strip geometry on hematite (110) surfaces are studied. Density functional theory + U calculations are carried out to determine the OER activity at different sites of these structures. The geometry with a continuous strip of NiOOH on hematite is stable and is able to explain the activity. We found that the Ni atoms at the edge sites of the NiOOH cocatalyst are catalytically more active than Ni atoms on the basal plane of the cocatalyst; the calculated overpotentials are as low as 0.39 V.</p
Magnetohydrodynamics of Laboratory and Astrophysical Plasmas
No full textWith ninety per cent of visible matter in the universe existing in the plasma state, an understanding of magnetohydrodynamics is essential for anyone looking to understand solar and astrophysical processes, from stars to accretion discs and galaxies; as well as laboratory applications focused on harnessing controlled fusion energy. This introduction to magnetohydrodynamics brings together the theory of plasma behavior with advanced topics including the applications of plasma physics to thermonuclear fusion and plasma- astrophysics. Topics covered include streaming and toroidal plasmas, nonlinear dynamics, modern computational techniques, incompressible plasma turbulence and extreme transonic and relativistic plasma flows. The numerical techniques needed to apply magnetohydrodynamics are explained, allowing the reader to move from theory to application and exploit the latest algorithmic advances. Bringing together two previous volumes: Principles of Magnetohydrodynamics and Advanced Magnetohydrodynamics, and completely updated with new examples, insights and applications, this volume constitutes a comprehensive reference for students and researchers interested in plasma physics, astrophysics and thermonuclear fusion.
- All analysis is explicitly worked out in the text, allowing students to derive results themselves
- Modern insights from astrophysical research and laboratory fusion are presented together with the theory, allowing the reader to appreciate how magnetohydrodynamics cuts across disciplines
- Provides cross-fertilisation of knowledge between scientific disciplines, including astrophysics, solar physics, laboratory plasma physics and computational fluid dynamic
Fokker-Planck equation for chemical reactions in plasmas
No full textIn the past few years, a new approach has been experimented for the calculation of the populations of vibrational levels of molecules involved in chemical reactions in ionized gases. The approach that can be defined as neo-diffusive is based on the use of numerical techniques to solve a Fokker–Planck equation in the space of internal energy. The transport coefficients are calculated from the rate coefficients of the reactions between molecules in different vibrational states. It represents a conceptually different alternative to the much used state-to-state (STS) approach, based on the solution of the Master equation. The neo-diffusive approach differs from a similar Fokker–Planck equation-based approach used in the 70s and the 80s of the past century, since exact numerical solutions are used. In this work, the state of the art and perspectives of this new approach are analyzed. Is it pointed out that, while the neo-diffusive method allows us to calculate populations of vibrational levels and reaction rates with much less computational effort than methods based on the Master equation, greatly important is that this method provides a powerful basis for intuition, allowing to highlight effects otherwise obscured by the complex network nature of the STS approach.</p
The Importance of Charge Redistribution during Electrochemical Reactions: A Density Functional Theory Study of Silver Orthophosphate (Ag3PO4)
Get PDFThe structural sensitivity of silver orthophosphate (Ag 3 PO 4 ) for photo-electrochemical water oxidation on (100), (110) and (111) surfaces has recently been reported by experimental studies (D. J. Martin et al., Energy Environ. Sci., 2013, 6, 3380-3386). The (111) surface showed the highest performance with an oxygen evolution rate of 10 times higher than the other surfaces. The high performance of the (111) surface was attributed to high hole mobility, high surface energy and, in a recent theoretical study (Z. Ma et al., RSC Adv., 2017, 7, 23994-24003), to a lower OH adsorption energy and the band structure. The investigations are based on a few structures and a full atomistic picture of the Ag 3 PO 4 under electrochemical reactions is still missing. Therefore, we report here a systematic study of the oxygen evolution reaction (OER) of Ag 3 PO 4 (100), (110), and (111) surfaces by density functional theory (DFT) calculations. Through a detailed investigation of the reaction energies and the overpotentials of OER on all possible surface orientations with all possible terminations and different involvement of Ag adsorption sites, we can confirm that (111) surfaces are highly active. However, surface orientation was not found to exclusively determine the electrochemical activity; neither did the number of Ag atoms involved in the adsorption of the intermediate species nor the type of surface termination or the different potential determining reaction steps. By using Bader charge analysis and investigation of the charge redistribution during OER, we found that the highest activity, i.e. lowest overpotential, is related to the charge redistribution of two OER steps, namely the O ad and the HOO ad formation. If the charge redistribution between these steps is small, then the overpotential is small and, hence, the activity is high. Charge redistributions are usually small for the (111) surface and therefore the (111) surface is usually the most active one. The concept of charge redistribution being decisive for the high activity of Ag 3 PO 4 may open a new design strategy for materials with highly efficient electrochemical surfaces.</p