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ELM-induced cold pulse propagation in ASDEX Upgrade
No full textIn ASDEX Upgrade, the propagation of cold pulses induced by type-I edge localized modes (ELMs) is studied using electron cyclotron emission measurements, in a dataset of plasmas with moderate triangularity. It is found that the edge safety factor or the plasma current are the main determining parameters for the inward penetration of the T e perturbations. With increasing plasma current the ELM penetration is more shallow in spite of the stronger ELMs. Estimates of the heat pulse diffusivity show that the corresponding transport is too large to be representative of the inter-ELM phase. Ergodization of the plasma edge during ELMs is a possible explanation for the observed properties of the cold pulse propagation, which is qualitatively consistent with non-linear magneto-hydro-dynamic simulations
Cation and anion immobilization through chemical bonding enhancement with fluorides for stable halide perovskite solar cells
No full textDefects play an important role in the degradation processes of hybrid halide perovskite absorbers, impeding their application for solar cells. Among all defects, halide anion and organic cation vacancies are ubiquitous, promoting ion diffusion and leading to thin-film decomposition at surfaces and grain boundaries. Here, we employ fluoride to simultaneously passivate both anion and cation vacancies, by taking advantage of the extremely high electronegativity of fluoride. We obtain a power conversion efficiency of 21.46% (and a certified 21.3%-efficient cell) in a device based on the caesium, methylammonium (MA) and formamidinium (FA) triple-cation perovskite (Cs0.05FA0.54MA0.41)Pb(I0.98Br0.02)3 treated with sodium fluoride. The device retains 90% of its original power conversion efficiency after 1,000?h of operation at the maximum power point. With the help of first-principles density functional theory calculations, we argue that the fluoride ions suppress the formation of halide anion and organic cation vacancies, through a unique strengthening of the chemical bonds with the surrounding lead and organic cations
The influence of siloxane side-chains on the photovoltaic performance of a conjugated polymer
No full textProgress toward divertor detachment on TCV within H-mode operating parameters
No full textRecent experiments on Tokamak a Configuration Variable have made significant progress toward partial detachment of the outer divertor in neutral beam heated H-mode plasmas in conventional and alternative divertor configurations. The heating power required to enter H-mode was measured in a range of divertor configurations. It is found that at the core densities most favourable for H-mode access, the L-H threshold power is largely independent of the poloidal flux expansion and major radius of the outer divertor, and in the snowflake minus configuration. A factor 2 reduction in the outer divertor power load was achieved in ELM-free (using a fuelling and nitrogen seeding) and ELMy (using nitrogen seeding) H-mode plasmas. No significant reduction in the outer divertor particle flux was achieved in the ELM-free scenarios, compared with similar to 30% reduction in the most strongly detached ELMy cases. The poloidal flux expansion at the outer divertor was not found to significantly alter the cooling of the divertor in the ELM-free scenarios
Elucidating the role of gas dynamics in the vortex-confined microwave plasma on CO2 dissociation efficiency
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Preserving the Emission Lifetime and Efficiency of a Monolayer Semiconductor upon Transfer
No full textModel-based real-time plasma electron density profile estimation and control on ASDEX Upgrade and TCV
No full textReal-time plasma electron density profile estimation and control are essential in the operation of future tokamaks. In particular, the robustness against diagnostics failure and disturbances is important for long pulse operation.
A model-based approach to profile estimation is implemented on the control systems of ASDEX Upgrade and TCV, which is able to merge information from various diagnostics for both core and edge density, as well as systematically handling diagnostic failure. The model used for profile estimation is employed to tune a feedback controller before an experiment, thereby reducing the experimental time required for tuning.
Subsequently, this observer and controller have been employed in scientific experiments on ASDEX Upgrade and TCV. On ASDEX Upgrade, the density profile estimator was used in high-density pellet-fuelled discharges, providing a more reliable real-time estimate of the core density for feedback control than previously achieved. On TCV, in experiments on integrated pressure and safety factor profile control, the density profile estimator and feedback controller provide a constant density despite disturbances from time-varying ECCD power. Additionally, the real-time density profiles provide an essential input for other real-time plasma state estimation codes including Electron Cyclotron ray tracing codes, contributing to a complete real-time estimation of the entire plasma state
Numerical model for the determination of the reduced electric field in a CO2 microwave plasma derived by the principle of impedance matching
Get PDFThree dimensional electromagnetic modelling of a free-standing CO2 microwave plasma has been performed, by describing the plasma as a dielectric medium. The relative permittivity and conductivity of the medium are parametrised. The waveguide geometry from experiment, including the tuner, is put into the model, knowing that this corresponds to maximum power transfer of the microwave generator to the plasma under plasma impedance matching conditions. Two CO2 plasma discharge regimes, differing mainly in pressure, input power and temperature, have been studied. The model\u27s validity has been checked through study of materials of known conductivity. From measurements of the neutral gas temperature and the plasma electron density profile, the reduced electric field is determined. From the parametrisation of the dielectric properties, a range for the effective electron-neutral collision frequency for momentum transfer is estimated. The results for the reduced electric field and the range of the electron neutral collision frequency obtained, are consistent as verified by simulations using BOLSIG+. In addition, from this comparison it is possible to narrow down the range of the collision frequencies, and to estimate the electron temperature. The reduced electric field lies between 80 and 180 Td for the relatively low pressure, low input power, the so-called \u27diffuse\u27 regime. For the relatively high pressure, high input power (\u27contracted\u27) regime it lies between 10 and 60 Td. The normalised collision frequency lies between 1.6 and 2.3 for the diffuse regime, while for the contracted regime it lies between 2 and 3. The electron temperature ranges from 2 to 3 eV for the diffuse regime, and from 0.5 to 1 eV for the contracted regime. Related content: 10.1088/1361-6595/ab1ca1</p