Repozytorium Uniwersytetu Śląskiego RE-BUŚ
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    23505 research outputs found

    The effect of petroleum-derived substances and their bioremediation on soil enzymatic activity and soil invertebrates

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    Petroleum-derived substances (PDSs) as main pollutants of the natural environment can negatively affect the microbiological, biochemical, and biological properties of agricultural soils and, consequently, plant production. The present study aimed to determine the after-effect of PDSs such as petrol, used engine oil, and diesel fuel on the activity of selected soil enzymes (phosphatase, dehydrogenase, and urease) and on the occurrence of soil invertebrates. Moreover, changes in the analyzed parameters in response to bioremediation of the polluted soil by using ZB-01 preparation were investigated. The field experiments were performed four- and five-years post contamination. The results showed that even after five years, PDSs significantly modified the activity of soil enzymes; however, this effect was often varied, depending on the pollutant, enzyme, and time after soil contamination. Dehydrogenase seems to be a good indicator of soil contamination with PDSs, particularly diesel fuel. Engine oil and diesel fuel limited still the occurrence of soil invertebrates, particularly Collembola from the families Hypogastruidae, Isotomidae, and Entomobryidae, even after four and five years of contamination. This finding suggests the usefulness of these organisms in assessing soil pollution and in monitoring the progress of bioremediation. The effect of ZB-01 biopreparation on the activity of selected enzymes was varied. Its effect on the occurrence of soil invertebrates was usually beneficial, which was evident in diesel fuel-contaminated soil

    The role of intermolecular interactions in stabilizing the structure of the nematic twist-bend phase

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    The understanding of the relationship between molecular structure and the formation of the nematic twistbend phase is still at an early stage of development. This is mainly related to molecular geometry, while the correlation between the nematic twist-bend phase and the electronic structure is ambiguous. To explore the electronic effect on properties and stabilization of the nematic twist-bend phase we investigated 20,30-difluoro-4,400-dipentyl-p-terphenyl dimers (DTC5Cn). We used polarized fourier transform infrared spectroscopy, which can, at least in principle, provide information about the ordering in the twist-bend phase. All dimers show a significant drop in the average value of the transition dipole moment for parallel dipoles at the transition from the nematic to the twist-bend phase, and an increase for perpendicular dipoles, despite remaining unchanged for the monomer. Density functional theory calculations were used to determine the geometric and electronic properties of the hydrogen bonded complexes. We have provided experimental and theoretical evidence of stabilization of the nematic twist-bend phase by arrays of multiple hydrogen bonds (XF/HX, X–benzene ring)

    Correlation between Microstructure and Magnetism in Ball-Milled SmCo5/α-Fe (5%wt. α-Fe) Nanocomposite Magnets

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    Magnetic nanocomposites SmCo5/ -Fe were synthesized mechanically by high-energy ball milling (HEBM) from SmCo5 and 5%wt. of -Fe powders. The X-ray diffraction analysis reveals the hexagonal 1:5 phase as the main one accompanied by the cubic -Fe phase and 2:17 rhombohedral as the secondary phase. The content of each detected phase is modified throughout the synthesis duration. A significant decrease in crystallite size with a simultaneous increase in lattice straining is observed. A simultaneous gradual reduction in particle size is noted from the microstructural analysis. Magnetic properties reveal non-linear modification of magnetic parameters associated with the strength of the exchange coupling induced by various duration times of mechanical synthesis. The highest value of the maximum energy product (BH)max at room temperature is estimated for samples milled for 1 and 6 h. The intermediate mixed-valence state of Sm ions is confirmed by electronic structure analysis. An increase in the Co magnetic moment versus the milling time is evidenced based on the performed fitting of the Co3s core level lines

    Erratum to: Measurements of π − production in 7Be + 9Be collisions at beam momenta from 19A to 150AGeV/c in the NA61/SHINE experiment at the CERN SPS

