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From hosting to regional engagement: A capability approach to understanding international education and public diplomacy from the Indo Pacific community perspective
No full textFrom hosting to regional engagement: A capability approach to understanding international education and public diplomacy from the Indo Pacific community perspectiv
Perceived benefits and drawbacks of cultivating self-compassion among women diagnosed with Gestational Diabetes Mellitus (GDM)
No full textPerceived benefits and drawbacks of cultivating self-compassion among women diagnosed with Gestational Diabetes Mellitus (GDM
Bidirectional motion-aware GAN for future frame prediction in autonomous driving
No full textBidirectional motion-aware GAN for future frame prediction in autonomous drivin
Reversibility as a Design Principle in Inorganic, Organometallic and Organic Redox Mediators for Biosensors
No full textRedox mediators are central to electrochemical biosensors, enabling electron transfer between deeply buried enzymatic cofactors and electrode surfaces when direct electron transfer is kinetically inaccessible. Among all design parameters, the reversibility of mediator redox cycling remains the most decisive yet under-examined factor governing biosensor stability, drift and long-term reproducibility. This review establishes reversibility as a unifying framework grounded in inorganic and organometallic redox chemistry, with particular emphasis on coordination environments, ligand-field effects and outer-sphere electron-transfer pathways. Recent advances (2010–2025) in ruthenium and osmium polypyridyl complexes, cobalt macrocycles, hexacyanoferrates and Prussian Blue analogues are examined alongside ferrocene derivatives and other organometallic mediators, which together define the upper limits of reversible behaviour. Organic mediator families, including quinones, phenazines, indophenols, aminophenols and viologens, are discussed as mechanistic contrasts that highlight the structural and thermodynamic constraints that limit long-term cycling in aqueous media. Mechanistic indicators of reversibility, including peak separation, current ratios and heterogeneous electron-transfer rate constants, are linked to mediator architecture, coordination chemistry and immobilisation environment. By integrating molecular electrochemistry with applied sensor engineering, this review provides a mechanistically grounded basis for selecting or designing redox mediators that sustain efficient electron transfer, minimal fouling and calibration stability across diverse sensing platforms
Civil Society Responses to Extremism in the Philippine Bangsamoro
No full textCivil Society Responses to Extremism in the Philippine Bangsamor
Factors influencing language teachers’ judgements and decision-making about the use of generative AI tools: A systematic review
No full textFactors influencing language teachers’ judgements and decision-making about the use of generative AI tools: A systematic revie
Rethinking outbound student mobility to the Indo-Pacific
No full textRethinking outbound student mobility to the Indo-Pacifi
Energy modulation in Atlantic salmon: Oleic acid increases adipogenesis and energy deposition
No full textEnergy modulation in Atlantic salmon: Oleic acid increases adipogenesis and energy depositio
Governing Gender: Transgender Children, Hormones, and the Law
No full textGoverning Gender: Transgender Children, Hormones, and the La