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The Effect of Nuclear-Quadrupole Coupling in the Laser-Induced Alignment of Molecules
No full textWe present a theoretical study of the time-dependent laser alignment of molecules taking into account the hyperfine coupling due to nuclear-quadrupole interactions. The coupling of nuclear spins to the overall angular momentum of molecules significantly influences their rotational dynamics. Here, we systematically analyze the impact of the nuclear-quadrupole coupling on the rotational dynamics of the linear and the asymmetric-top diiodobenzene molecule induced by external laser fields. We explore different regimes of pulse shapes and laser-pulse intensities and detail under which conditions the quadrupole coupling cannot be neglected in the description of the laser alignment of molecules
A critical evaluation of microstructure-texture-mechanical behavior heterogeneity in high pressure torsion processed CoCuFeMnNi high entropy alloy
No full textThe present study aims to understand the evolution of textural and microstructural heterogeneity and its effect on evolution of mechanical properties of an equiatomic FCC CoCuFeMnNi high entropy alloy (HEA) disc subjected to high pressure torsion (HPT). HPT was performed on disc specimen with a hydrostatic pressure of 5 GPa for 0.1, 0.5, 1 and 5 turns at room temperature where the hardness saturated at 1941 MPa at the periphery of the sample after five turns. Synchrotron diffraction texture analysis of five-turn HPT sample reveals characteristic shear texture with the dominance of A and A* components near central region of the disc and it shifts to C {001} component near the periphery of the disc. X-ray diffraction analysis shows decrease in crystalline size with simultaneous increase in dislocation density for five-turn HPT sample with increasing strain from centre to the periphery of the disc. Microstructural analysis using electron back scatter diffraction and transmission electron microscopy indicates extensive grain fragmentation (≈55 nm) at the periphery of five-turn sample. The evolution of hardness from centre to the periphery of the disc cannot be explained only on the basis of evolution of grain size and dislocation density. The increase in contribution from solid solution strengthening due to partial dissolution of copper rich nano-clusters is expected to be the underlying cause for increase in the hardness. Thus, evolution of gradient microstructure, texture, and chemistry opens up new vistas for designing functionally graded materials for engineering applications
Thermoelastic equation of state and melting of Mg metal at high pressure and high temperature
No full textThe p-V-T equation of state of magnesium metal has been measured up to 20 GPa and 1500 K using both multianvil and opposite anvil techniques combined with synchrotron x-ray diffraction. To fit the experimental data, the model of Anderson–Grüneisen has been used with fixed parameter δT. The 300-K bulk modulus of B0 = 32.5(1) GPa and its first pressure derivative, B0′ = 3.73(2), have been obtained by fitting available data up to 20 GPa to the Murnaghan equation of state. Thermal expansion at ambient pressure has been described using second order polynomial with coefficients a = 25(2) × 10−6 K−1 and b = 9.4(4) × 10−9 K−2. The parameter describing simultaneous pressure and temperature impact on the thermal expansion coefficient (and, therefore, volume) is δT = 1.5(5). The good agreement between fitted and experimental isobars has been achieved to relative volumes of 0.75. The Mg melting observed by x-ray diffraction and in situ electrical resistivity measurements confirms previous results and additionally confirms the p-T estimations in the vicinity of melting
Long-Sought Redox Isomerization of the Europium(III/II) Complex Achieved by Molecular Reorientation at the Interface
No full textRedox isomerism, that is, the change of a metal cation valence state in organic complexes, can find promising applications in multistable molecular switches for various molecular electronic devices. However, despite a large number of studies devoted to such processes in organic complexes of multivalent lanthanides, redox-isomeric transformations were never observed for europium. In the present work, we demonstrate the unique case of redox isomerization of Eu(III)/Eu(II) complexes on the example of Eu double-decker octa-n-butoxyph- thalocyaninate (Eu[(BuO)8Pc]2) under ambient conditions (air and room temperature). It is shown that assumption of the face-on orientation on the aqueous subphase surface, in which two of each phthalocyanine decks in Eu[(BuO)8Pc]2 are located in different media (air and water), leads to the intramolecular electron transfer that results in the formation of a divalent Eu(II) cation in the complex. Lateral compression of the thus-formed monolayer results in the reorientation of bisphthalocyaninate to the edge-on state, in which the ligands can be considered identical, and occurrence of the reverse redox-isomeric transformation into the complex with a trivalent Eu cation. Both redox-isomeric states were directly observed by X-ray absorption near-edge structure spectroscopy in ultrathin films formed under different conditions
Proof-of-concept for 2D/CT element analysis of entire cryofrozen islets of Langerhans using a cryoloop synchrotron X-ray fluorescence setup