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    A. Acharya, H. Adhikary, A. Aduszkiewicz, K. K. Allison, E. V. Andronov, T. Anti´ci´c, V. Babkin, M. Baszczyk, S. Bhosale, A. Blondel, M. Bogomilov, A. Brandin, A. Bravar, W. Brylinski, J. Brzychczyk, M. Buryakov, O. Busygina, A. Bzdak, H. Cherif, M. C´irkovic, M. Csanad, J. Cybowska, T. Czopowicz, A. Damyanova, N. Davis, M. Deliyergiyev, M. Deveaux, A. Dmitriev, W. Dominik, P. Dorosz, J. Dumarchez, R. Engel, G. A. Feofilov, L. Fields, Z. Fodor, A. Garibov, M. Gazdzicki, O. Golosov, V. Golovatyuk, M. Golubeva, K. Grebieszkow, F. Guber, A. Haesler, S. N. Igolkin, S. Ilieva, A. Ivashkin, S. R. Johnson, K. Kadija, N. Kargin, E. Kashirin, M. Kiełbowicz, V. A. Kireyeu, V. Klochkov, V. I. Kolesnikov, D. Kolev, A. Korzenev, V. N. Kovalenko, M. Koziel, A. Krasnoperov, W. Kucewicz, M. Kuich, A. Kurepin, D. Larsen, A. László, T. V. Lazareva, M. Lewicki, K. Łojek, V. V. Lyubushkin, M.Mackowiak-Pawłowska, Z. Majka, B. Maksiak, A. I. Malakhov, A. Marcinek, A. D. Marino, K. Marton, H.-J. Mathes, T. Matulewicz, V.Matveev, G. L. Melkumov, A. O. Merzlaya, B. Messerly, Ł.Mik, S. Morozov, S. Mrówczynski, Y. Nagai, M. Naskret, V. Ozvenchuk, V. Paolone, O. Petukhov, R. Płaneta, P. Podlaski, B. A. Popov, B. Porfy, M. Posiadała-Zezula, D. S. Prokhorova, D. Pszczel, J. Puzovic, M. Ravonel, R. Renfordt, D. Röhrich, E. Rondio, M. Roth, B. T. Rumberger, M. Rumyantsev, A. Rustamov, M. Rybczynski, A. Rybicki, S. Sadhu, A. Sadovsky, I. Selyuzhenkov, A. Yu. Seryakov, P. Seyboth, M. Słodkowski, P. Staszel, G. Stefanek, J. Stepaniak, M. Strikhanov, H. Ströbele, T. Šuša, A. Taranenko, A. Tefelska, D. Tefelski, V. Tereshchenko, A. Toia, R. Tsenov, L. Turko, R. Ulrich, M. Unger, D. Uzhva, F. F. Valiev, D. Veberic, V. V. Vechernin, A. Wickremasinghe, Z. Włodarczyk, O. Wyszynski, E. D. Zimmerman, R. ZwaskaErratum to: Eur. Phys. J. C. (2020) 80:961 https://doi.org/10.1140/epjc/s10052-020-08514-6 In this erratum, we clarify the details of the comparison of mT spectra between p+p, Be+Be, and Pb+Pb. In the published paper, the normalization of mT spectra was found inconsistent in Fig. 14. It was checked that not all spectra were normalized to the spectrum’s integral in the range 0.24 < mT − mπ − < 0.72 given in the paper. In this erratum, the ratios with correct normalization in the described region are shown. The normalized Be+Be spectra were then divided by the corresponding p+p and Pb+Pb spectra used as a reference

    Structural characterization of Al65Cu20Fe15 melt-spun alloy by X-ray, neutron diffraction, high-resolution electron microscopy and Mössbauer spectroscopy

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    The aim of the work was to characterize the structure of Al65Cu20Fe15 alloy obtained with the use of conventional casting and rapid solidification-melt-spinning technology. Based on the literature data, the possibility of an icosahedral quasicrystalline phase forming in the Al-Cu-Fe was verified. Structure analysis was performed based on the results of X-ray diffraction, neutron diffraction, 57Fe Mössbauer and transmission electron microscopy. Studies using differential scanning calorimetry were carried out to describe the crystallization mechanism. Additionally, electrochemical tests were performed in order to characterize the influence of the structure and cooling rate on the corrosion resistance. On the basis of the structural studies, the formation of a metastable icosahedral phase and partial amorphous state of ribbon structure were demonstrated. The possibility of the formation of icosahedral quasicrystalline phase I-AlCuFe together with the crystalline phases was indicated by X-ray diffraction (XRD), neutron diffraction (ND) patterns, Mössbauer spectroscopy, high-resolution transmission electron microscopy (HRTEM) observations and differential scanning calorimetry (DSC) curves. The beneficial effect of the application of rapid solidification on the corrosive properties was also confirmed

