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Recent trends in renewable energy driven chemistry for energy conversionand storage: plasma chemistry as the special case
Get PDFPlasma Assisted Catalytic Conversion of CO2 and H2O Over Ni/Al2O3 in a DBD Reactor
No full textWe present an innovative approach for reacting carbon dioxide and water to give syngas by combining heterogeneous catalysis and non-thermal plasma techniques. This approach utilizes an abundant water and nickel catalyst, and mitigates the thermodynamic penalty by using a Dielectric Barrier Discharge (DBD) plasma reactor. Argon dilution was used in the experiment to reduce the exothermic recombination of hydrogen and oxygen, which is considered as the major hurdle for H2O conversion. As a result, the syngas ratio was dramatically improved from 0.07 to 0.86. In addition, the conversions of CO2 and H2O were improved by packing Ni/γ–Al2O3 catalysts into the DBD reactor. The yields of H2 and CO were up to 13.8% and 5.6% respectively. The conditions for plasma catalysis and the catalyst characterization are presented and discussed
White paper on the future of plasma science and technology in plastics and textiles
No full textThis white paper considers the future of plasma science and technology related to the manufacturing and modifications of plastics and textiles, summarizing existing efforts and the current state-of-art for major topics related to plasma processing techniques. It draws on the frontier of plasma technologies in order to see beyond and identify the grand challenges which we face in the following 5-10 years. To progress and move the frontier forward, the paper highlights the major enabling technologies and topics related to the design of surfaces, coatings and materials with non-equilibrium plasmas. The aim is to progress the field of plastics and textile production using advanced plasma processing as the key enabling technology which is environmentally friendly, cost-efficient, and offers high-speed processing.</p
Tin, the enabler - Hydrogen diffusion into ruthenium
No full textHydrogen interaction with ruthenium is of particular importance for the ruthenium-capped multilayer reflectors used in extreme ultraviolet (EUV) lithography. Hydrogen causes blistering, which leads to a loss of reflectivity. This problem is aggravated by tin. This study aims to uncover the mechanism via which tin affects the hydrogen uptake, with a view to mitigation. We report here the results of a study of hydrogen interaction with the ruthenium surface in the presence of tin using Density Functional Theory and charge density analyses. Our calculations show a significant drop in the energy barrier to hydrogen penetration when a tin atom or a tin hydride molecule (SnHx) is adsorbed on the ruthenium surface; the barrier has been found to drop in all tested cases with tin, from 1.06 eV to as low as 0.28 eV in the case of stannane (SnH4). Analyses show that, due to charge transfer from the less electronegative tin to hydrogen and ruthenium, charge accumulates around the diffusing hydrogen atom and near the ruthenium surface atoms. The reduced atomic volume of hydrogen, together with the effect of electron–electron repulsion from the ruthenium surface charge, facilitates subsurface penetration. Understanding the nature of tin’s influence on hydrogen penetration will guide efforts to mitigate blistering damage of EUV optics. It also holds great interest for applications where hydrogen penetration is desirable, such as hydrogen storage
First principles and integrated modelling achievements: towards trustful fusion power predictions for JET and ITER
No full textPredictability of burning plasmas is a key issue for designing and building credible future fusion devices. In this context, an important effort of physics understanding and guidance is being carried out in parallel to the on-going JET experimental campaigns in H, D and T by performing analyses and modelling towards an improvement of the understanding of DT physics for the optimization of the JET-DT neutron yield and fusion born alpha particle physics. Extrapolations to JET-DT from recent experiments using the maximum power available have been performed including some of the most sophisticated codes and a broad selection of models. There is a general agreement that 11-15MW of fusion power can be expected in DT for the hybrid and baseline scenarios. On the other hand, in high beta, torque and fast ion fraction conditions, isotope effects could be favourable leading to higher fusion yield. It is shown that alpha particles related physics, such as TAE destabilization or fusion power electron heating, could be studied in ITER relevant JET-DT plasmas.</p
Co-electrolysis of H2O and CO2 on exsolved Ni nanoparticles for efficient syngas generation at controllable H2/CO ratios
Get PDFSyngas (CO+H2) is a key-intermediate for the production of liquid fuels via the Fischer-Tropsch process. An emerging technology for generating syngas is the co-electrolysis of H2O/CO2 in solid oxide cells powered by renewable electricity. An application of this technology, however, is still challenging because the Ni-based cermet fuel electrodes are susceptible to degradation under redox and coking conditions, requiring protective hydrogen atmosphere to maintain stable operation. Perovskite oxides are the most promising alternatives due to their redox stability, extensive range of functionalities and the exsolution concept. The latter allows perovskites to be decorated with uniformly dispersed Ni nanoparticles with unique functionalities that can dramatically enhance the performance. Herein, we demonstrate the advantage of employing a nanoparticle-decorated La0.43Ca0.37Ni0.06Ti0.94O3 (LCT-Ni) perovskite to efficiently generate syngas at adjustable H2/CO ratios and simultaneously avoid the need of a reducing agent, hence decreasing the total cost and complexity of the process.</p
Demonstration of hydrogen production in a hybrid lignite-assisted solid oxide electrolysis cell
No full textSOLPS-ITER simulations of the TCV divertor upgrade
No full textThe effect of the upcoming TCV divertor upgrade on the distribution of neutrals and the onset of detachment is studied using 2D transport code simulations. The divertor upgrade is centered around the installation of a gas baffle to form a divertor chamber of variable closure. SOLPS-ITER simulations predict that the baffle geometry selected to be installed in TCV in 2019 increases the divertor neutral density by a factor ~5 and the neutral compression by one order of magnitude in typical TCV single null, Ohmic heated scenarios (330 kW). The compression increases further with the addition of auxiliary heating systems (1.2 MW). Simulations show that volumetric power losses in the divertor increase giving access to deeper detachment for given upstream densities and heating power. Predictions for observations by various TCV diagnostics, including baratrons, divertor spectrometer and visible camera systems, are presented to guide the experimental verification of the efficiency of the divertor baffles.</p