No full textRobust cosmological constraints on axion-like particles
No full textAxion-like particles with masses in the keV-GeV range have a profound impact on the cosmological evolution of our Universe, in particular on the abundance of light elements produced during Big Bang Nucleosynthesis. The resulting limits are complementary to searches in the laboratory and provide valuable additional information regarding the validity of a given point in parameter space. A potential drawback is that altering the cosmological history may potentially weaken or even fully invalidate these bounds. The main objective of this article is therefore to evaluate the robustness of cosmological constraints on axion-like particles in the keV–GeV region, allowing for various additional effects which may weaken the bounds of the standard scenario. Employing the latest determinations of the primordial abundances as well as information from the cosmic microwave background we find that while bounds can indeed be weakened, very relevant robust constraints remain
P2M: A 2MPixel CMOS Image Sensor for Soft X-Ray Detection
No full textHigh brilliance synchrotrons and Free Electron Lasers (FELs) require high performing detector systems to realise their full potential. High dynamic range, low noise and high frame rate are all of great importance. In this paper we describe the P2M CMOS sensor, designed for soft X-ray detection at such facilities. We refer to previous work on test devices demonstrating a noise of 5Me- and quantum efficiency of >80% at 400eV (and with good sensitivity even below this value). Initial test results on the first Front Side Illuminated (FSI) 2 Megapixel device are also presented, and an outline of future work is described
Structure of a collagen VI α3 chain VWA domain array: adaptability and functional implications of myopathy causing mutations
No full textCollagen VI is a ubiquitous heterotrimeric protein of the extracellular matrix (ECM) that plays an essential role in the proper maintenance of skeletal muscle. Mutations in collagen VI lead to a spectrum of congenital myopathies, from the mild Bethlem myopathy to the severe Ullrich congenital muscular dystrophy. Collagen VI contains only a short triple helix and consists primarily of von Willebrand factor type A (VWA) domains, protein–protein interaction modules found in a range of ECM proteins. Disease-causing mutations occur commonly in the VWA domains, and the second VWA domain of the α3 chain, the N2 domain, harbors several such mutations. Here, we investigate structure-function relationships of the N2 mutations to shed light on their possible myopathy mechanisms. We determined the X-ray crystal structure of N2, combined with monitoring secretion efficiency in cell culture of selected N2 single-domain mutants, finding that mutations located within the central core of the domain severely affect secretion efficiency. In longer α3 chain constructs, spanning N6-N3, small-angle X-ray scattering demonstrates that the tandem VWA array has a modular architecture and samples multiple conformations in solution. Single-particle EM confirmed the presence of multiple conformations. Structural adaptability appears intrinsic to the VWA domain region of collagen VI α3 and has implications for binding interactions and modulating stiffness within the ECM
An improved setup for radial diffraction experiments at high pressures and high temperatures in a resistive graphite-heated diamond anvil cell
No full textWe present an improved setup for the experimental study of deformation of solids at simultaneous high pressures and temperatures by radial x-ray diffraction. This technique employs a graphite resistive heated Mao–Bell type diamond anvil cell for radial x-ray diffraction in combination with a water-cooled vacuum chamber. The new chamber has been developed by the sample environment group at PETRA III and implemented at the Extreme Conditions Beamline P02.2 at PETRA III, DESY (Hamburg, Germany). We discuss applications of the new setup to study deformation of a variety of materials, including ferropericlase, calcium perovskite, bridgmanite, and tantalum carbide, at high-pressure/temperature
A search for dark matter in Triangulum II with the MAGIC telescopes
No full textWe present the first results from very-high-energy observations of the dwarf spheroidal satellite candidate Triangulum II with the MAGIC telescopes from 62.4 hours of good-quality data taken between August 2016 and August 2017. We find no gamma-ray excess in the direction of Triangulum II, and upper limits on both the differential and integral gamma-ray flux are presented. Currently, the kinematics of Triangulum II are affected by large uncertainties leading to a bias in the determination of the properties of its dark matter halo. Using a scaling relation between the annihilation J-factor and heliocentric distance of well-known dwarf spheroidal galaxies, we estimate an annihilation J-factor for Triangulum II for WIMP dark matter of GeV cm. We also derive a dark matter density profile for the object relying on results from resolved simulations of Milky Way sized dark matter halos. We obtain 95% confidence-level limits on the thermally averaged annihilation cross section for WIMP annihilation into various Standard Model channels. The most stringent limits are obtained in the final state, where a cross section for annihilation down to cm s is excluded