    Deflationist Caprice : "Imperfections" in the Sculpture of Leon Podsiadły

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    This article is an attempt to define the ambiguous specificity of artistic deflation in the sculpture of the Wroclavian artist Leon Podsiadły. At the outset, the author describes the principle of deflationist art and proposes a method of approach. She then discusses the “imperfections” within Podsiadły’s sculpture, the main manifestations of which include the use of common materials and mundane objects, secondary anti-mastery, and dememorization. These features coexist with wellthought- out composition, the inventiveness of the choice-making artist, and the creative fascination of unconventional artistic qualities, to which deflationist unlearning adds a unique slant. Seen from this perspective, Podsiadły’s deflationist caprice persuasively affirms the elasticity of the oscillation between the optics of modernism and postmodernism that defines his art. This oscillation can be seen, for instance, in those among his sculptures that were inspired by his stay in Africa in 1960s; in his “erotic” compositions; and in his installations of the 2010s in which he used the ready made. His “reductive” artistic experiments testify to a need for ironic distance; they individually gravitate toward the transgressive avant-garde and at the same time respond to the current trend of deskilling in art

    Intergenerational transmission of resistance of Callosobruchus maculatus to essential oil treatment

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    Due to the rise of numerous legal restrictions as well as the increasing emergence of resistant populations, the number of available pesticides is decreasing significantly. One of the potential alternatives often described in the literature are essential oils (EOs). However, there is a lack of research addressing the potential emergence of resistance to this group of substances. In this paper, we investigated the multi-generational effects of sublethal concentrations of rosemary oil (Rosmarinus officinalis) on physiological and biochemical parameters of the cowpea weevil (Callosobruchus maculatus) such as egg laying, hatchability, oxygen consumption and acetylcholinesterase activity. Imago, which as larvae were exposed to EO at concentrations equivalent to LC25, showed significantly lower mortality. The results obtained indicate the potential development of resistance in insects exposed to EO in concentrations corresponding to LC25. In addition, in the case of the group treated with an EO concentration corresponding to LC3.12, a stimulation effect of the above-mentioned parameters was observed, which may indicate the occurrence of a hormesis effect. The obtained results may be an important reference for the development of future guidelines and EO-based insecticides

    Intercultural Competence and Pragmatic Error

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    This paper discusses two topics which are very popular nowadays among the academics dealing with foreign language teaching, namely: intercultural competence and pragmatic error. The author notes the fact that those two notions appear separately, because the starting points for discussing them are usually different fields of science. The aim of the paper is to demonstrate that on one hand the two notions need to be treated uniformly, and on the other, that the pragmatic error should be included in error classifications which are references for both the authors of handbooks as well as people educating future teachers. For that purpose, the author defines intercultural competence, presents various approaches to error and its classification in teaching, and then explains what pragmatic error is and describes its linguistic characteristics

    Lament nad światem : o ludzkiej godności, nierównościach i niepokojach społecznych w kinie najnowszym

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    Przedmiot rozważań stanowią wybrane filmy ilustrujące społeczne nierówności i wynikające z nich niepokoje w różnych częściach świata na przełomie drugiej i trzeciej dekady XXI wieku. Ich bohaterowie pozbawieni możliwości edukacji, pracy, opieki medycznej i godnego miejsca do mieszkania żyją bez nadziei na poprawę egzystencji. Narastająca frustracja prowadzi do agresji, łamania prawa, brutalnej przemocy oraz zamieszek i walk ulicznych. Celem artykułu jest namysł nad problematyką podejmowaną w filmowych dyskursach i próba znalezienia odpowiedzi na pytania o przyczyny i czynniki wywołujące społeczne niepokoje. Do analizy badanej problematyki została wykorzystana kategoria godności ludzkiej

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